Corrosion Protection Performance Evaluation of Low Permeable Concretes in Exposure Specimens

Corrosion Protection Performance Evaluation of Low Permeable Concretes in Exposure Specimens

Author: Jerzy Zemajtis

Publisher:

Published: 1999

Total Pages: 152

ISBN-13:

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The application of a mineral admixture or a combination of a mineral admixture with corrosion inhibitor are the methods used for the corrosion protection for reinforced concrete bridges. The results of a 1.5-year study on evaluation of three concretes with fly ash, slag cement (SC), and silica fume (SF) and one concrete with silica fume and a corrosion inhibitor (SFD) are presented. The specimens were built to simulate four exposure conditions typical for concrete bridges located in the coastal region or inland where deicing salts are used. The exposure conditions were horizontal, vertical, tidal, and immersed zones. The specimens were kept inside the laboratory and were exposed to weekly ponding cycles of 6% sodium chloride solution by weight. In addition, cover depth measurements from 21 bridge decks and chloride data from 3 bridge decks were used, together with laboratory data, in modeling the service lives of investigated corrosion protection methods. The methods used to assess the condition of the specimens included chloride concentration measurements, corrosion potentials, and corrosion rates (3LP). Additionally, visual observations were performed for identification of rust stains and cracking on concrete surfaces. The results of chloride testing indicate that the amount of chlorides present at the bar level is more than sufficient to initiate corrosion. Chloride and rapid permeability data demonstrate that for low permeable (LP) concretes there appears to be significant difference both in a rate of chloride ingress and in the diffusion coefficients in comparison to the controls. Corrosion potentials agree with corrosion rates and suggest the possibility of an active corrosion process development on control specimens during indoor exposure. The structural cracks that were observed in some specimens appeared to have no influence on the corrosion development on the bars in the vicinity of the these cracks. It was concluded that the silicone and duct tape protection was adequate. The cracking, other than structural, appeared to be related to the reinforcing steel corrosion, except the cracks in the horizontal zone of the specimen with slag cement which were probably caused by the subsidence cracking. The least number of cracks was observed on the SF and SFD specimens. Modeling the time as a function of probability of the end of functional service life (EFSL) was presented. It has been shown that the distributions of surface concentrations of chloride ions (CO) and diffusion constants (DC) are key elements in the model. Model predictions show that the LP concretes provide much better level of protection against moisture and chlorides than the A4 concrete alone. Application of a corrosion inhibitor causes an elevation of the chloride threshold resulting in an additional increase in time to EFSL. Recommendations are to continue monitoring until cracking has occurred in all specimens to a greater extent to better estimate the service lives of LP concretes than is presently known in the construction of concrete bridge components in Virginia. The specimens with LP concretes and one control (continuous reinforcement in the legs) should be taken to the Hampton Road North Tunnel Island and placed in the brackish water to a depth of the immersed zone at low tide for further exposure to chloride. The other control (non-continuous reinforcement in the legs) should remain in an outdoor exposure in Southwest Virginia like the Civil Engineering Materials Research Laboratory in Blacksburg, Virginia. Also more field studies are needed to better estimate distributions of surface chloride concentration and diffusion coefficient of Virginia bridge decks, and to confirm predicted times to EFSL for LP concretes.


Performance Evaluation of Corrosion Inhibitors and Galvanized Steel in Concrete Exposure Specimens

Performance Evaluation of Corrosion Inhibitors and Galvanized Steel in Concrete Exposure Specimens

Author: Jerzy Zemajtis

Publisher:

Published: 1999

Total Pages: 80

ISBN-13:

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Corrosion inhibitor admixtures (CIA) and galvanized reinforcing steel (GS) are used for the corrosion protection for reinforced concrete bridges. The results of a 3.5-year evaluation of exposure specimens containing CIA from three different manufacturers and GS are presented. The specimens were built to simulate four exposure conditions typical for concrete bridges located in the coastal region or inland where deicing salts are used. The exposure conditions were Horizontal, Vertical, Tidal, and Immersed Zones. The specimens were kept inside the laboratory and were exposed to weekly ponding cycles of 6% sodium chloride solution by weight. The methods used to assess the condition of the specimens included chloride concentration measurements, corrosion potentials, and corrosion rates. Additionally, visual observations were performed for identification of rust stains and cracking on concrete surfaces. The results of chloride testing indicate that the amount of chlorides present at the bar level is more than sufficient to initiate corrosion. Chloride and rapid permeability data indicate no significant difference either in a rate of chloride ingress or in the diffusion coefficients for concretes with and without CIA. Corrosion potentials were the most negative for the Bare Steel (BS) specimen prepared with the Armatec 2000 corrosion inhibitor and generally indicated a 90% probability of active corrosion. Corrosion potentials were similar for the two BS control specimens and the BS specimen prepared with Rheocrete 222 and generally indicated an uncertain probability of corrosion. Corrosion potentials were the least negative for the BS specimen prepared with DCI-S corrosion inhibitor and generally indicated a 90% probability of no corrosion. Rate of corrosion measurements were the highest for the BS control specimens and the one prepared with A2000 and the most recent data suggest corrosion damage in 2 to 10 years. Although early rate of corrosion measurements were higher or about the same as for BS control specimens, recent measurements were slightly lower for the specimen prepared with Rheocrete 222 and suggest corrosion damage in 10 to 15 years. Rate of corrosion measurements were consistently the lowest for the BS specimens prepared with DCI-S and indicate corrosion damage is expected in 10 to 15 years. The corrosion potential and rate of corrosion data indicate that DCI-S is the only CIA evaluated that clearly provides some level of corrosion protection. A direct comparison of the GS specimens to the BS specimens is not possible because the measured potential refers to the zinc oxide and not to the steel. Nevertheless, the potential data agree with the chloride and permeability data, as well as with the visual observations, and indicate the damaging effect of a high concentration of chloride ions on the GS. At low and moderate chloride exposures, however, GS does provide corrosion protection. Recommendations are to continue monitoring until sufficient cracking has occurred in all specimens to provide for making a better estimate of the service lives of CIA and GS used in the construction of concrete bridge components in Virginia. The specimens with CIA and one control (continuous reinforcement in the legs) should be taken to the Hampton Road North Tunnel Island and placed in the brackish water to a depth of the Immersed Zone at low tide for further exposure to chloride. The specimens with GS and the other control (non-continuous reinforcement in the legs) should remain in an outdoor exposure in Southwest Virginia like the Civil Engineering Materials Research Laboratory in Blacksburg, Virginia.


