Influence of Mixture Characteristics on the Oxidative Aging of Asphalt Binders

Influence of Mixture Characteristics on the Oxidative Aging of Asphalt Binders

Author: Nathaniel Evan Morian

Publisher:

Published: 2014

Total Pages: 1802

ISBN-13:

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The objective of this research effort focused on the evaluation of asphalt mixtures with respect to thermal cracking. Preliminary investigations soon indicated that a fundamental evaluation of thermal cracking was highly dependent upon the more complicated understanding of asphalt binder oxidation. The oxidation of asphalt binders within an asphalt mixture were understood to potentially be influenced by the mixture characteristics (i.e. air void levels, binder content, etc.) and aggregate properties (i.e. aggregate absorption, gradation, etc.). Therefore, this study was conducted in order to investigate and quantify the effects different aggregate sources and mixture properties may have on the oxidation and thermal cracking performance of asphalt mixtures. The investigation specifically focused on quantifying the oxidation of the asphalt binder alone and as part of the asphalt mixture when subjected to isothermal oven aging. The oxidation parameters of pan-aged asphalt binders were quantified, according to the standard of practice in the industry. These parameters were then compared to extracted and recovered mixture-aged asphalt binders to examine the influence of the main aggregate and mixture factors on the binder oxidation. The study observed differences between the pan-aged and mixture-aged asphalt binders in terms of oxidation kinetics, rheological measures, and the combined effect represented as the hardening susceptibility. Further evaluation of the binder oxidation based upon the dynamic modulus measures indicated marked influences of the mixture characteristics, the individual component materials, and the interactions between the investigated factors. Differentiation of the experimental factors was further identified by the newly developed low-temperature evaluation method, Uniaxial Thermal Stress and Strain Test (UTSST). The UTSST provides a fundamental approach to characterize the thermo-viscoelastic properties of asphalt mixtures permitting the pragmatic evaluation of changes in the stiffness and overall behavior of mixtures as a function of oxidative aging. Five distinct stages in the UTSST modulus were identified as thermo-viscoelastic properties, which are identified as a function of temperature: viscous softening, viscous-glassy transition, glassy hardening, crack initiation, and fracture stages. Through consideration of the thermo-viscoelastic properties, marked differences in the binder oxidation were noted between the experimental factors. Typically, decreases in the viscous response of the mixtures as well as increases in both the stiffness and brittle behavior were observed with aging. The evaluation method provides definitive measures to monitor multiple aspects of the performance of asphalt mixtures subjected to thermal loading.


Rheological, Chemical and Microstructural Characterization of Asphalt Binders Aged at Different Conditions and Evaluation of the Use of Antioxidants and Copolymers to Retard Aging

Rheological, Chemical and Microstructural Characterization of Asphalt Binders Aged at Different Conditions and Evaluation of the Use of Antioxidants and Copolymers to Retard Aging

Author: Mohammad Solaiman Khan

Publisher:

Published: 2017

Total Pages: 314

ISBN-13:

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The rheological, chemical and microstructural properties of asphalt binders change with oxidative aging which is accelerated at elevated temperatures. Aging stiffens asphalt binders and increases the embrittlement of asphalt mixtures which would lead to fatigue cracking and eventually pavement failure under repetitive traffic loading. This study explored the feasibility of using antioxidant additives and copolymers with antioxidant agents to retard oxidative aging of asphalt binders. The performance of the additives was evaluated at the binder and mastic levels. The laboratory experiments included two unmodified binders, various antioxidant additives and copolymers, and three aggregate types. The fatigue characteristics of asphalt binders and mastic were determined before and after aging and an aging index was defined to evaluate the effect of the additives on aging. The results demonstrated that certain antioxidants and copolymers such as Redicote AP, Solprene, and Calprene may retard the aging and improve the rheological properties of the asphalt binders. In addition, the results of mastic testing confirmed the favorable effect of certain antioxidants on improving the resistance to fatigue cracking. Furthermore, the type of aggregate was found to influence the rate of aging of asphalt mixtures. Based on the rheological and fracture test results on asphalt binders and mastic, the effect of antioxidants was further investigated and validated at spectroscopic, chemical and microstructural level using Fourier-transform infrared spectroscopy (FTIR), Gel-permeation chromatography (GPC) and Atomic Force Microscopy (AFM), respectively. The spectroscopic analysis with FTIR supported the efficacy of the additives in retarding aging by reducing the carbonyl growth in aged binders. The chemical analysis with GPC confirmed that both Redicote and Solprene were capable of reducing the large molecular size fraction in binders subjected to long-term aging. The image analysis with AFM provided insight on the spatial distribution, surface roughness parameters and micromechanical properties (i.e., adhesion, stiffness) of various phases and the effect of aging on the micro-rheology of antioxidant-modified binders. The last part of this study examined the effect of aging on the viscoelastic response of asphalt mixture using the Prony series representation and a newly developed parameter called aging state variable 'A'. The dynamic modulus test data was used for the analysis. The aging state variable 'A' was found to capture the effect of aging temperature and duration of aging on the viscoelastic properties of asphalt mixtures.


Physical Properties of Asphalt Cement Binders

Physical Properties of Asphalt Cement Binders

Author: John C. Hardin

Publisher: ASTM International

Published: 1995

Total Pages: 237

ISBN-13: 0803119887

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A dozen papers from a December 1993 symposium in Dallas/Fort Worth, Texas. Among the topics are why the new proposed rheological properties of asphalt binders are required and how they compare to conventional properties, the development and use of the SHRP direct tension specification test, oxidatio


Asphalt Paving Technology 2015

Asphalt Paving Technology 2015

Author: Eugene Skok

Publisher: DEStech Publications, Inc

Published: 2016-02-16

Total Pages: 768

ISBN-13: 160595294X

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Recent research on asphalt binder aging and rejuvenatorsKey data on asphalt performance and formulationsUpdates on tests and specificationsFully-searchable text on CD-ROM (included) This series volume comprises research papers and technical reports developed within the U.S.-based Association of Asphalt Paving Technologists. The book is divided into sessions focused on technology, specifications, cold recycling of RAP, and rejuvenators, with special emphasis on aging and on how rejuvenators are modeled, formulated and used to improve asphalt binders and prevent cracking. The CD-ROM displays figures and illustrations in articles in full color along with a title screen and main menu screen. Each user can link to all papers from the Table of Contents and Author Index and also link to papers and front matter by using the global bookmarks which allow navigation of the entire CD-ROM from every article. Search features on the CD-ROM can be by full text including all key words, article title, author name, and session title. The CD-ROM has Autorun feature for Windows 2000 with Service Pack 4 or higher products along with the program for Adobe Acrobat Reader with Search 11.0. One year of technical support is included with your purchase of this product.


Introduction to Unmanned Aircraft Systems, Second Edition

Introduction to Unmanned Aircraft Systems, Second Edition

Author: Douglas M. Marshall

Publisher: CRC Press

Published: 2015-10-26

Total Pages: 1944

ISBN-13: 113802693X

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The proliferation of technological capability, miniaturization, and demand for aerial intelligence is pushing unmanned aerial systems (UAS) into the realm of a multi-billion dollar industry. This book surveys the UAS landscape from history to future applications. It discusses commercial applications, integration into the national airspace system (NAS), System function, operational procedures, safety concerns, and a host of other relevant topics. The book is dynamic and well-illustrated with separate sections for terminology and web- based resources for further information.