Meteorological Conditions Surrounding High Ozone Events in California's Central Valley

Meteorological Conditions Surrounding High Ozone Events in California's Central Valley

Author: Samantha Danielle Caputi

Publisher:

Published: 2020

Total Pages: 0

ISBN-13:

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The San Joaquin Valley has a notorious ozone violation problem that has persisted despite other areas in California trending toward cleaner air at a faster rate in recent decades. Here we synthesize the various synoptic, mesoscale, and microscale meteorological factors that contribute to this problem. In particular, data from the California Baseline Ozone Transport Study (CABOTS) field campaign in the summer of 2016 are analyzed, which include 170 hours of aircraft data, and these aircraft deployments are looked at in the context of background synoptic-scale meteorological conditions. We lastly highlight the importance of measuring synoptic-scale subsidence in mountain-valley systems such as the San Joaquin Valley where air pollution is an issue, assess our current ability to accomplish this, and propose new methods for future research in this domain. Some key findings from these analyses include: 1) Nighttime mesoscale features in the Southern San Joaquin Valley, mainly the low level jet and Fresno Eddy, can either recirculate or deplete ozone from the previous day, and which of these two processes dominate on any given night is determined by the low level jet strength; 2) It is extremely important to track the chemical fate of the Nitrate radical at night as this can have a large effect on the ozone budget; 3) A 3-layer model of the atmosphere is proposed, where a buffer layer exists between the daytime boundary layer and free troposphere above, and the entrainment processes at the top of the boundary layer are important to track as pollutants from the previous day can be injected into the buffer layer by the mountain-valley circulation; 4) A low-cost method of estimating turbulence (specifically the convective velocity scale, turbulent kinetic energy, and eddy dissipation) from aircraft data without a gust probe is developed; 5) The newly developed Micro-Doppler lidar that was used during CABOTS shows promising first results in its ability to measure fair-weather vertical velocities in the lower atmosphere.


Meteorology-induced Variations in the Spatial Behavior of Summer Ozone Pollution in Central California

Meteorology-induced Variations in the Spatial Behavior of Summer Ozone Pollution in Central California

Author:

Publisher:

Published: 2010

Total Pages:

ISBN-13:

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Cluster analysis was applied to daily 8 h ozone maxima modeled for a summer season to characterize meteorology-induced variations in the spatial distribution of ozone. Principal component analysis is employed to form a reduced dimension set to describe and interpret ozone spatial patterns. The first three principal components (PCs) capture (almost equal to)85% of total variance, with PC1 describing a general spatial trend, and PC2 and PC3 each describing a spatial contrast. Six clusters were identified for California's San Joaquin Valley (SJV) with two low, three moderate, and one high-ozone cluster. The moderate ozone clusters are distinguished by elevated ozone levels in different parts of the valley: northern, western, and eastern, respectively. The SJV ozone clusters have stronger coupling with the San Francisco Bay area (SFB) than with the Sacramento Valley (SV). Variations in ozone spatial distributions induced by anthropogenic emission changes are small relative to the overall variations in ozone amomalies observed for the whole summer. Ozone regimes identified here are mostly determined by the direct and indirect meteorological effects. Existing measurement sites are sufficiently representative to capture ozone spatial patterns in the SFB and SV, but the western side of the SJV is under-sampled.