Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution

Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution

Author: D. D. Perrin

Publisher: Elsevier

Published: 2016-09-14

Total Pages: 195

ISBN-13: 1483284611

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Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution, Second Edition provides a compilation of tables that summarize relevant data recorded in the literature up to the end of 1980 for the ionization constants of inorganic acids and bases in aqueous solution. This book includes references to acidity functions for strong acids and bases, as well as details about the formation of polynuclear species. This text then explains the details of each column of the tables, wherein column 1 gives the name of the substance and the negative logarithm of the ionization constant and column 2 gives the temperature of measurements in degree Celsius. This book presents as well the method of measurement and the literature references that are listed alphabetically at the end of the tables. Chemists will find this book useful.


Purification of Laboratory Chemicals

Purification of Laboratory Chemicals

Author: W.L.F. Armarego

Publisher: Butterworth-Heinemann

Published: 2017-03-14

Total Pages: 1200

ISBN-13: 0128054565

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Purification of Laboratory Chemicals, Eighth Edition, tabulates methods taken from literature for purifying thousands of individual commercially available chemicals. To help in applying this information, the more common processes currently used for purification in chemical laboratories and new methods are discussed. For dealing with substances not separately listed, a chapter is included setting out the usual methods for purifying specific classes of compounds. - Features empirical formulae inserted for every entry - References all important applications of each substance - Updates and confirms the accuracy of all CAS registry numbers, molecular weights, original reference, and physical data - Provides increased coverage of the latest commercial chemical products, including pharmaceutical chemicals, updated safety and hazard material, and expanded coverage of laboratory and work practices and purification methods


pKa Prediction for Organic Acids and Bases

pKa Prediction for Organic Acids and Bases

Author: D. Perrin

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 154

ISBN-13: 9400958838

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Many chemists and biochemists require to know the ionization constants of organic acids and bases. This is evident from the Science Citation Index which lists The Determination of Ionization Constants by A. Albert and E. P. Serjeant (1971) as one of the most widely quoted books in the chemical literature. Although, ultimately, there is no satisfactory alternative to experimental measurement, it is not always convenient or practicable to make the necessary measure ments and calculations. Moreover, the massive pK. compilations currently available provide values for only a small fraction of known or possible acids or bases. For example, the compilations listed in Section 1. 3 give pK. data for some 6 000--8 000 acids, whereas if the conservative estimate is made that there are one hundred different substituent groups available to substitute in the benzene ring of benzoic acid, approximately five million tri-substituted benzoic acids are theoretically possible. Thus we have long felt that it is useful to consider methods by which a pK. value might be predicted as an interim value to within several tenths of a pH unit using arguments based on linear free energy relationships, by analogy, by extrapolation, by interpolation from existing data, or in some other way. This degree of precision may be adequate for many purposes such as the recording of spectra of pure species (as anion, neutral molecule or cation), for selection of conditions favourable to solvent extraction, and for the interpretation of pH-profiles for organic reactions.


March's Advanced Organic Chemistry

March's Advanced Organic Chemistry

Author: Michael B. Smith

Publisher: John Wiley & Sons

Published: 2007-01-29

Total Pages: 2379

ISBN-13: 0470084944

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The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations


Strategies and Solutions to Advanced Organic Reaction Mechanisms

Strategies and Solutions to Advanced Organic Reaction Mechanisms

Author: Andrei Hent

Publisher: Academic Press

Published: 2019-06-28

Total Pages: 886

ISBN-13: 0128128704

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Strategies and Solutions to Advanced Organic Reaction Mechanisms: A New Perspective on McKillop's Problems builds upon Alexander (Sandy) McKillop's popular text, Solutions to McKillop's Advanced Problems in Organic Reaction Mechanisms, providing a unified methodological approach to dealing with problems of organic reaction mechanism. This unique book outlines the logic, experimental insight and problem-solving strategy approaches available when dealing with problems of organic reaction mechanism. These valuable methods emphasize a structured and widely applicable approach relevant for both students and experts in the field. By using the methods described, advanced students and researchers alike will be able to tackle problems in organic reaction mechanism, from the simple and straight forward to the advanced. - Provides strategic methods for solving advanced mechanistic problems and applies those techniques to the 300 original problems in the first publication - Replaces reliance on memorization with the understanding brought by pattern recognition to new problems - Supplements worked examples with synthesis strategy, green metrics analysis and novel research, where available, to help advanced students and researchers in choosing their next research project


Transparent Conductive Materials

Transparent Conductive Materials

Author: David Levy

Publisher: John Wiley & Sons

Published: 2019-04-29

Total Pages: 390

ISBN-13: 3527342079

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Edited by well-known pioneers in the field, this handbook and ready reference provides a comprehensive overview of transparent conductive materials with a strong application focus. Following an introduction to the materials and recent developments, subsequent chapters discuss the synthesis and characterization as well as the deposition techniques that are commonly used for energy harvesting and light emitting applications. Finally, the book concludes with a look at future technological advances. All-encompassing and up-to-date, this interdisciplinary text runs the gamut from chemistry and materials science to engineering, from academia to industry, and from fundamental challenges to readily available applications.


