This book provides a comprehensive overview of reaction processes in the Earth's crust and on its surface, both in the laboratory and in the field. A clear exposition of the underlying equations and calculation techniques is balanced by a large number of fully worked examples. The book uses The Geochemist's Workbench® modeling software, developed by the author and already installed at over 1000 universities and research facilities worldwide. Since publication of the first edition, the field of reaction modeling has continued to grow and find increasingly broad application. In particular, the description of microbial activity, surface chemistry, and redox chemistry within reaction models has become broader and more rigorous. These areas are covered in detail in this new edition, which was originally published in 2007. This text is written for graduate students and academic researchers in the fields of geochemistry, environmental engineering, contaminant hydrology, geomicrobiology, and numerical modeling.
This book provides a comprehensive overview of reaction processes in the Earth's crust and on its surface, both in the laboratory and in the field. A clear exposition of the underlying equations and calculation techniques is balanced by a large number of fully worked examples. The book uses The Geochemist's Workbench® modeling software, developed by the author and already installed at over 1000 universities and research facilities worldwide. Since publication of the first edition, the field of reaction modeling has continued to grow and find increasingly broad application. In particular, the description of microbial activity, surface chemistry, and redox chemistry within reaction models has become broader and more rigorous. These areas are covered in detail in this new edition, which was originally published in 2007. This text is written for graduate students and academic researchers in the fields of geochemistry, environmental engineering, contaminant hydrology, geomicrobiology, and numerical modeling.
An indispensable primer and reference textbook, the third edition of Geochemical and Biogeochemical Reaction Modeling carries the reader from the field's origins and theoretical underpinnings through to a collection of fully worked examples. A clear exposition of the underlying equations and calculation techniques is balanced by real-world example calculations. The book depicts geochemical reaction modeling as a vibrant field of study applicable to a wide spectrum of issues of scientific, practical, and societal concern. The new edition offers a thorough description of surface complexation modeling, including two- and three-layer methods; broader treatment of kinetic rate laws; the effect of stagnant zones on transport; and techniques for determining gas partial pressures. This handbook demystifies and makes broadly accessible an elegant technique for portraying chemical processes in the geosphere. It will again prove to be invaluable for geochemists, environmental scientists and engineers, aqueous and surface chemists, microbiologists, university teachers, and government regulators.
Geochemical reaction modeling plays an increasingly vital role in several areas of geoscience, from environmental geochemistry and petroleum geology to the study of geothermal and hydrothermal fluids. This book provides an up-to-date overview of the use of numerical methods to model reaction processes in the Earth's crust and on its surface. Early chapters develop the theoretical foundations of the field, derive a set of governing equations, and show how numerical methods can be used to solve these equations. Other chapters discuss the distribution of species in natural waters; methods for computing activity coefficients in dilute solutions and in brines; the complexation of ions into mineral surfaces; the kinetics of precipitation and dissolution reactions; and the fractionation of stable isotopes. Later chapters provide a large number of fully worked calculation examples and case studies demonstrating the modeling techniques that can be applied to scientific and practical problems. Students in a variety of specialties from low-temperature geochemistry to groundwater hydrology will benefit from the wealth of information and practical applications this book has to offer.
Elements move through Earth's critical zone along interconnected pathways that are strongly influenced by fluctuations in water and energy. The biogeochemical cycling of elements is inextricably linked to changes in climate and ecological disturbances, both natural and man-made. Biogeochemical Cycles: Ecological Drivers and Environmental Impact examines the influences and effects of biogeochemical elemental cycles in different ecosystems in the critical zone. Volume highlights include: Impact of global change on the biogeochemical functioning of diverse ecosystems Biological drivers of soil, rock, and mineral weathering Natural elemental sources for improving sustainability of ecosystems Links between natural ecosystems and managed agricultural systems Non-carbon elemental cycles affected by climate change Subsystems particularly vulnerable to global change The American Geophysical Union promotes discovery in Earth and space science for the benefit of humanity. Its publications disseminate scientific knowledge and provide resources for researchers, students, and professionals. Find out more about this book from this Q&A with the Author. Book Review: http://www.elementsmagazine.org/archives/e16_6/e16_6_dep_bookreview.pdf
Geochemical kinetics as a topic is now of importance to a wide range of geochemists in academia, industry, and government, and all geochemists need a rudimentary knowledge of the field. This book summarizes the fundamentals of geochemical kinetics with examples drawn especially from mineral dissolution and precipitation. It also encompasses discussion of high temperature processes and global geochemical cycle modeling. Analysis of textures of rocks, sediments, and mineral surfaces are incorporated throughout and provide a sub-theme of the book.
Environmental and Low-Temperature Geochemistry presents conceptual and quantitative principles of geochemistry in order to foster understanding of natural processes at and near the earth’s surface, as well as anthropogenic impacts on the natural environment. It provides the reader with the essentials of concentration, speciation and reactivity of elements in soils, waters, sediments and air, drawing attention to both thermodynamic and kinetic controls. Specific features include: • An introductory chapter that reviews basic chemical principles applied to environmental and low-temperature geochemistry • Explanation and analysis of the importance of minerals in the environment • Principles of aqueous geochemistry • Organic compounds in the environment • The role of microbes in processes such as biomineralization, elemental speciation and reduction-oxidation reactions • Thorough coverage of the fundamentals of important geochemical cycles (C, N, P, S) • Atmospheric chemistry • Soil geochemistry • The roles of stable isotopes in environmental analysis • Radioactive and radiogenic isotopes as environmental tracers and environmental contaminants • Principles and examples of instrumental analysis in environmental geochemistry The text concludes with a case study of surface water and groundwater contamination that includes interactions and reactions of naturally-derived inorganic substances and introduced organic compounds (fuels and solvents), and illustrates the importance of interdisciplinary analysis in environmental geochemistry. Readership: Advanced undergraduate and graduate students studying environmental/low T geochemistry as part of an earth science, environmental science or related program. Additional resources for this book can be found at: www.wiley.com/go/ryan/geochemistry.
Ground water reactive transport models are useful to assess and quantify contaminant precipitation, absorption and migration in subsurface media. Many ground water reactive transport models available today are characterized by varying complexities, strengths, and weaknesses. Selecting accurate, efficient models can be a challenging task. This book addresses the needs, issues and challenges relevant to selecting a ground water reactive transport model to evaluate natural attenuation and alternative remediation schemes. It should serve as a handy guide for water resource managers seeking to achieve economically feasible results.