Lithium Metal Anodes and Rechargeable Lithium Metal Batteries
Lithium Metal Anodes and Rechargeable Lithium Metal Batteries

Author: Ji-Guang Zhang

Publisher: Springer

Published: 2016-10-06

Total Pages: 206

ISBN-13: 3319440543

DOWNLOAD EBOOK

This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

Rechargeable Lithium Metal Batteries
Rechargeable Lithium Metal Batteries

Author: Christian Julien

Publisher: Springer

Published: 2024-10-07

Total Pages: 0

ISBN-13: 9783031674693

DOWNLOAD EBOOK

This monograph overviews cutting-edge advances in lithium metal batteries, showcasing a significant breakthrough in solving the longstanding issue of lithium dendrites. The key revelation is that this breakthrough paves the way for the development of lithium metal batteries, incorporating lithium metal anodes. The authors illustrate how overcoming the dendrite challenge leads to batteries with higher energy densities, enhanced safety, and further present a special focus on the development of all-solid-state batteries. This book not only highlights the scientific progress in solid-state batteries but also positions them as the next generation of rechargeable batteries. With a focus on bridging the gap from laboratory research to industrial development, the authors explain the profound implications of these advancements. Targeting a diverse audience, including PhD students aspiring to focus on future energy storage research and engineers involved in the transition from laboratory-scale prototypes to large-scale industrial development, this book serves as a comprehensive guide to the forefront of lithium battery technology.

Next Generation Batteries
Next Generation Batteries

Author: Kiyoshi Kanamura

Publisher: Springer Nature

Published: 2021-03-23

Total Pages: 580

ISBN-13: 9813366680

DOWNLOAD EBOOK

In this book, the development of next-generation batteries is introduced. Included are reports of investigations to realize high energy density batteries: Li-air, Li-sulfur, and all solid-state and metal anode (Mg, Al, Zn) batteries. Sulfide and oxide solid electrolytes are also reviewed.A number of relevant aspects of all solid-state batteries with a carbon anode or Li-metal anode are discussed and described: The formation of the cathode; the interface between the cathode (anode) and electrolyte; the discharge and charge mechanisms of the Li-air battery; the electrolyte system for the Li-air battery; and cell construction. The Li-sulfur battery involves a critical problem, namely, the dissolution of intermediates of sulfur during the discharge process. Here, new electrolyte systems for the suppression of intermediate dissolution are discussed. Li-metal batteries with liquid electrolytes also present a significant problem: the dendrite formation of lithium. New separators and electrolytes are introduced to improve the safety and rechargeability of the Li-metal anode. Mg, Al, and Zn metal anodes have been also applied to rechargeable batteries, and in this book, new metal anode batteries are introduced as the generation-after-next batteries.This volume is a summary of ALCA-SPRING projects, which constitute the most extensive research for next-generation batteries in Japan. The work presented in this book is highly informative and useful not only for battery researchers but also for researchers in the fields of electric vehicles and energy storage.

Theoretical Study on Graphite and Lithium Metal as Anode Materials for Next-Generation Rechargeable Batteries
Theoretical Study on Graphite and Lithium Metal as Anode Materials for Next-Generation Rechargeable Batteries

Author: Gabin Yoon

Publisher: Springer Nature

Published: 2022-07-08

Total Pages: 75

ISBN-13: 9811389144

DOWNLOAD EBOOK

This thesis describes in-depth theoretical efforts to understand the reaction mechanism of graphite and lithium metal as anodes for next-generation rechargeable batteries. The first part deals with Na intercalation chemistry in graphite, whose understanding is crucial for utilizing graphite as an anode for Na-ion batteries. The author demonstrates that Na ion intercalation in graphite is thermodynamically unstable because of the unfavorable Na-graphene interaction. To address this issue, the inclusion of screening moieties, such as solvents, is suggested and proven to enable reversible Na-solvent cointercalation in graphite. Furthermore, the author provides the correlation between the intercalation behavior and the properties of solvents, suggesting a general strategy to tailor the electrochemical intercalation chemistry. The second part addresses the Li dendrite growth issue, which is preventing practical application of Li metal anodes. A continuum mechanics study considering various experimental conditions reveals the origins of irregular growth of Li metal. The findings provide crucial clues for developing effective counter strategies to control the Li metal growth, which will advance the application of high-energy-density Li metal anodes.

