Volume 1: Mechanisms of Inorganic and Organometallic Reactions

Volume 1: Mechanisms of Inorganic and Organometallic Reactions

Author: M. Twigg

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 381

ISBN-13: 1461574102

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During recent years a high level of interest has been maintained in the kinetics and mechanisms of inorganic compounds in solution, and there has also been a notable upsurge of literature concerned with reaction mechanisms of organo transition metal compounds. The reviews of the primary literature previously provided by "Inorganic Reaction Mechanisms" (Royal Society of Chemistry) and "Reaction Mechanisms in Inorganic Chemistry" in "MTP International Re views of Science" (Butterworths) continue to be of considerable value to those concerned with mechanistic studies, and it is unfortunate they are no longer published. The objective of the present series is to provide a continuing critical review of literature dealing with mechanisms of inorganic and organometallic reactions in solution. The scope of potentially relevant work is very large, particularly in the field of organotransition metal chemistry, and papers for inclusion have been chosen that specifically probe mechanistic aspects, rather than those of a prep arative nature. This volume covers the literature published during the period July 1979 to December 1980 inclusive. Material is arranged basically by type of reaction and type of compound along generally accepted lines. Numerical data are usually reported in the units used by the original authors, though the units of some results have been converted in order to make comparisons.


Mechanisms of Inorganic and Organometallic Reactions Volume 7

Mechanisms of Inorganic and Organometallic Reactions Volume 7

Author: M.V. Twigg

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 468

ISBN-13: 146153710X

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The objective of Mechanisms of Inorganic and Organometallic Reactions is to provide an ongoing critical review of the literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. The main focus is on reactions in solution, although solid state and gas phase studies are included where they provide relevant mechanistic insight. Each volume covers an eighteen month literature period, and this, the seventh volume in the series, deals with papers published during July 1988 through December 1989. Where appropriate, there are references to earlier work, and also to specific sections in previous volumes. Coverage continues to span the whole area as comprehensively as possible in each volume, and although it is impossible be absolutely complete, every effort is made to include all the important for it to published work that is relevant to the elucidation of reaction mechanisms. Numerical data are reported in the units used by the original authors, and they are only converted to common units when making comparisons. The basic format of earlier volumes is retained to facilitate tracing progress over several years in a particular topic; this can now be done for more than a decade worth of research. In the last volume, ligand reactivity of both coordination and organometallic compounds were brought together in Chapter 12, and, in response to numerous positive comments from readers, this arrangement has been maintained. There have been some similar suggestions about oscillating reactions, and this topic may have a separate section in the next volume.


Inorganic and Organometallic Reaction Mechanisms

Inorganic and Organometallic Reaction Mechanisms

Author: Jim D. Atwood

Publisher: John Wiley & Sons

Published: 1997-02-18

Total Pages: 327

ISBN-13: 0471188972

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Jetzt in neuer Auflage: Das erfolgreiche Lehrwerk über Kinetik und Mechanismen anorganischer und organometallischer Reaktionen für fortgeschrittene Studenten! Hervorragend geeignet als Begleiter eines Vorlesungssemesters. Mit zahlreichen Übungsaufgaben; für eine bessere Übersicht sorgen Zusammenfassungen am Ende jedes Kapitels.


Mechanisms of Inorganic and Organometallic Reactions

Mechanisms of Inorganic and Organometallic Reactions

Author: M.V. Twigg

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 539

ISBN-13: 1461308275

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This series, Mechanisms of Inorganic and Organometallic Reactions, provides an ongoing critical review of the published literature concerned with the mechanisms of reactions of inorganic and organometallic compounds. Emphasis is on reactions in solution, although solid state and gas phase studies are included where they provide mechanistic insight. The sixth volume deals with papers published during the period January 1987 through June 1988 inclusive, together with some earlier work where it is appropriate to make comparisons. Coverage spans the whole area as comprehensively as practically possible, and the cited references are chosen for their relevance to the elucidation of reaction mechanisms. The now familiar format of earlier volumes has been maintained to facilitate tracing progress in a particular topic over several volumes, but some small changes have been made. Reflecting the a'mount of mechanistic work associated with ligand reactivity, and the growing importance of this area, Chapter 12 has been renamed and enlarged to bring together informa tion on both coordination and organometallic systems involving ligand reactions. Numerical data are usually reported in the units used by the original authors, except when making comparisons and conversion to common units is necessary.


