Metallo-Supramolecular Polymers
Metallo-Supramolecular Polymers

Author: Masayoshi Higuchi

Publisher: Springer Nature

Published: 2019-11-12

Total Pages: 92

ISBN-13: 4431568913

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This book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.

Supramolecular Polymer Networks and Gels
Supramolecular Polymer Networks and Gels

Author: Sebastian Seiffert

Publisher: Springer

Published: 2015-04-06

Total Pages: 293

ISBN-13: 3319154044

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The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science. The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics. Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist. Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned. Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students.

Supramolecular Chemistry in Water
Supramolecular Chemistry in Water

Author: Stefan Kubik

Publisher: John Wiley & Sons

Published: 2019-09-03

Total Pages: 586

ISBN-13: 3527344675

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Provides deep insight into the concepts and recent developments in the area of supramolecular chemistry in water Written by experts in their respective field, this comprehensive reference covers various aspects of supramolecular chemistry in water?from fundamental aspects to applications. It provides readers with a basic introduction to the current understanding of the properties of water and how they influence molecular recognition, and examines the different receptor types available in water and the types of substrates that can be bound. It also looks at areas to where they can be applied, such as materials, optical sensing, medicinal imaging, and catalysis. Supramolecular Chemistry in Water offers five major sections that address important topics like water properties, molecular recognition, association and aggregation phenomena, optical detection and imaging, and supramolecular catalysis. It covers chemistry and physical chemistry of water; water-mediated molecular recognition; peptide and protein receptors; nucleotide receptors; carbohydrate receptors; and ion receptors. The book also teaches readers all about coordination compounds; self-assembled polymers and gels; foldamers; vesicles and micelles; and surface-modified nanoparticles. In addition, it provides in-depth information on indicators and optical probes, as well as probes for medical imaging. -Covers, in a timely manner, an emerging area in chemistry that is growing more important every day -Addresses topics such as molecular recognition, aggregation, catalysis, and more -Offers comprehensive coverage of everything from fundamental aspects of supramolecular chemistry in water to its applications -Edited by one of the leading international scientists in the field Supramolecular Chemistry in Water is a one-stop-resource for all polymer chemists, catalytic chemists, biochemists, water chemists, and physical chemists involved in this growing area of research.

Supramolecular Polymers and Assemblies
Supramolecular Polymers and Assemblies

Author: Ulrich S. Schubert

Publisher: John Wiley & Sons

Published: 2021-06-28

Total Pages: 544

ISBN-13: 3527333568

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Explore modern characterization methods and new applications in this modern overview of supramolecular polymer chemistry Supramolecular Polymers and Assemblies: From Synthesis to Properties and Applications delivers a superlative summary and description of general concepts and definitions in the field. The book offers informative and accessible treatments of crucial concepts like metal-containing compounds, hydrogen bonding, ionic interactions, pi-pi stacking, and more. Characterization remains a primary focus of the book throughout, making it extremely useful for practitioners in the field. Emphasis is also placed on metallo-supramolecular polymers and materials which have found applications in areas like smart or intelligent materials and systems with special photochemical and photophysical properties, like LEDs and solar cells. Applications, including self-healing materials, opto-electronics, sensing, and catalysis are all discussed as well. The book details many of the exciting developments in the field of supramolecular chemistry that have occurred since the 1987 Nobel Prize was awarded to pioneers in this rapidly developing field. Readers will also benefit from the inclusion of: A thorough introduction to supramolecular assemblies based on ionic interactions Explorations of supramolecular polymers based on hydrogen-bonding interactions, metal-to-ligand interactions, p-Electronic interactions, crown-ether recognition, cucurbiturils, and host-guest chemistry of calixarenes A discussion of cyclodextrins in the field of supramolecular polymers Examinations of supramolecular polymers based on the host-guest chemistry of pillarenes, and those formed by orthogonal non-covalent interactions A treatment of the characterization of supramolecular polymers Supramolecular Polymers and Assemblies: From Synthesis to Properties and Applications will earn a place in the libraries of researchers and practitioners of the material science, as well as polymer chemists seeding a one-stop reference for supramolecular polymers.

Supramolecular Gels
Supramolecular Gels

Author: Tifeng Jiao

Publisher: John Wiley & Sons

Published: 2021-08-23

Total Pages: 274

ISBN-13: 3527345116

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Supramolecular Gels Discover a current and authoritative overview of the cutting-edge in supramolecular gels from a leading voice in the field A promising new class of materials shows potential and is receiving increasing attention as an intelligent material for multifunctional systems. In a work that is sure to be of great interest to a wide variety of researchers, chemists, and engineers, Supramolecular Gels: Materials and Emerging Applications delivers an application-oriented and focused book exploring the most recent applications of supramolecular gels. This interdisciplinary book presents the underlying fundamentals of supramolecular gels before discussing their assembly mechanisms and structures. It also introduces different material systems, including composite supramolecular gels, organogels, hydrogels, self-healing, and graphene-based supramolecular gels. The book discusses current and emerging applications of these materials in devices like sensors and actuators, biomedical tools, and environmental applications. The distinguished author also offers valuable insights with respect to the design and character of brand-new versatile soft materials. Readers will also benefit from the inclusion of: A thorough introduction to the fundamentals of supramolecular gels, including their formation, classification, self-assembly, and mechanisms An exploration of supramolecular chirality and regulation in gel structures, as well as self-assembly and environmental applications of composite supramolecular gels Practical discussions of fluorescent organogels and hydrogels and their applications in analyte sensing An examination of self-healing and graphene-based supramolecular gels, and supramolecular gels for sensors and actuators Perfect for materials scientists, organic chemists, biochemists, catalytic chemists, and environmental chemists, Supramolecular Gels: Materials and Emerging Applications will also earn a place in the libraries of sensor developers and other professionals seeking a one-stop reference for this rapidly developing category of intelligent materials.

