Investigations of Transition Metal Rare Earth Alloys
Investigations of Transition Metal Rare Earth Alloys

Author: Franz Lihl

Publisher:

Published: 1969

Total Pages: 82

ISBN-13:

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The phase diagrams of the binary systems samarium-cobalt and gadolinium-cobalt have been established. The phases present have been checked by X-ray diffraction and X-ray fluorescence methods. The ternary system yttrium-iron-cobalt has been investigated in three essential concentration regions corresponding to the compositions Y(Fe, Co)2, Y(Fe, Co)5 and Y2(Fe, Co)17. Only in the case of Y2(Fe, Co)17 complete solid solubility has been found, the other series show only limited ranges of solid solubility. By the amalgam process the preparation of RECo5 and RE(Co, Cu)5 alloys has been studied. The results have been compared with alloys, prepared by high frequency melting. Quenched alloys of the composition RE(Co, Cu)5 show complete solid solubility. By static and dynamic magnetic measurements the permanent magnet properties of RECo5 alloys, prepared by high frequency melting and by the amalgam process have been measured. The influence of different milling methods and of different chemical treatments on the magnetic properties have been determined. Alloys, prepared by the amalgam process are superior to other alloys respective of their permanent magnetic properties. (Author).

Transition Metal and Rare Earth Compounds
Transition Metal and Rare Earth Compounds

Author: Hartmut Yersin

Publisher: Springer

Published: 2003-07-01

Total Pages: 198

ISBN-13: 3540444475

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Transition metal and rare earth compounds are investigated intensively because of important questions concerning fundamental research problems. More recently also their enormous potential for the development of new materials for photophysical and photochemical applications has been explored. Thus, it is important to focus on a deeper understanding of the elctronic energies, transition prohabilities, intermolecular interactions, etc.. This task has been accomplished by leading researchers in the field. They present introductions into, but also detailed reviews of the current state of knowledge of three different subjects.

Transition Metal and Rare Earth Compounds
Transition Metal and Rare Earth Compounds

Author: Hartmut Yersin

Publisher: Springer

Published: 2003-07-01

Total Pages: 201

ISBN-13: 3540444742

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There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4– lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements.

Rare Earths-Transition Metals-Boron Compounds
Rare Earths-Transition Metals-Boron Compounds

Author: Emil Burzo

Publisher: Springer Nature

Published: 2023-06-10

Total Pages: 544

ISBN-13: 3030992454

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This book presents advances in the field of rare-earth (R) – transition metal (M) – boron compounds with extensive references. Since titanium and scandium do not form compounds with rare-earths, the Sc/Ti-M-B series are additionally presented. In each chapter the crystal structures, the complex physical properties as determined from neutron diffraction, magnetic measurements, resonance studies, transport properties and band structure calculations are critical analyzed. The models used in describing the experimental evidence are also presented. Tables with the main properties of the R-M-B compounds are given and representative data are illustrated in figures. In this way, the book provides state-of-the art knowledge and a valuable analysis of up-to-date results in the field. The technical applications, as permanent magnets, thermoelectric and magnetocaloric devices, hydrogen storage are also highlighted along with the authors insights into future directions in the field. The book is of interest for scientists involved in the development of the field as well as those working in the technical uses of rare-earth compounds.

Studies on Al Base Rare Earth Alloys with Potential for Outstanding Permanent Magnet Properties
Studies on Al Base Rare Earth Alloys with Potential for Outstanding Permanent Magnet Properties

Author: Hans Oesterreicher

Publisher:

Published: 1973

Total Pages: 159

ISBN-13:

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Data pertaining to structures, phase relations, and magnetic properties over a wide region in temperature are presented for Al substituted rare earth (R) transition metal (T) alloys of composition R2T17, RT5 and RT2. The mode of this substitution is investigated by x-ray diffraction. Large increases of coercive force are observed on Al substitution, particularly at low temperatures. The temperature dependence of coercive force is investigated. Changes in direction of easy magnetization are described as a function of concentration and temperature in Al substituted PrCo5. The mechanism of magnetization in narrow domain wall rare earth Laves phases is investigated. (Author).

Magnetic Transition Metal. Rare Earth Alloys
Magnetic Transition Metal. Rare Earth Alloys

Author: Franz Lihl

Publisher:

Published: 1967

Total Pages: 36

ISBN-13:

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The present state of the preparation of YCo5 and other RECo5 compounds by means of the amalgam process is reviewed. These compounds are interesting for powder permanent magnets. By an ultrasonic treatment of Y-Co-amalgam, followed by a heat treatment up to 1200C, finely divided YCo5 particles can be obtained, which seem to be well suited for permanent magnets. The system Nd-Mn has been investigated by X-ray diffraction, X-ray fluorescence DTA and micrographs. The intermetallic compounds Nd6Mn23 and NdMn12 are present. A schematic phase diagram is presented. Magnetic measurements on these compounds are given. Nd6Mn23 is ferromagnetic, NdMn12 seems to be antiferromagnetic at low temperatures. The system Tb-Mn has also been investigated and a schematic phase diagram is given. The compounds TbMn2, Tb6Mn23 and TbMn12 are present. Their crystal structure and lattice spacings are given. The phase diagrams of Tb-Hg and Yb-Hg have been investigated by differential thermal analysis. The schematic phase diagrams are presented. These diagrams are the basis for investigations of Tb- and Yb-alloys by means of the amalgam process. (Author).