Mechanical Properties and Recrystallization Behavior of Electron-beam-melted Tungsten Compared with Arc-melted Tungsten

Mechanical Properties and Recrystallization Behavior of Electron-beam-melted Tungsten Compared with Arc-melted Tungsten

Author: William D. Klopp

Publisher:

Published: 1966

Total Pages: 42

ISBN-13:

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A study has been conducted of the properties of tungsten fabricated from three ingots consolidated by electron-beam melting. The study included purity as a function of number of melts, recrystallization a d grain growth behavior, low-temperature ductility, and high-temperature tensile and creep strength. The level of most metallic impurities in tungsten decreased with increasing number of electron-beam melts, the reduction being greatest for aluminum, iron, nickel, and silicon. The levels of interstitial impurities generally were not affected by remelting. Resistivity ratios for single crystals machined from ingot slices tended to increase on remelting. The recrystallization rates for worked, electron-beam- melted (EB-melted) tungsten were significantly higher than those observed earlier for arc-melted tungsten. The grain growth rates of EB-melted tungsten were higher than those reported previously for arc-melted tungsten, further reflecting the higher purity of the EB-melted materials. The activation energies for both recrystallization and grain growth in EB-melted tungsten were consistent with expected values assuming grain boundary self-diffusion to be the rate-controlling reaction. The ductile-brittle bend transition temperature for EB-melted tungsten is slightly higher in the worked condition than that reported for arc-melted tungsten. In the recrystallized conditions, the transition temperatures for EB- and arc-melted tungsten are similar. The tensile strength of EB-melted tungsten at 2500 to 4000 F is less than that of arc-melted tungsten. This is partly associated with the large grain size of EB-melted tungsten. However, when compared at the same grain size,


Effect of Alloying on Grain Refinement of Electron-beam-melted Tungsten

Effect of Alloying on Grain Refinement of Electron-beam-melted Tungsten

Author: Walter R. Witzke

Publisher:

Published: 1966

Total Pages: 28

ISBN-13:

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Ingot structures resulting from electron-beam melting of tungsten consist mainly of columnar grains extending the length of the ingot. In order to examine the grain refining capabilities of various elemental and refractory compound additions, small ingots of tungsten containing these additions were prepared by electron-beam melting. Measurements on transverse ingot sections from each melt indicated that all the additions decreased the average grain diameter of the columnar grains typical of electron-beam melted tungsten and that grain refining effectiveness varied with the concentration of the solute S. Losses of the additions during melting were in excess of 90 percent in many cases. The most potent grain refiner was boron. A nominal addition of 0. 5 weight percent decreased the average grain diameter of the columnar grains from 0. 48 to 0. 008 centimeter. The effectiveness of the elemental additions decreased in the following order: boron, yttrium, carbon, hafnium, zirconium, molybdenum, columbium, rhenium, and tantalum. The losses of these elements during melting also decreased in approximately the same order. The elemental additions were generally more effective grain refiners than the refractory compounds. The elements with the smallest distribution coefficients were the most effective grain refiners.


Ultra-High Temperature Materials I

Ultra-High Temperature Materials I

Author: Igor L. Shabalin

Publisher: Springer

Published: 2014-05-16

Total Pages: 800

ISBN-13: 9400775873

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This exhaustive work in three volumes with featuring cross-reference system provides a thorough overview of ultra-high temperature materials – from elements and chemical compounds to alloys and composites. Topics included are physical (crystallographic, thermodynamic, thermo-physical, electrical, optical, physico-mechanical, nuclear) and chemical (solid-state diffusion, interaction with chemical elements and compounds, interaction with gases, vapours and aqueous solutions) properties of the individual physico-chemical phases and multi-phase materials with melting (or sublimation) points over or about 2500 °C. The first volume focuses on carbon (graphite/graphene) and refractory metals (W, Re, Os, Ta, Mo, Nb, Ir). The second and third volumes are dedicated solely to refractory (ceramic) compounds (oxides, nitrides, carbides, borides, silicides) and to the complex materials – refractory alloys, carbon and ceramic composites, respectively. It will be of interest to researchers, engineers, postgraduate, graduate and undergraduate students in various disciplines alike. The reader is provided with the full qualitative and quantitative assessment for the materials, which could be applied in various engineering devices and environmental conditions at ultra-high temperatures, on the basis of the latest updates in the field of physics, chemistry, materials science, nanotechnology and engineering.