Out-of-Equilibrium (Supra)molecular Systems and Materials
Out-of-Equilibrium (Supra)molecular Systems and Materials

Author: Nicolas Giuseppone

Publisher: John Wiley & Sons

Published: 2021-03-30

Total Pages: 448

ISBN-13: 3527821988

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A must-have resource that covers everything from out-of-equilibrium chemical systems and materials to dissipative self-assemblies Out-of-Equilibrium Supramolecular Systems and Materials presents a comprehensive overview of the synthetic approaches that use supramolecular bonds in various out-of-thermodynamic equilibrium situations. With contributions from noted experts on the topic, the text contains information on the design of dissipative self-assemblies that maintain their structures when fueled by an external source of energy. The contributors also examine molecules and nanoscale objects and materials that can produce mechanical work based on molecular machines. Additionally, the book explores non-equilibrium supramolecular polymers that can be trapped in kinetically stable states, as well as out-of-equilibrium chemical systems and oscillators that are important to understand the emergence of complex behaviors and, in particular, the origin of life. This important book: Offers comprehensive coverage of fields from design of dissipative self-assemblies to non-equilibrium supramolecular polymers Presents information on a highly emerging and interdisciplinary topic Includes contributions from internationally renowned scientists Written for chemists, physical chemists, biochemists, material scientists, Out-of-Equilibrium Supramolecular Systems and Materials is an indispensable resource written by top scientists in the field.

Chemistry of Polymeric Metal Chelates
Chemistry of Polymeric Metal Chelates

Author: Gulzhian I. Dzhardimalieva

Publisher: Springer

Published: 2018-02-13

Total Pages: 1036

ISBN-13: 3319560247

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This book deals with the chemistry of polymeric metal chelates. The main results and the production and chemical structure of polymers with chelate units as well as the specificity of metal complex binding of different structure are presented here. This book also reveals the transformations which components undergo in the course of chelation. Special attention is paid not only to synthetic but also to natural (including living) systems. The usage of polymeric metal chelates and their development are examined. The related research was performed for chelates with chain structure. This book is useful to researchers being active in synthesis and design of macromolecular metal chelates

Gel Chemistry
Gel Chemistry

Author: Jianyong Zhang

Publisher: Springer

Published: 2018-01-10

Total Pages: 217

ISBN-13: 981106881X

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This book covers various molecular, metal-organic, dynamic covalent, polymer and other gels, focusing on their driving interactions, structures and properties. It consists of six chapters demonstrating interesting examples of these gels, classified by the type of driving interaction, and also discusses the effect of these interactions on the gels’ structures and properties. The book offers an interesting and useful guide for a broad readership in various fields of chemical and materials science.

Functional Metallosupramolecular Materials
Functional Metallosupramolecular Materials

Author: John George Hardy

Publisher: Royal Society of Chemistry

Published: 2015-07-13

Total Pages: 417

ISBN-13: 1782622675

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There is great interest in metallosupramolecular materials because of their use in magnetic, photonic and electronic materials. Functional Metallosupramolecular Materials focuses on the applications of these materials covering the chemistry underlying the synthesis of a variety of ligands to coordinate various metal ions and the generation of 2D and 3D materials based on these constructs. The book starts by looking at different metallosupramolecular systems including naturally occurring functional metallosupramolecular materials; DNA-based metallosupramolecular materials; metallopolymers; metallogels as well as functional materials based on MOFs. Subsequent chapters then systematically cover the different applications such as molecular computation, spin-crossover, light harvesting and as photocatalysts for the production of solar fuels. The book provides an overview of functional metallosupramolecular materials that will be of interest to graduate students, academics and industrial chemists interested in supramolecular chemistry, materials science and the materials applications.

Porous Polymers
Porous Polymers

Author: Michael S. Silverstein

Publisher: John Wiley & Sons

Published: 2011-02-14

Total Pages: 480

ISBN-13: 0470934743

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This book gathers the various aspects of the porous polymer field into one volume. It not only presents a fundamental description of the field, but also describes the state of the art for such materials and provides a glimpse into the future. Emphasizing a different aspect of the ongoing research and development in porous polymers, the book is divided into three sections: Synthesis, Characterization, and Applications. The first part of each chapter presents the basic scientific and engineering principles underlying the topic, while the second part presents the state of the art results based on those principles. In this fashion, the book connects and integrates topics from seemingly disparate fields, each of which embodies different aspects inherent in the diverse field of porous polymeric materials.