Performance-Based Specifications and Control of Concrete Durability

Performance-Based Specifications and Control of Concrete Durability

Author: Hans Beushausen

Publisher: Springer

Published: 2015-09-24

Total Pages: 384

ISBN-13: 9401773092

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This work gives an overview of significant research from recent years concerning performance-based design and quality control for concrete durability and its implementation. In engineering practice, performance approaches are often still used in combination with prescriptive requirements. This is largely because, for most durability test methods, sufficient practical experience still has to be gained before engineers and owners are prepared to fully rely on them. This book, compiled by RILEM TC 230-PSC, is intended to assist efforts to successfully build the foundation for the full implementation of performance-based approaches through the exchange of relevant knowledge and experience between researchers and practitioners worldwide.


Corrosion Protection of Reinforcing Steels

Corrosion Protection of Reinforcing Steels

Author: fib Fédération internationale du béton

Publisher: fib Fédération internationale du béton

Published: 2009-01-01

Total Pages: 123

ISBN-13: 2883940894

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It has long been recognised that corrosion of steel is extremely costly and affects many industry sectors, including concrete construction. The cost of corrosion of steel reinforcement within concrete is estimated at many billions of dollars worldwide. The corrosion of steel reinforcement represents a deterioration of the steel which in turn detrimentally affects its performance and therefore that of the concrete element within which it has been cast. A great amount of work has been undertaken over the years concerning the prevention of corrosion of steel, including the application of coatings, which has included the study of the process of corrosion itself, the properties of reinforcing steels and their resistance to corrosion as well as the design of structures and the construction process. The objective of fib Bulletin 49 is to provide readers with an appreciation of the principles of corrosion of reinforcing steel embedded in concrete and to describe the behaviour of particular steels and their coatings as used to combat the effects of such corrosion. These include galvanised reinforcement, epoxy coated reinforcement, and stainless reinforcing steel. It also provides information on the relative costs of the materials and products which it covers. It does not deal with structure design or the process of construction or with the post-construction phase of structure management including repair. It is hoped that it will nevertheless increase the understanding of readers in the process of corrosion of reinforcing steels and the ability of key materials and processes to reduce its harmful effects.


Concrete Solutions

Concrete Solutions

Author: Michael Grantham

Publisher: CRC Press

Published: 2009-06-10

Total Pages: 482

ISBN-13: 0415550823

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Concrete repair continues to be a subject of major interest to engineers and technologists worldwide. The concrete repair budget for the UK alone currently runs at some UKP 220 per annum. Some estimates have indicated that, worldwide, in 2010 the expenditure for maintenance and repair work will represent about 85% of the total expenditure in the construction field. It has been forecast that, in the same year in the USA, 50 billion dollars will be spent just for the restoration of deteriorated bridges and viaducts. An understanding of the latest techniques in repair and testing and inspection is thus crucial to the international construction industry. This book, with contributions from 34 countries, brings together the best in research, practical application, strategy and theory relating to concrete repair, testing and inspection, fire damage, composites and electro-chemical repair.


Eco-efficient Repair and Rehabilitation of Concrete Infrastructures

Eco-efficient Repair and Rehabilitation of Concrete Infrastructures

Author: Fernando Pacheco-Torgal

Publisher: Woodhead Publishing

Published: 2017-11-15

Total Pages: 777

ISBN-13: 0081021828

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Eco-efficient Repair and Rehabilitation of Concrete Infrastructures provides an updated state-of-the-art review on eco-efficient repair and rehabilitation of concrete infrastructure. The first section focuses on deterioration assessment methods, and includes chapters on stress wave assessment, ground-penetrating radar, monitoring of corrosion, SHM using acoustic emission and optical fiber sensors. Other sections discuss the development and application of several new innovative repair and rehabilitation materials, including geopolymer concrete, sulfoaluminate cement-based concrete, engineered cementitious composites (ECC) based concrete, bacteria-based concrete, concrete with encapsulated polyurethane, and concrete with super absorbent polymer (SAPs), amongst other topics. Final sections focus on crucial design aspects, such as quality control, including lifecycle and cost analysis with several related case studies on repair and rehabilitation. The book will be an essential reference resource for materials scientists, civil and structural engineers, architects, structural designers and contractors working in the construction industry. - Delivers the latest research findings with contributions from leading international experts - Provides fully updated information on the European standard on materials for concrete repair (EN 1504) - Includes an entire sections on the state-of-the-art in NDT, innovative repair and rehabilitation materials, as well as LCC and LCA information