Metal Complexes Containing Boron Based Ligands
Metal Complexes Containing Boron Based Ligands

Author: Gareth Owen

Publisher: MDPI

Published: 2019-10-30

Total Pages: 110

ISBN-13: 3039215841

DOWNLOAD EBOOK

Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.

Boron-Based Compounds
Boron-Based Compounds

Author: Evamarie Hey-Hawkins

Publisher: John Wiley & Sons

Published: 2018-07-23

Total Pages: 490

ISBN-13: 1119275555

DOWNLOAD EBOOK

Noted experts review the current status of boron-containing drugs and materials for molecular medical diagnostics Boron-Based Compounds offers a summary of the present status and promotes the further development of new boron-containing drugs and advanced materials, mostly boron clusters, for molecular medical diagnostics. The knowledge accumulated during the past decades on the chemistry and biology of bioorganic and organometallic boron compounds laid the foundation for the emergence of a new area of study and application of boron compounds as lipophilic pharmacophores and modulators of biologically active molecules.This important text brings together in one comprehensive volume contributions from renowned experts in the field of medicinal chemistry of boron compounds. The authors cover a range of the most relevant topics including boron compounds as modulators of the bioactivity of biomolecules, boron clusters as pharmacophores or for drug delivery, boron compounds for boron neutron capture therapy (BNCT) and for diagnostics, as well as in silico molecular modeling of boron- and carborane-containing compounds in drug design. Authoritative and accessible, Boron-Based Compounds: Contains contributions from a panel of internationally renowned experts in the field Offers a concise summary of the current status of boron-containing drugs and materials used for molecular diagnostics Highlights the range and capacity of boron-based compounds in medical applications Includes information on boron neutron capture therapy and diagnostics Designed for academic and industrial scientists, this important resource offers the cutting-edge information needed to understand the current state of boron-containing drugs and materials for molecular medical diagnostics.

Contemporary Boron Chemistry
Contemporary Boron Chemistry

Author: Matthew G Davidson

Publisher: Royal Society of Chemistry

Published: 2007-10-31

Total Pages: 555

ISBN-13: 1847550649

DOWNLOAD EBOOK

The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.

Nuclear Magnetic Resonance Spectroscopy of Boron Compounds
Nuclear Magnetic Resonance Spectroscopy of Boron Compounds

Author: Heinrich Nöth

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 474

ISBN-13: 3642667570

DOWNLOAD EBOOK

The revolutionary impetus of the NMR methods in organic chemistry has parallels in the field of boron chemistry. lIB NMR spectroscopy provided a basis for the elucida tion of structures and reactions of the boron hydrides. However, although many studies have been carried out with the higher boranes, carboranes, metalloboranes, etc. , and although certain patterns have emerged, the correlation between the observed chemical shift and the assigned structural unit is still not fully understood. Therefore, predictions in this area are still rather limited, and semiquantitative interpretations are not yet pos sible. Several years ago Eaton and Lipscomb sUpImarized the status in this field in their book "NMR Studies of Boron Hydrides and Related Compounds" and a plethora of new data has accumulated since then. The book also contained material on simple bo rane derivatives, but they were not discussed in any detail. On the other hand many systematic studies, both synthetic and spectroscopic, have been conducted on these simple boron materials in the last decade. Thus a large amount of NMR information is available, not only on lIB but also on 1 H, 1 3 C, and 14 N. However, this information is widely scattered in the literature, and often the data are not discussed at all. It see med appropriate, therefore, to collect these data and to present them in one volume.

Scorpionates: The Coordination Chemistry Of Polypyrazolylborate Ligands
Scorpionates: The Coordination Chemistry Of Polypyrazolylborate Ligands

Author: Swiatoslaw Trofimenko

Publisher: World Scientific

Published: 1999-08-16

Total Pages: 294

ISBN-13: 1783261994

DOWNLOAD EBOOK

This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their “Bite” can be adjusted, and additional coordinating sites can be added to the pyrazolyl rings. Over 170 different scorpionate ligands are known today, and some are published for the first time in this book.The author, Swiatoslaw Trofimenko, discovered and developed this ligand system and has written several reviews on the subject. The book is intended as a reference work, placing at the researcher's command practically all of the over 1500 references on the subject up, and into 1999, organized both according to the ligand type and according to the metal or metalloid being coordinated. It acquaints the reader with the special features of this ligand system and permits an assessment of what has been done in a given sub-area, and of which areas remain relatively unexplored. It presents procedures for ligand synthesis, and also covers their use in catalysis and in the modelling of biologically active substances.

