Light-Active Functional Organic Materials

Light-Active Functional Organic Materials

Author: Hiroko Yamada

Publisher: CRC Press

Published: 2019-05-22

Total Pages: 167

ISBN-13: 0429827989

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Inspired by naturally occurring light-active molecular systems such as photosynthesis, scientists have long devoted their efforts to understanding how light and molecules interact. Based on a raft of knowledge on light absorption, energy migration and electron transfer, fluorescence and phosphorescence, and various photochemical reactions, light can now be utilized for energy conversion, information storage, medical applications, and development of next-generation photofunctional materials that cannot be obtained via conventional organic synthesis. This book overviews some of the cutting-edge p-conjugated molecular and polymer materials for organic photovoltaics, artificial photosynthesis, and organic light-emitting devices. It gives insights into the interactions between light and molecules and discusses sophisticated molecular designs, self-assembly and self-organization strategies, and state-of-the-art unconventional analytical methods.


Functional Materials from Carbon, Inorganic, and Organic Sources

Functional Materials from Carbon, Inorganic, and Organic Sources

Author: Sanjay J. Dhoble

Publisher: Woodhead Publishing

Published: 2022-11-23

Total Pages: 618

ISBN-13: 0323909299

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Functional Materials from Carbon, Inorganic and Organic Sources: Methods and Advances describes the basic principles, mechanisms and theoretical background of functional materials. Sections cover Carbon-based functional materials, Inorganic functional materials for renewable and sustainable energy applications, and Organic and biological based functional materials. Applications such as energy storage and conversion, electronic and photonics devices, and in medicine are also explored. Sections dive into photovoltaic devices, light emitting devices, energy storage materials and quantum dot devices, solar cell fundamentals and devices, perovskite materials and ceramic thin films. Final sections emphasize green approaches to synthesis in semiconductor nanoparticles, quinolone complexes, biomaterials and biopolymers. - Introduces the reader to a wide range of the most relevant functional materials, including carbon-based materials, inorganic materials for energy applications, and organic and biological based materials - Reviews the synthesis and characterization methods used to create, optimize and analyze functional materials properties - Discusses the use of functional materials to enable emerging technologies, along with remaining barriers to commercial adoption and opportunities


Photoelectrochemical Engineering for Solar Harvesting

Photoelectrochemical Engineering for Solar Harvesting

Author: Samrana Kazim

Publisher: Elsevier

Published: 2024-06-24

Total Pages: 504

ISBN-13: 0323954952

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Photoelectrochemical Engineering for Solar Harvesting provides an up-to-date appraisal of the photon engineering of innovative catalysts for solar energy harvesting.Sunlight-driven fuel synthesis is the most sustainable and potentially economical option for producing energy vectors through water splitting. Thus this book focuses on the design of photocatalysts and water oxidation catalysts, as artificial photosynthesis and hydrogen fuel production via water oxidation (in place of fossil fuels) are two promising approaches towards renewable energy.The book critically analyzes the overall progress, potential challenges, and the possibility of industrialization of new catalysts in the near future. The primary emphasis of the discussion is on experimental approaches from materials synthesis to device applications, however, there will also be some introduction to relevant photochemistry concepts.Photoelectrochemical Engineering for Solar Harvesting is suitable for materials scientists and chemists who through the use of photonics are in continuous pursuit of improving the efficiencies of different devices used to capture solar energy for the generation of sustainable fuel. - Covers design of innovative energy materials such as photocatalysts and water oxidation catalysts for solar energy harvesting - Reviews briefly computational and theoretical approaches before providing comprehensive overview of experimental directions - Provides information to guide photon and photoelectrochemical engineering of catalysts for solar application


