Membrane Reactors for Hydrogen Production Processes

Membrane Reactors for Hydrogen Production Processes

Author: Marcello De Falco

Publisher: Springer Science & Business Media

Published: 2011-03-25

Total Pages: 244

ISBN-13: 0857291513

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Membrane Reactors for Hydrogen Production Processes deals with technological and economic aspects of hydrogen selective membranes application in hydrogen production chemical processes. Membrane Reactors for Hydrogen Production Processes starts with an overview of membrane integration in the chemical reaction environment, formulating the thermodynamics and kinetics of membrane reactors and assessing the performance of different process architectures. Then, the state of the art of hydrogen selective membranes, membrane manufacturing processes and the mathematical modeling of membrane reactors are discussed. A review of the most useful applications from an industrial point of view is given. These applications include: natural gas steam reforming, autothermal reforming, water gas shift reaction, decomposition of hydrogen sulphide, and alkanes dehydrogenation. The final part is dedicated to the description of a pilot plant where the novel configuration was implemented at a semi-industrial scale. Plant engineers, researchers and postgraduate students will find Membrane Reactors for Hydrogen Production Processes a comprehensive guide to the state of the art of membrane reactor technology.


Membrane Reactors for Hydrogen Production Processes

Membrane Reactors for Hydrogen Production Processes

Author: Marcello De Falco

Publisher: Springer

Published: 2014-08-20

Total Pages: 0

ISBN-13: 9781447160502

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Membrane Reactors for Hydrogen Production Processes deals with technological and economic aspects of hydrogen selective membranes application in hydrogen production chemical processes. Membrane Reactors for Hydrogen Production Processes starts with an overview of membrane integration in the chemical reaction environment, formulating the thermodynamics and kinetics of membrane reactors and assessing the performance of different process architectures. Then, the state of the art of hydrogen selective membranes, membrane manufacturing processes and the mathematical modeling of membrane reactors are discussed. A review of the most useful applications from an industrial point of view is given. These applications include: natural gas steam reforming, autothermal reforming, water gas shift reaction, decomposition of hydrogen sulphide, and alkanes dehydrogenation. The final part is dedicated to the description of a pilot plant where the novel configuration was implemented at a semi-industrial scale. Plant engineers, researchers and postgraduate students will find Membrane Reactors for Hydrogen Production Processes a comprehensive guide to the state of the art of membrane reactor technology.


Membrane Reactors for Hydrogen Production Processes

Membrane Reactors for Hydrogen Production Processes

Author: Marcello De Falco

Publisher: Springer

Published: 2011-04-08

Total Pages: 235

ISBN-13: 9780857291523

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Membrane Reactors for Hydrogen Production Processes deals with technological and economic aspects of hydrogen selective membranes application in hydrogen production chemical processes. Membrane Reactors for Hydrogen Production Processes starts with an overview of membrane integration in the chemical reaction environment, formulating the thermodynamics and kinetics of membrane reactors and assessing the performance of different process architectures. Then, the state of the art of hydrogen selective membranes, membrane manufacturing processes and the mathematical modeling of membrane reactors are discussed. A review of the most useful applications from an industrial point of view is given. These applications include: natural gas steam reforming, autothermal reforming, water gas shift reaction, decomposition of hydrogen sulphide, and alkanes dehydrogenation. The final part is dedicated to the description of a pilot plant where the novel configuration was implemented at a semi-industrial scale. Plant engineers, researchers and postgraduate students will find Membrane Reactors for Hydrogen Production Processes a comprehensive guide to the state of the art of membrane reactor technology.


Handbook of Membrane Reactors

Handbook of Membrane Reactors

Author: Angelo Basile

Publisher: Elsevier

Published: 2013-04-04

Total Pages: 973

ISBN-13: 0857097342

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Membrane reactors are increasingly replacing conventional separation, process and conversion technologies across a wide range of applications. Exploiting advanced membrane materials, they offer enhanced efficiency, are very adaptable and have great economic potential. There has therefore been increasing interest in membrane reactors from both the scientific and industrial communities, stimulating research and development. The two volumes of the Handbook of membrane reactors draw on this research to provide an authoritative review of this important field.Volume 2 reviews reactor types and industrial applications, beginning in part one with a discussion of selected types of membrane reactor and integration of the technology with industrial processes. Part two goes on to explore the use of membrane reactors in chemical and large-scale hydrogen production from fossil fuels. Electrochemical devices and transport applications of membrane reactors are the focus of part three, before part four considers the use of membrane reactors in environmental engineering, biotechnology and medicine. Finally, the book concludes with a discussion of the economic aspects of membrane reactors.With its distinguished editor and international team of expert contributors, the two volumes of the Handbook of membrane reactors provide an authoritative guide for membrane reactor researchers and materials scientists, chemical and biochemical manufacturers, industrial separations and process engineers, and academics in this field. Discusses integration of membrane technology with industrial processes Explores the use of membrane reactors in chemical and large-scale hydrogen production from fossil fuels Considers electrochemical devices and transport applications of membrane reactors


