Porphyrins play a vital role in many biological functions including oxygen transport, electron transfer and catalyzing the incorporation of oxygen into other molecules. This current survey discusses the use of modern physical techniques to probe porphyrin structure and function. The authors review the data available through a particular technique and show what can be learned therefrom about the (electronic) structure and function of biologically important porphyrins. The techniques include magnetic circular dichroism, X-ray absorption fine structure (EXAFS) and Mössbauer spectroscopies. All contributors are well known in their respective fields, enjoying world-wide reputation.
Biofuel Cells: The Design and Application of Biological Catalysts presents a detailed examination of biofuel cells, from their fundamentals and basic principles through to the latest technological, materials, and bioengineering developments. The book follows a clear, step-by-step chapter structure that takes the reader through each stage of the design, construction, and operation of BFC-based devices. Chapters 1 and 2 provide a detailed review of the fundamentals and basic principles of microbial and biofuel cells, including the electrochemistry, materials and mechanics, and applications. Chapter 3 provides an in-depth examination of catalyst evolution and chapter 4 explains all aspects of electron transfer in enzymatic biofuel cells. Chapter 5 reviews all types of hybrid biofuel cell, including fabrication and design strategies for thermoelectric and triboelectric energy devices. In chapter 6 advanced manufacture techniques for biofuel cells and bio-devices are explained, including the working principles and methodologies for printing, microfluidics, fiber, microneedle, and others. Finally, chapter 7 explores the diverse applications of biofuel cells and bio-devices, from biosensors and bioelectronics to capacitive biofuel cells. Chapters are supported by computational tools, working manuals for the techniques discussed, and detailed schematics and flowcharts for BCF fabrication. Biofuel Cells: The Design and Application of Biological Catalysts is an invaluable resource for graduate students and early career researchers interested in any aspect of biofuel cells and bio-devices and is specifically designed to benefit students from multiple backgrounds, including chemical engineering, electrical engineering, mechanical engineering, and biotechnology. - Explains the mechanisms of enzymatic and microbial biocatalysts, electron transfer mechanisms, and bioengineering for biocatalysts in BFCs - Explores the latest developments in biofuel cell technology, including printed biofuel cells, fiber biofuel cells, as well as other manufacturing methods - Reviews the versatile applications of biofuel cells, including bio-hybrid systems, self-powered biosensors, and flexible bioelectronics
The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead. As such, it covers both homogeneous as well as heterogeneous chemocatalysis and biocatalysis, along with examples taken from various industries: bulk chemicals and monomers, specialty chemicals, flavors and fragrances, vitamins, and pharmaceuticals. One chapter is devoted to reactor concepts and engineering aspects of these methods, while another deals with the relevance of aerobic oxidation catalysis for the conversion of renewable feedstock. With chapters written by a team of academic and industrial researchers, this is a valuable reference for synthetic and catalytic chemists at universities as well as those working in the pharmaceutical and fine chemical industries seeking a better understanding of these reactions and how to design large scale processes based on this technology.
A one-stop reference that reviews protein design strategies to applications in industrial and medical biotechnology Protein Engineering: Tools and Applications is a comprehensive resource that offers a systematic and comprehensive review of the most recent advances in the field, and contains detailed information on the methodologies and strategies behind these approaches. The authors—noted experts on the topic—explore the distinctive advantages and disadvantages of the presented methodologies and strategies in a targeted and focused manner that allows for the adaptation and implementation of the strategies for new applications. The book contains information on the directed evolution, rational design, and semi-rational design of proteins and offers a review of the most recent applications in industrial and medical biotechnology. This important book: Covers technologies and methodologies used in protein engineering Includes the strategies behind the approaches, designed to help with the adaptation and implementation of these strategies for new applications Offers a comprehensive and thorough treatment of protein engineering from primary strategies to applications in industrial and medical biotechnology Presents cutting edge advances in the continuously evolving field of protein engineering Written for students and professionals of bioengineering, biotechnology, biochemistry, Protein Engineering: Tools and Applications offers an essential resource to the design strategies in protein engineering and reviews recent applications.
This textbook describes the types of natural products, the biosynthetic pathways that enable the production of these molecules, and an update on the discovery of novel products in the post-genomic era.
Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973
Bioelectrochemical Systems (BESs) are innovative and sustainable devices. They combine biological and electrochemical processes to engineer sensors, treat wastewater and/or produce electricity, fuel or high-value chemicals. In BESs, scientists have managed to incorporate biological catalysts, i.e. enzymes and/or microorganisms, and make them work in advanced electrochemical cells. BESs operate under mild conditions — at close to ambient temperature and pressure and at circumneutral pH — and represent a sustainable alternative to precious metal-based systems. Incorporating biological catalysts into devices while maintaining their activity and achieving electrical communication with electrode surfaces is a critical challenge when trying to advance the field of BESs.From implantable enzymatic biosensors to microbial electrosynthesis, and from laboratory-scale systems and fundamental studies to marketed devices, this book provides a comprehensive overview of recent advances related to functional electrodes for BESs. Suitable for researchers and graduate students of chemistry, biochemistry, materials science and environmental science and technology.
The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.
This Handbook on Metalloproteins focuses on the available structural information of proteins and their metal ion coordination spheres. It centers on the metal ions indispensable for life but also considers metal ions used as substitution probes in studies of metalloproteins. Emphasizing the structure-function relationship, the book covers the common and distinct characterstics of metallo- enzymes, proteins, and amino acids bonded to copper, zinc, iron, and more.