Lithium Metal Anodes and Rechargeable Lithium Metal Batteries
Lithium Metal Anodes and Rechargeable Lithium Metal Batteries

Author: Ji-Guang Zhang

Publisher: Springer

Published: 2016-10-14

Total Pages: 0

ISBN-13: 9783319440538

DOWNLOAD EBOOK

This book provides comprehensive coverage of Lithium (Li) metal anodes for rechargeable batteries. Li is an ideal anode material for rechargeable batteries due to its extremely high theoretical specific capacity (3860 mAh g-1), low density (0.59 g cm-3), and the lowest negative electrochemical potential (−3.040 V vs. standard hydrogenelectrodes). Unfortunately, uncontrollable dendritic Li growth and limited Coulombic efficiency during Li deposition/stripping inherent in these batteries have prevented their practical applications over the past 40 years. With the emergence of post Liion batteries, safe and efficient operation of Li metal anodes has become an enabling technology which may determine the fate of several promising candidates for the next generation energy storage systems, including rechargeable Li-air batteries, Li-S batteries, and Li metal batteries which utilize intercalation compounds as cathodes. In this work, various factors that affect the morphology and Coulombic efficiency of Li anodes are analyzed. The authors also present the technologies utilized to characterize the morphology of Li deposition and the results obtained by modeling of Li dendrite growth. Finally, recent developments, especially the new approaches that enable safe and efficient operation of Li metal anodes at high current densities are reviewed. The urgent need and perspectives in this field are also discussed. The fundamental understanding and approaches presented in this work will be critical for the applicationof Li metal anodes. The general principles and approaches can also be used in other metal electrodes and general electrochemical deposition of metal films.

Nanomaterials for Lithium-Ion Batteries
Nanomaterials for Lithium-Ion Batteries

Author: Rachid Yazami

Publisher: CRC Press

Published: 2013-10-08

Total Pages: 464

ISBN-13: 9814316407

DOWNLOAD EBOOK

This book covers the most recent advances in the science and technology of nanostructured materials for lithium-ion application. With contributions from renowned scientists and technologists, the chapters discuss state-of-the-art research on nanostructured anode and cathode materials, some already used in commercial batteries and others still in development. They include nanostructured anode materials based on Si, Ge, Sn, and other metals and metal oxides together with cathode materials of olivine, the hexagonal and spinel crystal structures.

Nonaqueous Electrochemistry
Nonaqueous Electrochemistry

Author: Doron Aurbach

Publisher: CRC Press

Published: 1999-07-27

Total Pages: 980

ISBN-13: 9780824741389

DOWNLOAD EBOOK

An examination of applications of electrochemical techniques to many organic and inorganic compounds that are either unstable or insoluble in water. It focuses on the continuing drive toward miniaturization in electronics met by designs for high-energy density batteries (based on nonaqueous systems). It addresses applications to nonaqueous batteries, supercapacitators, highly sensitive reagents, and electroorganic and electroinorganic synthesis.

Lithium metal stabilization for next-generation lithium-based batteries: from fundamental chemistry to advanced characterization and effective protection
Lithium metal stabilization for next-generation lithium-based batteries: from fundamental chemistry to advanced characterization and effective protection

Author: Yu Yan

Publisher: OAE Publishing Inc.

Published: 2023-01-11

Total Pages: 32

ISBN-13:

DOWNLOAD EBOOK

Lithium (Li) metal-based rechargeable batteries hold significant promise to meet the ever-increasing demands for portable electronic devices, electric vehicles and grid-scale energy storage, making them the optimal alternatives for next-generation secondary batteries. Nevertheless, Li metal anodes currently suffer from major drawbacks, including safety concerns, capacity decay and lifespan degradation, which arise from uncontrollable dendrite growth, notorious side reactions and infinite volume variation, thereby limiting their current practical application. Numerous critical endeavors from different perspectives have been dedicated to developing highly stable Li metal anodes. Herein, a comprehensive overview of Li metal anodes regarding fundamental mechanisms, scientific challenges, characterization techniques, theoretical investigations and advanced strategies is systematically presented. First, the basic working principles of Li metal-based batteries are introduced. Specific attention is then paid to the fundamental understanding of and challenges facing Li metal anodes. Accordingly, advanced characterization approaches and theoretical computations are introduced to understand the fundamental mechanisms of dendrite growth and parasitic reactions. Recent key progress in Li anode protection is then comprehensively summarized and categorized to generate an overview of the respective superiorities and limitations of the various strategies. Furthermore, this review concludes the remaining obstacles and potential research directions for inspiring the innovation of Li metal anodes and endeavors to accomplish the practical application of next-generation Li-based batteries.

Functional Materials For Next-generation Rechargeable Batteries
Functional Materials For Next-generation Rechargeable Batteries

Author: Jiangfeng Ni

Publisher: World Scientific

Published: 2021-02-10

Total Pages: 229

ISBN-13: 9811230684

DOWNLOAD EBOOK

Over-consumption of fossil fuels has caused deficiency of limited resources and environmental pollution. Hence, deployment and utilization of renewable energy become an urgent need. The development of next-generation rechargeable batteries that store more energy and last longer has been significantly driven by the utilization of renewable energy.This book starts with principles and fundamentals of lithium rechargeable batteries, followed by their designs and assembly. The book then focuses on the recent progress in the development of advanced functional materials, as both cathode and anode, for next-generation rechargeable batteries such as lithium-sulfur, sodium-ion, and zinc-ion batteries. One of the special features of this book is that both inorganic electrode materials and organic materials are included to meet the requirement of high energy density and high safety of future rechargeable batteries. In addition to traditional non-aqueous rechargeable batteries, detailed information and discussion on aqueous batteries and solid-state batteries are also provided.