Electrochemical-induced hydrofunctionalizations of alkenes and alkynes
Electrochemical-induced hydrofunctionalizations of alkenes and alkynes

Author: Yahui Zhang

Publisher: OAE Publishing Inc.

Published: 2024-03-01

Total Pages: 29

ISBN-13:

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The hydrofunctionalizations of readily available alkenes and alkynes are one of the most effective and useful routes to afford diverse value-added compounds. Although traditional hydrofunctionalization strategies catalyzed by metal catalysts present convenient approaches, they are also accompanied by resource consumption and environmental crisis. Electrosynthesis, as a renewable and sustainable technology, has become a cost- and atom-efficient and useful synthetic route. In this review, the electrochemical-induced hydrofunctionalizations of alkenes and alkynes are summarized and presented. In each section, the electrochemical synthetic strategy to access hydrogenation and other hydrofunctionalization (hydroboration, hydrosilylation, hydroalkylation, hydroalkoxylation, hydrocyanation, hydrocarboxylation, etc.) products are elaborated in detail separately. Finally, the current challenges and prospects for electrochemical hydrofunctionalizations of unsaturated carbon‒carbon (C‒C) bonds are also discussed briefly.

Industrial Applications of Homogeneous Catalysis
Industrial Applications of Homogeneous Catalysis

Author: A. Mortreux

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 371

ISBN-13: 9400938977

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Catalysts are now widely used in both laboratory and industrial-scale chemistry. Indeed, it is hard to find any complex synthesis or industrial process that does not, at some stage, utilize a catalytic reaction. The development of homogeneous transition metal catalysts on the laboratory scale has demonstrated that these systems can be far superior to the equivalent heterogeneous systems, at least in terms of selectivity. is an increasing interest in this field of research from both an Thus, there academic and industrial point of view. In connection with the rapid developments in this area, four universities from the E.E.C (Aachen, FRG; Liege, Belgium; Milan, Italy; and Lille, France) have collaborated to organise a series of seminars for high-level students and researchers. These meetings have been sponsored by the Commission of the E.E.C and state organizations. The most recent of these meetings was held in Lille in September 1985 and this book contains updated and expanded presentations of most of the lectures given there. These lectures are concerned with the field of homogeneous transition metal catalysis and its application to the synthesis of organic intermediates and fine chemicals from an academic and industrial viewpoint. The continuing petroleum crisis which began in the early 1970s has given rise to the need to develop new feedstocks for the chemical industry.

Organic Reaction Mechanisms 2016
Organic Reaction Mechanisms 2016

Author: A. C. Knipe

Publisher:

Published: 2020-01-14

Total Pages: 872

ISBN-13: 9781119288657

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Organic Reaction Mechanisms 2016, the 52nd annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2016. The following classes of organic reaction mechanisms are comprehensively reviewed: * Reaction of Aldehydes and Ketones and their Derivatives * Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives * Oxidation and Reduction * Carbenes and Nitrenes * Nucleophilic Aromatic Substitution * Electrophilic Aromatic Substitution * Carbocations * Nucleophilic Aliphatic Substitution * Carbanions and Electrophilic Aliphatic Substitution * Elimination Reactions * Polar Addition Reactions * Cycloaddition Reactions * Molecular Rearrangements

Iron Catalysis
Iron Catalysis

Author: Bernd Plietker

Publisher: Springer Science & Business Media

Published: 2011-01-05

Total Pages: 227

ISBN-13: 3642146694

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Juan I. Padrón and Víctor S. Martín: Catalysis by means of Fe-based Lewis acids; Hiroshi Nakazawa*, Masumi Itazaki: Fe–H Complexes in Catalysis; Kristin Schröder, Kathrin Junge, Bianca Bitterlich, and Matthias Beller: Fe-catalyzed Oxidation Reactions of Olefins, Alkanes and Alcohols: Involvement of Oxo- and Peroxo Complexes; Chi-Ming Che, Cong-Ying Zhou, Ella Lai-Ming Wong: Catalysis by Fe=X Complexes (X=NR, CR2); René Peters, Daniel F. Fischer and Sascha Jautze: Ferrocene and Half Sandwich Complexes as Catalysts with Iron Participation; Markus Jegelka, Bernd Plietker: Catalysis by Means of Complex Ferrates.

Oxidative Cross-Coupling Reactions
Oxidative Cross-Coupling Reactions

Author: Aiwen Lei

Publisher: John Wiley & Sons

Published: 2016-08-12

Total Pages: 240

ISBN-13: 3527681019

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The first handbook on this emerging field provides a comprehensive overview of transition metal-catalyzed coupling reactions in the presence of an oxidant. Following an introduction to the general concept and mechanism of this reaction class, the team of authors presents chapters on C-C cross-coupling reactions using organometallic partners, C-Heteroatom bond forming reactions via oxidative couplings, and C-H couplings via C-H activation. The text also covers such groundbreaking topics as recent achievements in the fields of C-C and C-X bond formation reactions as well as C-H activation involving oxidative couplings. With its novel and concise approach towards important building blocks in organic chemistry and its focus on synthetic applications, this handbook is of great interest to all synthetic chemists in academia and industry alike.

