Cyclophanes
Cyclophanes

Author: Philip Keehn

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 391

ISBN-13: 0323152562

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Cyclophanes, Volume I is a collection of papers that reviews cyclophane chemistry. One paper describes the genesis of the cyclophane concept, covering its past, present, and future possible applications. The results of experimental and theoretical studies show the interrelationships between the structure and energetics in the class of compounds known as cyclophanes. Another paper relates the X-ray crystal structure determinations of cyclophanes to set the crystallographic and structural data of these systems in such a form that will enable comparisons, lead to an understanding of the geometries and deviations, and open the application of data to other areas of cyclophane chemistry. One paper reviews the methods by which nuclear magnetic resonance is applied to assign stereochemistry in the fixed phanes to show the conformational effects that have been observed in the mobile phanes. Another paper explains the synthesis, chemical, and physical properties of [n]cyclophanes, including systems with benzene, naphthalene, anthracene rings, heteroaromatics pyridine, furan, pyrrole, and thiophene. This collection can greatly profit researchers and academicians in the fields of organic chemistry, physical chemistry, and other scientists whose works revolve around aromatic compounds and cyclophanes.

Cyclophanes
Cyclophanes

Author: Philip M. Keehn

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 401

ISBN-13: 1483269477

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Cyclophanes, Volume II, provides a comprehensive review of the field of cyclophane chemistry for the period between the earlier volume in this series (Bridged Aromatic Compounds by A. H. Smith, 1964) and the present (generally through 1981). An attempt has been made to provide a selection of topics that delineate the past and present of cyclophane chemistry and point toward some of its future directions. The ordering of chapters has been chosen to present background, theory, structure, and spectroscopy followed by a somewhat arbitrary division of cyclophanes into subgroups, roughly in order of increasing structural complexity. Key topics discussed include the synthesis and properties of heterophanes, condensed benzenoid and nonbenzenoid cyclophanes, multibridged and multilayered cyclophanes, cyclophanes in host-guest chemistry, and cyclophanes as synthetic analogs of enzymes and receptors. Individual chapters have been written so that they may be read with little or no direct reference to other chapters. Each stands alone as a review of a particular area of cyclophane chemistry and therefore some overlap between chapters will be apparent.

Modern Cyclophane Chemistry
Modern Cyclophane Chemistry

Author: Rolf Gleiter

Publisher: John Wiley & Sons

Published: 2006-03-06

Total Pages: 586

ISBN-13: 3527604634

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Here, the editors Rolf Gleiter and Henning Hopf present an excellent overview of all the important aspects and latest results in cyclophane chemistry. Clearly structured and covering the entire range, the book introduces readers to the most recent research in the field. Twenty chapters, written by well-known scientists, cover in particular: - synthesis of carbo- and heterocyclic cyclophanes and metallocenophanes, - structural and spectroscopic properties of cyclophanes, - current and future applications in synthesis and material science, - novel reactions of cyclophanes, - use of cyclophanes as building blocks in supramolecular chemistry for this fascinating class of compounds. Thus, this is not only an extremely valuable source of information for synthetic organic chemists, but also a ready reference for scientists working in related fields of arene chemistry, stereoselective synthesis, material science, and bioorganic chemistry.

Cyclophanes
Cyclophanes

Author: Francois N Diederich

Publisher: Royal Society of Chemistry

Published: 2016-11-08

Total Pages: 330

ISBN-13: 1788010922

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Cyclophanes are bridged aromatic compounds and represent the central class of synthetic receptors in molecular recognition. All types of substrates, from inorganic and organic cations and anions, to neutral molecules have been complexed by tailor-made cyclophanes. This monograph focuses on the principles of supramolecular complexation and catalysis. It provides a state-of-the-art review of the intermolecular forces that hold together the supramolecular complexes of cyclophanes with neutral and charged organic molecules in the liquid phase. Cyclophanes also demonstrates the characteristics and advantages of bridged aromatic compounds as receptors. The book has great clarity, is very readable and will be extremely useful in both teaching and research.

Aza-Crown Macrocycles
Aza-Crown Macrocycles

Author: Jerald S. Bradshaw

Publisher: John Wiley & Sons

Published: 2009-09-17

Total Pages: 896

ISBN-13: 0470188901

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The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects – properties, synthesis, reactions, physiological and industrial significance – of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.

Carbon Rich Compounds I
Carbon Rich Compounds I

Author: Armin de Meijere

Publisher: Springer

Published: 2003-09-05

Total Pages: 238

ISBN-13: 3540696911

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Carbon Rich Compounds are defined here as carbon skeletons with a carbon to hydrogen ratio of 1:(=

Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures
Electronic and Magnetic Properties of Chiral Molecules and Supramolecular Architectures

Author: Ron Naaman

Publisher: Springer Science & Business Media

Published: 2011-01-25

Total Pages: 323

ISBN-13: 3642181031

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Time-dependent density functional response theory for electronic chiroptical properties of chiral molecules; by Jochen Autschbach, Lucia Nitsch–Velasquez, and Mark Rudolph * Chiroptical Properties of Charge-Transfer Compounds; by Yoshihisa Inoue, Tadashi Mori * G-C content independent long-range charge transfer through DNA; by Tetsuro Majima * Induced chirality in porphiryn aggregates: the role of weak and strong interactions; by Roberto Purrello * Vibrational circular dichroism spectroscopy of chiral molecules in solution; by Yunjie Xu * Magneto-electric properties of self-assembled monolayers of chiral molecules; by Zeev Vager and Ron Naaman * Theory of adsorption induced chirality and electron transfer through chiral systems; by Spiros Skourtis and David Beratan * Chiral-selective surface chemistry induced by spin-polarized secondary electrons; by Richard Rosenberg

Supramolecular Electrochemistry
Supramolecular Electrochemistry

Author: Angel E. Kaifer

Publisher: John Wiley & Sons

Published: 2008-07-11

Total Pages: 255

ISBN-13: 3527613617

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This book describes the electrochemical behavior of supramolecular systems. Special emphasis will be given to the electrochemistry of host-guest complexes, monolayer and multilayer assemblies, dendrimers, and other supramolecular assemblies. A fundamental theme throughout the book is to explore the effects that supramolecular structure exerts on the thermodynamics and kinetics of electrochemical reactions. Conversely, attention will be placed to the various ways in which electrochemical or redox conversions can be utilized to control or affect the structure or properties of supramolecular systems. This first book on this topic will be of value for graduate students and advanced researchers in both electrochemistry and supramolecular chemistry.