Dyes and Photoactive Molecules in Microporous Systems

Dyes and Photoactive Molecules in Microporous Systems

Author: Virginia Martínez-Martínez

Publisher: Springer Nature

Published: 2020-12-15

Total Pages: 411

ISBN-13: 303056634X

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This book provides an overview of the design, synthesis, and characterization of different photoactive hybrid organic-inorganic materials, based on the combination of mainly organic molecules and inorganic nanostructures, tackling their uses in different scientific fields from photonics to biomedicine. There are many examples extensively describing how the confinement of organic compounds (i.e. chromophores, photochromic molecules or photoreactants), or other photoactive compounds (i.e.metal clusters) into several microporous systems can modulate the photophysical properties and photochemical reactions leading to interesting applications. Among (ordered)-hosts, different systems of diverse nature are widely used, such as the, the 1D- or 3D- channels of zeolitic frameworks, interlayer space of 2D-clays, the organic nanospace of curcubituril and cyclodextrins or the organo-inorganic porous crystalline MOFs systems. This volume highlights the advances of these photoactive materials and aims to be an inspiration for researchers working in materials science and photochemistry, including chemists, material engineers, physicists, biologists, and medical researchers.


Photofunctional Rare Earth Hybrid Materials

Photofunctional Rare Earth Hybrid Materials

Author: Bing Yan

Publisher: Springer

Published: 2017-08-28

Total Pages: 266

ISBN-13: 9811029571

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This book presents the main research advances in the field of photofunctional rare earth hybrid materials. The first chapter discusses the fundamental principles, ranging from rare earth, rare earth luminescence, luminescent rare earth compounds and photofunctional rare earth hybrid materials. The main body of the book consists of six chapters exploring different kinds of photofunctional hybrid materials, such as hybrids based on organically modified silica; organically modified mesoporous silica; functionalized microporous zeolite and metal-organic frameworks; polymer or polymer/silica composite; and multi-component assembly of hybrids. It also includes a chapter introducing the photofunctional application of these hybrid materials. It is a valuable resource for a wide readership in various fields of rare earth chemistry, chemical science and materials science.


Rare Earth Metal-Organic Framework Hybrid Materials for Luminescence Responsive Chemical Sensors

Rare Earth Metal-Organic Framework Hybrid Materials for Luminescence Responsive Chemical Sensors

Author: Bing Yan

Publisher: Woodhead Publishing

Published: 2022-06-01

Total Pages: 538

ISBN-13: 0323914306

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Rare Earth Metal-Organic Framework Hybrid Materials for Luminescence Responsive Chemical Sensors primarily focuses on rare earth functionalized metal-organic framework (MOF) hybrid materials for sensing applications. Sections cover an introduction to the field and key concepts like luminescence, rare earth ion luminescence and luminescence response for chemical sensing. Other section emphasize the luminescence response mode and sensing mechanisms of these important materials, including single mode and dual mode sensing, as well as chemical sensing mechanisms. Final sections outline different kinds of sensing analytes by rare earth functionalized MOFs hybrids and delve into emerging application. This book is suitable for materials scientists and engineers, materials chemists, chemists and chemical engineers. In addition, the material is appropriate for those working in academia and R&D in industry. - Authored by one of the world's leading experts on rare earth metal-organic framework hybrid materials - Introduces advanced concepts in luminescence and sensing mechanisms of metal-organic framework hybrid materials - Discusses the use of luminescence responsive chemical sensors (based on metal organic frameworks) for logic gate or imaging applications


Alkyne‐Based Nanostructures on Silver Substrates

Alkyne‐Based Nanostructures on Silver Substrates

Author: Raphael Hellwig

Publisher: Springer

Published: 2018-11-02

Total Pages: 132

ISBN-13: 3030009971

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Acetylenic precursors are important reactants for creating carbon-based architectures via linkage reactions. While their capability of forming intermolecular bonds is well investigated in solution, very few systematic studies have been carried out to create alkyne-based nanostructures on metal substrates under ultra-high vacuum conditions. Synthesizing extended and regular carbon scaffolds requires a detailed knowledge of alkyne chemistry in order to control reaction pathways and limit unwanted side reactions. Using the bottom-up approach on metal surfaces, the authors establish protocols to fabricate regular architectures built up by the on-surface formation of selective organometallic and C-C bonds with thoughtfully designed alkyne-functionalized monomers. The structural and functional properties of the resulting organometallic and covalent nanostructures are characterized by means of scanning tunneling microscopy. The results open up new perspectives in the fields of heterogeneous catalysis and the on-surface synthesis of functional interfaces under mild reaction conditions.