Electroorganic Chemistry as a New Tool in Organic Synthesis
Electroorganic Chemistry as a New Tool in Organic Synthesis

Author: Tatsuya Shono

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 180

ISBN-13: 3642694934

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Although the first electroorganic reaction used in organic synthesis is probably the famous Kolbe electrolysis published in 1849, no other remarkable reactions have been found until the reductive dimerization of acrylonitrile to adipo nitrile was developed by Dr. M. M. Baizer of Monsanto Co. in 1964. Since then, the electro organic chemistry has been studied extensively with the expectation that it is a new useful tool for finding novel reactions in organic synthesis. The purpose of this book is not to give a comprehensive survey of studies on electrochemical reactions of organic compounds but to show that the electro organic chemistry is indeed useful in organic synthesis. Thus, this book has been written under the following policies. (1) Since this monograph is mainly concerned with organic synthesis, only few studies carried out from the view point of electrochemical, theoretical, or analytical chemistry are mentioned. (2) Since electroorganic chemistry covers a great variety of reactions, the types of reactions described in this book are selected mainly with regard to their application in organic synthesis. Simple transformations of functional groups are only described in particular cases, and also some well established processes such as the Kolbe electrolysis, pinacolic coupling, and hydrodimerization are only briefly mentioned. (3) Since many reports have already been published for each type of these reactions, only a limited number of the relevant papers are cited in this book.

Organic Electrochemistry
Organic Electrochemistry

Author: Ole Hammerich

Publisher: CRC Press

Published: 2015-09-22

Total Pages: 1706

ISBN-13: 142008402X

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Praise for the Fourth Edition"Outstanding praise for previous editions.the single best general reference for the organic chemist."-Journal of the Electrochemical Society"The cast of editors and authors is excellent, the text is, in general, easily readable and understandable, well documented, and well indexed those who purchase the book will be sa

Manganese Catalysis in Organic Synthesis
Manganese Catalysis in Organic Synthesis

Author: Jean-Baptiste Sortais

Publisher: John Wiley & Sons

Published: 2021-12-20

Total Pages: 372

ISBN-13: 3527347305

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Manganese Catalysis in Organic Synthesis A must-read reference for anyone interested in catalyst design and sustainable organic synthesis In Manganese Catalysis in Organic Synthesis, distinguished researcher Jean-Baptiste Sortais delivers an insightful and robust overview of the use of manganese in homogenous catalysis. The editor includes papers from authoritative academics describing the organometallic precursors used to develop manganese catalysts and covers critical applications in organic synthesis, including reduction to oxidation reactions, C-C, C-N, C-X bond formation reactions, cross-coupling reactions, C-H bond activation to dihydroxylation and epoxidation reactions. Manganese Catalysis in Organic Synthesis is a practical resource for every organic chemist in academia and industry with an interest in non-noble metal catalysis, organic synthesis, and sustainable chemistry. It is intuitively and clearly organized, covering the most important synthetic procedures using homogenous manganese catalysts. It is also the ideal companion to works like Cobalt Catalysis in Organic Synthesis, Nickel Catalysis in Organic Synthesis, and Iron Complexes in Catalysis. Readers will also enjoy: Thorough introductions to organometallic manganese compounds in organic synthesis and manganese-catalyzed hydrogenation and hydrogen transfer reactions A comprehensive exploration of manganese-catalyzed hydrogen borrowing reactions and dehydrogenative coupling reactions Practical discussions of manganese-catalyzed hydrosilylation and hydroboration reactions and manganese-catalyzed electro- and photocatalysis transformations In-depth examinations of manganese-catalyzed C-H oxygenation reactions and manganese-catalyzed organometallic C-H activation Insightful treatments of manganese-catalyzed cross-coupling processes and manganese(III) acetate mediated cyclizations Perfect for catalytic, organic, and pharmaceutical chemists, Manganese Catalysis in Organic Synthesis deserves a place in the libraries of researchers and professionals interested in catalyst design and sustainable organic synthesis.

Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes
Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes

Author: Mark Greenhalgh

Publisher: Springer

Published: 2018-05-27

Total Pages: 306

ISBN-13: 9783319815688

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This thesis gives a thorough account of the development of iron-catalysed hydrosilylation, hydroboration and hydromagnesiation reactions. With extraordinary referencing and scientific argument, Mark Greenhalgh describes the development of methodologies which require only commercially available materials and non-specialised techniques. The intention of this approach is to ensure the science can be adopted widely by the chemical community. In addition to an insight into the processes involved in methodology development, Greenhalgh discusses and determines the relevant reaction mechanisms. This thesis provides not only the most thorough review of the area, but offers a level of insight well beyond that expected from a Ph.D. student. The work in this thesis has been published at the highest level, and the results and ideas have led to 3 industry-funded Ph.D. studentships and grant income in excess of £1 million.