Enzymatic Polymerization towards Green Polymer Chemistry

Enzymatic Polymerization towards Green Polymer Chemistry

Author: Shiro Kobayashi

Publisher: Springer

Published: 2019-04-04

Total Pages: 391

ISBN-13: 9811338132

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This book comprehensively covers researches on enzymatic polymerization and related enzymatic approaches to produce well-defined polymers, which is valuable and promising for conducting green polymer chemistry. It consists of twelve chapters, including the following topics: The three classes of enzymes, oxidoreductases, transferases and hydrolases, have been employed as catalysts for enzymatic polymerization and modification; Well-defined polysaccharides are produced by enzymatic polymerization catalyzed by hydrolases and transferases; Hydrolase-catalyzed polycondensation and ring-opening polymerization are disclosed to produce a variety of polyesters; Polyesters are synthesized by in-vivo acyltransferase catalysis produced by microorganisms; Enzymatic polymerization catalyzed by appropriate enzymes also produces polypeptides and other polymers; Poly(aromatic)s are obtained by enzymatic polymerization catalyzed by oxidoreductases and their model complexes; Such enzymes also induce oxidative polymerization of vinyl monomers; Enzymatic modification of polymers is achieved to produce functionalized polymeric materials; The enzymatic polymerization is a green process with non-toxic catalysts, high catalyst efficiency, green solvents and renewable starting materials, and minimal by-products; Moreover, renewable resources like biomass are potentially employed as a starting substrate, producing useful polymeric materials. This book is not only educative to young polymer chemists like graduate students but also suggestive to industrial researchers, showing the importance of the future direction of polymer synthesis for maintaining a sustainable society.


Enzymatic Polymerization Towards Green Polymer Chemistry

Enzymatic Polymerization Towards Green Polymer Chemistry

Author: Shiro Kobayashi

Publisher:

Published: 2019

Total Pages: 389

ISBN-13: 9789811338144

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This book comprehensively covers researches on enzymatic polymerization and related enzymatic approaches to produce well-defined polymers, which is valuable and promising for conducting green polymer chemistry. It consists of twelve chapters, including the following topics: The three classes of enzymes, oxidoreductases, transferases and hydrolases, have been employed as catalysts for enzymatic polymerization and modification; Well-defined polysaccharides are produced by enzymatic polymerization catalyzed by hydrolases and transferases; Hydrolase-catalyzed polycondensation and ring-opening polymerization are disclosed to produce a variety of polyesters; Polyesters are synthesized by in-vivo acyltransferase catalysis produced by microorganisms; Enzymatic polymerization catalyzed by appropriate enzymes also produces polypeptides and other polymers; Poly(aromatic)s are obtained by enzymatic polymerization catalyzed by oxidoreductases and their model complexes; Such enzymes also induce oxidative polymerization of vinyl monomers; Enzymatic modification of polymers is achieved to produce functionalized polymeric materials; The enzymatic polymerization is a green process with non-toxic catalysts, high catalyst efficiency, green solvents and renewable starting materials, and minimal by-products; Moreover, renewable resources like biomass are potentially employed as a starting substrate, producing useful polymeric materials. This book is not only educative to young polymer chemists like graduate students but also suggestive to industrial researchers, showing the importance of the future direction of polymer synthesis for maintaining a sustainable society.


Green Polymer Chemistry

Green Polymer Chemistry

Author: H. N. Cheng

Publisher: ACS Symposium

Published: 2015

Total Pages: 0

ISBN-13: 9780841230651

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Green chemistry is the design of chemical products and processes that reduce or eliminate the use or generation of hazardous substances. Green polymer chemistry is an extension of green chemistry to polymer science and engineering. Developments in this area have been stimulated by health and environmental concerns, interest in sustainability, desire to decrease the dependence on petroleum, and opportunities to design and produce "green" products and processes. Major advances include new uses of biobased feedstock, green reactions, green processing methodologies, and green polymeric products. A current feature of green polymer chemistry is that it is both global and multidisciplinary. Thus, publications in this field are spread out over different journals in different countries. Moreover, a successful research effort may involve collaborations of people in various disciplines, such as organic chemistry, polymer chemistry, material science, chemical engineering, biochemistry, molecular biology, microbiology, enzymology, toxicology, environmental science, and analytical chemistry. This book combines the major interdisciplinary research in this field and is targeted for scientists, engineers, and students, who are involved or interested in green polymer chemistry. These may include chemists, biochemists, material scientists, chemical engineers, microbiologists, molecular biologists, enzymologists, toxicologists, environmental scientists, and analytical chemists. It can be a textbook for a course on green chemistry and also a reference book for people who need information on specific topics involving biocatalysis and biobased materials.


Green Chemistry

Green Chemistry

Author: Mark Anthony Benvenuto

Publisher: Walter de Gruyter GmbH & Co KG

Published: 2023-10-23

Total Pages: 116

ISBN-13: 3110745658

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The "greening" of industry processes—making them more sustainable—is a popular and often lucrative trend. The volume covers green chemical processing in the context of climate change. The impact of catalysis, remediation of pollutants, and sustainable practices in process development on climate change are themes addressed in this volume. We also explore the adoption of sustainability and environmental justice in educational curricula. The American Chemical Society’s 12 Principles of Green Chemistry are woven throughout this text as well as throughout the series to which this book belongs.