Current Trends and Future Developments on (Bio-) Membranes

Current Trends and Future Developments on (Bio-) Membranes

Author: Adolfo Iulianelli

Publisher: Elsevier

Published: 2020-07-22

Total Pages: 488

ISBN-13: 0128173858

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In the last decade, the attention paid to the environmental protection has generated a considerable interest towards the development of new energy carriers and green energy production methods. Hydrogen as an energy carrier becomes a potential important source of energy due to its neutral environmental impact. However, its production, transformation and purification, presents a challenge in the so called hydrogen economy. Current Trends and Future Developments on (Bio-) Membranes gives a comprehensive review on the present state of the art of the hydrogen production and purification using new and alternative technologies stressing green processes and environment protection. The book covers green processes, renewable feedstocks utilization and membrane reactor technology for hydrogen production in line with new process intensification strategy. The book is divided in four sections, ie fundamentals of hydrogen generation, its impact on environmental issue, new applications involving hydrogen and its storage and distribution. The main scope of this book is to offer a new horizon on hydrogen generation and utilization. It stresses the role of new technologies for hydrogen generation, including the “micro-reactors technology for portable applications , their combination with high temperature fuel cells, the role of gas-separation for both hydrogen purification and CO2 sequestration, the exploitation of renewable sources (biogas, bioethanol and other renewables feedstocks) in reforming processes useful to generate hydrogen, membrane and membrane reactor technology as well as membrane bio-reactors etc. Presents process intensification and commercialization of new and alternative hydrogen generation technologies Relates new hydrogen production methods to their environmental impact Outlines the fundamentals of hydrogen generation Includes new developed technologies for hydrogen transport and storage


Membrane Reactor Engineering

Membrane Reactor Engineering

Author: Angelo Basile

Publisher: John Wiley & Sons

Published: 2016-08-01

Total Pages: 344

ISBN-13: 1118906810

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Uniquely focussed on the engineering aspects of membrane reactors Provides tools for analysis with specific regard to sustainability Applications include water treatment, wastewater recycling, desalination, biorefineries, agro-food production Membrane reactors can bring energy saving, reduced environmental impact and lower operating costs


Hydrogen Production, Separation and Purification for Energy

Hydrogen Production, Separation and Purification for Energy

Author: Angelo Basile

Publisher: IET

Published: 2017-02-24

Total Pages: 489

ISBN-13: 1785611003

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Hydrogen is one of the most promising next-generation fuels. It has the highest energy content per unit weight of any known fuel and in comparison to the other known natural gases it is environmentally safe - in fact, its combustion results only in water vapour and energy. This book provides an overview of worldwide research in the use of hydrogen in energy development, its most innovative methods of production and the various steps necessary for the optimization of this product.


Palladium Membrane Technology for Hydrogen Production, Carbon Capture and Other Applications

Palladium Membrane Technology for Hydrogen Production, Carbon Capture and Other Applications

Author: A Doukelis

Publisher: Elsevier

Published: 2014-10-20

Total Pages: 403

ISBN-13: 1782422412

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Thanks to their outstanding hydrogen selectivity, palladium membranes have attracted extensive R&D interest. They are a potential breakthrough technology for hydrogen production and also have promising applications in the areas of thermochemical biorefining. This book summarises key research in palladium membrane technologies, with particular focus on the scale-up challenges. After an introductory chapter, Part one reviews the fabrication of palladium membranes. Part two then focuses on palladium membrane module and reactor design. The final part of the book reviews the operation of palladium membranes for synthesis gas/hydrogen production, carbon capture and other applications. Review of manufacture and design issues for palladium membranes Discussion of the applications of palladium membrane technology, including solar steam reforming, IGCC plants, NGCC plants, CHP plants and hydrogen production Examples of the technology in operation


A NOVEL MEMBRANE REACTOR FOR DIRECT HYDROGEN PRODUCTION FROM COAL.

A NOVEL MEMBRANE REACTOR FOR DIRECT HYDROGEN PRODUCTION FROM COAL.

Author:

Publisher:

Published: 2005

Total Pages:

ISBN-13:

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Gas Technology Institute is developing a novel concept of membrane reactor coupled with a gasifier for high efficiency, clean and low cost production of hydrogen from coal. The concept incorporates a hydrogen-selective membrane within a gasification reactor for direct extraction of hydrogen from coal-derived synthesis gases. The objective of this project is to determine the technical and economic feasibility of this concept by screening, testing and identifying potential candidate membranes under high temperature, high pressure, and harsh environments of the coal gasification conditions. The best performing membranes will be selected for preliminary reactor design and cost estimates. Hydrogen permeation data for several perovskite membranes BCN (BaCe{sub 0.9}Nd{sub 0.1}O{sub 3-x}), SCE (SrCe{sub 0.9}Eu{sub 0.1}O3) and SCTm (SrCe{sub 0.95}Tm{sub 0.05}O3) have been successfully obtained for temperatures between 800 and 950 C and pressures from 1 to 12 bar in this project. However, it is known that the cerate-based perovskite materials can react with CO2. Therefore, the stability issue of the proton conducting perovskite materials under CO2 or H2S environments was examined. Tests were conducted in the Thermo Gravimetric Analyzer (TGA) unit for powder and disk forms of BCN and SCE. Perovskite materials doped with zirconium (Zr) are known to be resistant to CO2. The results from the evaluation of the chemical stability for the Zr doped perovskite membranes are presented. During this reporting period, flowsheet simulation was also performed to calculate material and energy balance based on several hydrogen production processes from coal using high temperature membrane reactor (1000 C), low temperature membrane reactor (250 C), or conventional technologies. The results show that the coal to hydrogen process employing both the high temperature and the low temperature membrane reactors can increase the hydrogen production efficiency (cold gas efficiency) by more than 50% compared to the conventional process. Using either high temperature or low temperature membrane reactor process also results in an increase of the cold gas efficiencies as well as the thermal efficiencies of the overall process.


Hydrogen Production Technologies

Hydrogen Production Technologies

Author: Mehmet Sankir

Publisher: John Wiley & Sons

Published: 2017-03-20

Total Pages: 653

ISBN-13: 1119283655

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Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.