Bakery Products

Bakery Products

Author: Y. H. Hui

Publisher: John Wiley & Sons

Published: 2008-02-28

Total Pages: 589

ISBN-13: 0470276320

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While thousands of books on baking are in print aimed at food service operators, culinary art instruction, and consumers, relatively few professional publications exist that cover the science and technology of baking. In Bakery Products: Science and Technology, nearly 50 professionals from industry, government, and academia contribute their perspectives on the state of baking today. The latest scientific developments, technological processes, and engineering principles are described as they relate to the essentials of baking. Coverage is extensive and includes: raw materials and ingredients, from wheat flours to sweeteners, yeast, and functional additives; the principles of baking, such as mixing processes, doughmaking, fermentation, and sensory evaluation; manufacturing considerations for bread and other bakery products, including quality control and enzymes; special bakery products, ranging from manufacture of cakes, cookies, muffins, bagels, and pretzels to dietetic bakery products, gluten-free cereal-based products; and specialty bakery items from around the world, including Italian bakery foods. Blending the technical aspects of baking with the freshest scientific research, Bakery Products: Science and Technology has all the finest ingredients to serve the most demanding appetites of food science professionals, researchers, and students.


Handbook of Food Science, Technology, and Engineering - 4 Volume Set

Handbook of Food Science, Technology, and Engineering - 4 Volume Set

Author: Y. H. Hui

Publisher: CRC Press

Published: 2005-12-19

Total Pages: 3539

ISBN-13: 146650787X

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Advances in food science, technology, and engineering are occurring at such a rapid rate that obtaining current, detailed information is challenging at best. While almost everyone engaged in these disciplines has accumulated a vast variety of data over time, an organized, comprehensive resource containing this data would be invaluable to have. The


Bakery Products Science and Technology

Bakery Products Science and Technology

Author: Weibiao Zhou

Publisher: John Wiley & Sons

Published: 2014-06-04

Total Pages: 1374

ISBN-13: 1118792076

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Baking is a process that has been practiced for centuries, and bakery products range in complexity from the simple ingredients of a plain pastry to the numerous components of a cake. While currently there are many books available aimed at food service operators, culinary art instruction and consumers, relatively few professional publications exist that cover the science and technology of baking. In this book, professionals from industry, government and academia contribute their perspectives on the state of industrial baking today. The second edition of this successful and comprehensive overview of bakery science is revised and expanded, featuring chapters on various bread and non-bread products from around the world, as well as nutrition and packaging, processing, quality control, global bread varieties and other popular bakery products. The book is structured to follow the baking process, from the basics, flour and other ingredients, to mixing, proofing and baking. Blending the technical aspects of baking with the latest scientific research, Bakery Products Science and Technology, Second Edition has all the finest ingredients to serve the most demanding appetites of food science professionals, researchers, and students.


Recommended Methods for Purification of Solvents and Tests for Impurities

Recommended Methods for Purification of Solvents and Tests for Impurities

Author: J. F. Coetzee

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 68

ISBN-13: 1483138453

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Recommended Methods for Purification of Solvents and Tests for Impurities is a compilation of recommended procedures for purification of solvents and tests for solvent impurities. Ten solvents are covered: acetonitrile, sulfolane, propylene carbonate, dimethyl sulfoxide, dimethylformamide, hexamethylphosphoramide, pyridine, ethylenediamine, N-methylacetamide, and N-methylpropionamide. This book is comprised of 12 chapters and opens with an introduction to general aspects of impurity effects. The rationale for the selection of solvent is explained, and the relative reactivities of solutes in different solvents are described. The following chapters deal with dipolar aprotic solvents (acetonitrile, sulfolane, propylene carbonate, dimethyl sulfoxide, dimethylformamide, hexamethylphosphoramide, and pyridine) for which impurity effects can be particularly severe, along with their general properties (freezing and boiling temperatures, density, dynamic viscosity, refractive index, dipole moment, relative permittivity, etc.) and the typical chronology of improvements in purification procedures and tests for purity. The final three chapters focus on amphiprotic solvents (ethylenediamine, N-methylacetamide, and N-methylpropionamide). This monograph will be a useful resource for chemists.