Enzymatic Polymerizations

Enzymatic Polymerizations

Author:

Publisher: Academic Press

Published: 2019-10-14

Total Pages: 382

ISBN-13: 0128170964

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Enzymatic Polymerizations, Volume 627 in the Methods in Enzymology series, continues the legacy of this premier serial with quality chapters authored by leaders in the field. - Provides the authority and expertise of leading contributors from an international board of authors - Presents the latest release in the Methods in Enzymology series - Includes the latest information on Enzymatic Polymerizations


Modification of Polymers

Modification of Polymers

Author: Charles E. Carraher

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 414

ISBN-13: 1461337488

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The sheer volume of topics which could have been included under our general title prompted us to make some rather arbitrary decisions about content. Modification by irradiation is not included because the activity in this area is being treated elsewhere. We have chosen to emphasize chemical routes to modification and have striven to pre sent as balanced a representation of current activity as time and page count permit. Industrial applications, both real and potential, are included. Where appropriate, we have encouraged the contributors to include review material to help provide the reader with adequate context. The initial chapter is a review from a historical perspective of polymer modification and contains an extensive bibliography. The remainder of the book is divided into four general areas: Reactions and Preparation of Copolymers Reactions and Preparation of Block and Graft Copolymers Modification Through Condensation Reactions Applications The chemical modification of homopolymers such as polyvinylchlo ride, polyethylene, poly(chloroalkylene sulfides), polysulfones, poly chloromethylstyrene, polyisobutylene, polysodium acrylate, polyvinyl alcohol, polyvinyl chloroformate, sulfonated polystyrene; block and graft copolymers such as poly(styrene-block-ethylene-co-butylene block-styrene), poly(I,4-polybutadiene-block ethylene oxide), star chlorine-telechelic polyisobutylene, poly(isobutylene-co-2,3-dimethyl- 1,3-butadiene), poly(styrene-co-N-butylmethacrylate); cellulose, dex tran and inulin, is described.


Handbook of Natural Polymers, Volume 1

Handbook of Natural Polymers, Volume 1

Author: M.S. Sreekala

Publisher: Elsevier

Published: 2023-05-31

Total Pages: 702

ISBN-13: 0323998542

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The Handbook of Natural Polymers: Sources, Synthesis, and Characterization is a comprehensive resource covering extraction and processing methods for polymers from natural sources, with an emphasis on the latest advances. The book begins by introducing the current state-of-the-art, challenges, and opportunities in natural polymers. This is followed by detailed coverage of extraction, synthesis, and characterization methods, organized by polymer type. Along with broad chapters discussing approaches to polysaccharide-based polymers, dedicated chapters offer in-depth information on nanocellulose, chitin and chitosan, gluten, alginate, natural rubber, gelatin, pectin, lignin, keratin, gutta percha, shellac, silk, wood, casein, albumin, collagen, hemicellulose, polyhydroxyalkanoates, zein, soya protein, and gum. The final chapters explore other key themes, including filler interactions and properties in natural polymer-based composites, biocompatibility and cytotoxicity, biodegradability, life cycle, and recycling. Throughout the book, information is supported by data, and guidance is offered regarding potential scale-up and industry factors. As part of a 3-volume handbook offering comprehensive coverage of natural polymers, this book will be of interest to all those looking to gain a broad knowledge of natural polymers, including academic researchers, scientists, advanced students, engineers, and R&D professionals from a range of disciplines and industries. - Provides systematic coverage of the latest methods for the extraction, synthesis, and characterization of natural polymers. - Includes an extensive range of natural polymer sources, including established biopolymers and emerging materials. - Explores preparation of natural polymers and their composites, blends, IPNs, gels, and nanoparticles.


Oxidoreductase

Oxidoreductase

Author:

Publisher: BoD – Books on Demand

Published: 2021-02-17

Total Pages: 182

ISBN-13: 1838809007

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Oxidoreductase enzymes are a group of enzymes that catalyzes the transfer of electrons from one molecule, the reductant, also called the electron donor, to another, the oxidant, also called the electron acceptor. Oxidoreductase enzymes utilize NADP+ or NAD+ as cofactors. Oxidoreductase enzymes include the following: oxidase, dehydrogenase, peroxidase, hydroxylase, oxygenase, and reductase. Most oxidoreductase enzymes are dehydrogenases. However, reductases are also common. The accepted nomenclature for dehydrogenases is “donor dehydrogenase”, where the donor is the oxidized substrate. Metabolic abnormalities disorders resulting from a deficiency (quantitative and qualitative) or from over-activity of oxidoreductase, which may contribute to the decreased normal performance of life, are becoming common. This book covers the potential applications of oxidoreductases on the growth of oxidoreductase-based diagnostic tests and better biosensors in the design of inventive systems for crucial co-enzyme generations and in the synthesis of polymers and organic substrates. The book describes the role of oxidoreductase as essential in medical drug formation. It can be employed to produce a huge amount of compounds that act as medical mediators like Cephalosporin (beta lactam antibiotic). Furthermore, the idea of how to use different enzymes as targets for medical treatment in different types of cancers is also described in this book.


Nanostructured Catalysts for Environmental Applications

Nanostructured Catalysts for Environmental Applications

Author: Marco Piumetti

Publisher: Springer Nature

Published: 2021-01-20

Total Pages: 435

ISBN-13: 303058934X

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This book offers an overview of the recent studies and advances in environmental catalysis by nanomaterials, considering both the fundamental and the technological aspects. It offers contributions in different areas of environmental catalysis, including the catalytic and photocatalytic abatement of environmentally hazardous effluents from stationary or mobile sources, the valorization of waste and the production of sustainable energy. In other words, this monograph provides an overview of modern environmental and energy related applications with a particular emphasis to nano-sized catalytic materials. Recent concepts, experimental data and advanced theories are reported in this book to give evidence of the environmental and sustainable applications that can be found in the highly interdisciplinary field of catalysis.