GeR4 Compounds and Ge(CH3) 3R Compounds up to Cyclic Alkyl Groups

GeR4 Compounds and Ge(CH3) 3R Compounds up to Cyclic Alkyl Groups

Author: Frank Glockling

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 247

ISBN-13: 3662074532

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The present volume opens the Gmelin series on organogermanium compounds, that is, those compounds containing at least one germanium-to-carbon bond. This whole series is being coordinated by Professor J. Satge of the Universite Paul Sabatier in Toulouse. Germanium is of historical interest because its existence was predicted by Newlands in 1864 and by Mendeleeff in 1871 although it was not isolated until1887 by Winkler. Mendeleeff's predictions of the properties of germanium and its compounds by comparison with what was known of the chemistry of its neighbors, silicon and tin, proved remarkably accurate and included predictions of the existence of organic derivatives GeR and of their properties. 4 Although significant applications are as yet lacking for organogermanium compounds in contrast to organo-silicon, -tin, and -lead compounds there has been considerable interest in the parallel development of its chemistry. Up to 1983 about 1500 publications have appeared on organogermanium chemistry. The material of the present series will be grouped in a similar way as for the organotin series beginning with compounds containing only one germanium atom (mononuclear com pounds) and continuing with binuclear up to polynuclear compounds. Within each group the compounds are arranged by the kind of non-carbon substituents rather than by following the usual Gmelin principle of the last position using the Gmelin system of elements.


Basic Inorganic Chemistry

Basic Inorganic Chemistry

Author: F. Albert Cotton

Publisher: John Wiley & Sons

Published: 1995-01-18

Total Pages: 858

ISBN-13: 0471505323

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Explains the basics of inorganic chemistry with a primary emphasis on facts; then uses the student's growing factual knowledge as a foundation for discussing the important principles of periodicity in structure, bonding and reactivity. New to this updated edition: improved treatment of atomic orbitals and properties such as electronegativity, novel approaches to the depiction of ionic structures, nomenclature for transition metal compounds, quantitative approaches to acid-base chemistry, Wade's rules for boranes and carboranes, the chemistry of major new classes of substances including fullerenes and silenes plus a chapter on the inorganic solid state.


Reaction Mechanisms of Metal Complexes

Reaction Mechanisms of Metal Complexes

Author: R W Hay

Publisher: Elsevier

Published: 2000-03-01

Total Pages: 177

ISBN-13: 1782420630

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This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. - Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry - Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands


Inorganic Chemistry

Inorganic Chemistry

Author: Harold H. Trimm

Publisher: CRC Press

Published: 2011-04-15

Total Pages: 334

ISBN-13: 1926692594

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Inorganic chemistry is the study of all chemical compounds except those containing carbon, which is the field of organic chemistry. There is some overlap since both inorganic and organic chemists traditionally study organometallic compounds. Inorganic chemistry has very important ramifications for industry. Current research interests in inorganic chemistry include the discovery of new catalysts, superconductors, and drugs to combat disease. This new volume covers a diverse collection of topics in the field, including new methods to detect unlabeled particles, measurement studies, and more.


Basics of Reaction Mechanism in Inorganic Chemistry

Basics of Reaction Mechanism in Inorganic Chemistry

Author: Jayprakash S Chauhan

Publisher: Educreation Publishing

Published:

Total Pages: 138

ISBN-13:

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The reading journey of this book starts with very important phenomenon in inorganic chemistry known as the Trans effect. The Trans effect then leads to a very fascinating discovery that changed the whole world. That was the discovery of the anti-cancer drug. The story of its invention is really interesting. This will really trigger the minds of students that how inventions are made. This will show you how one invention leads path to the other. This book introduces the work of Nobel Prize winners and scientist who dedicated their whole life for the sake of chemistry. Henry Taube was awarded the Nobel Prize for his work on complexes & outer and inner sphere reaction mechanism. This book introduces his work. Rudolf A. Marcus received Nobel Prize for his work on redox reactions in complexes. This book discusses the basic principles of redox reactions in complexes. Transition metal complexes plays a fundamental role in three important areas. (1) Bioinorganic chemistry (2) Medicinal chemistry (3) Industrial chemistry. The study of the mechanism helps in designing new inorganic materials, new inorganic catalysts, and new inorganic medicines and for understanding the biological processes. This is a simple book discussing basic principles of inorganic reaction mechanisms. Further, we have provided minor information about basic bioinorganic reactions, nuclear reactions and the chain reaction mechanism. The phenomenon such as acid rain has also been discussed. The last chapter classifies the reactions of metal complexes. Hope this book will be useful for science graduates and post graduates and also for the engineering students.