Organometallic Chemistry
Organometallic Chemistry

Author: M Green

Publisher: Royal Society of Chemistry

Published: 2007-10-31

Total Pages: 321

ISBN-13: 184755850X

DOWNLOAD EBOOK

Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry.

Organometallic Chemistry Volume 43
Organometallic Chemistry Volume 43

Author: Paul I. P. Elliott

Publisher: Royal Society of Chemistry

Published: 2020-11-09

Total Pages: 247

ISBN-13: 1788016912

DOWNLOAD EBOOK

Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic and coordination chemistry research and emerging fields. With the increase in volume, velocity and variety of information, researchers can find it difficult to keep up to date with the literature in their field. The reviews range in scope and include recent advances in chromium coordination chemistry, borohydride and borane ligand architectures supported by heterocyclic units and discussion on behaviours of novel ruthenium (II) complexes. This volume is a key reference for researchers in academic and industrial settings.

Organometallic Chemistry
Organometallic Chemistry

Author: Nathan J Patmore

Publisher: Royal Society of Chemistry

Published: 2020-11-02

Total Pages: 247

ISBN-13: 1788017072

DOWNLOAD EBOOK

Providing an invaluable resource, this volume contains analysed, evaluated and distilled information on the latest in organometallic and coordination chemistry research and emerging fields. With the increase in volume, velocity and variety of information, researchers can find it difficult to keep up to date with the literature in their field. The reviews range in scope and include recent advances in chromium coordination chemistry, borohydride and borane ligand architectures supported by heterocyclic units and discussion on behaviours of novel ruthenium(II) complexes. This volume is a key reference for researchers in academic and industrial settings.

Coordination Chemistry—XIV
Coordination Chemistry—XIV

Author: A. B. P. Lever

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 206

ISBN-13: 1483284727

DOWNLOAD EBOOK

Coordination Chemistry–XIV provides information pertinent to the fundamental characteristics and synthesis of coordination compounds. This book discusses the importance of undertaking accurate X-ray analysis of a wide-ranging series of complexes in order to derive more secure theoretical correlations. Organized into 13 chapters, this book begins with an overview of the properties of alkyl and aryl derivatives of transition elements. This text then describes the two methods that lead to transition metal complexes of carborane ligands, namely, polyhedral expansion and polyhedral contraction. Other chapters consider the argument that organo-transition metal complexes also consisting phosphines and similar ligands are often too kinetically inert to act as good models for catalytic processes. This book discusses as well the developments in the mechanisms of substitution in transition metal complexes. The final chapter deals with the calibration of low resolution spectrometers. This book is a valuable resource for chemists, organometallic chemists, and inorganic chemists.

Boron-Based Compounds
Boron-Based Compounds

Author: Evamarie Hey-Hawkins

Publisher: John Wiley & Sons

Published: 2018-04-03

Total Pages: 496

ISBN-13: 111927558X

DOWNLOAD EBOOK

Noted experts review the current status of boron-containing drugs and materials for molecular medical diagnostics Boron-Based Compounds offers a summary of the present status and promotes the further development of new boron-containing drugs and advanced materials, mostly boron clusters, for molecular medical diagnostics. The knowledge accumulated during the past decades on the chemistry and biology of bioorganic and organometallic boron compounds laid the foundation for the emergence of a new area of study and application of boron compounds as lipophilic pharmacophores and modulators of biologically active molecules.This important text brings together in one comprehensive volume contributions from renowned experts in the field of medicinal chemistry of boron compounds. The authors cover a range of the most relevant topics including boron compounds as modulators of the bioactivity of biomolecules, boron clusters as pharmacophores or for drug delivery, boron compounds for boron neutron capture therapy (BNCT) and for diagnostics, as well as in silico molecular modeling of boron- and carborane-containing compounds in drug design. Authoritative and accessible, Boron-Based Compounds: Contains contributions from a panel of internationally renowned experts in the field Offers a concise summary of the current status of boron-containing drugs and materials used for molecular diagnostics Highlights the range and capacity of boron-based compounds in medical applications Includes information on boron neutron capture therapy and diagnostics Designed for academic and industrial scientists, this important resource offers the cutting-edge information needed to understand the current state of boron-containing drugs and materials for molecular medical diagnostics.