Control of Particle Concentration and Particle Size Distribution in (semi) Batch Emulsion Polymerization
Author: S. V. W. de Lima
Publisher:
Published: 2000
Total Pages: 118
ISBN-13: 9789044400618
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Author: S. V. W. de Lima
Publisher:
Published: 2000
Total Pages: 118
ISBN-13: 9789044400618
DOWNLOAD EBOOKAuthor: Charles D. Immanuel
Publisher:
Published: 2002
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: Alireza Hosseini
Publisher: Elsevier Inc. Chapters
Published: 2013-06-10
Total Pages: 17
ISBN-13: 0128086300
DOWNLOAD EBOOKIn this paper, a new control strategy that employs a mid-course correction to control the particle size distribution in emulsion polymerization is developed. In this approach, online and infrequent measurements are used to obtain the states of the system at the mid-course of the process. Then an optimization is performed to obtain the optimal trajectory of the input from the mid-course up to the end of the process. For this optimization, a hybrid model is used. This hybrid model consists of the Fokker-Planck particle size distribution model of emulsion polymerization and a data-driven component which corrects the predictions of the Fokker-Planck model based upon the estimated states of the system at the mid-course of the process.
Author: Charles D. Immanuel
Publisher:
Published: 2002
Total Pages: 574
ISBN-13:
DOWNLOAD EBOOKAuthor: Nicola Bianco
Publisher:
Published: 2009
Total Pages:
ISBN-13:
DOWNLOAD EBOOKAuthor: Mustafa Tekin Dokucu
Publisher: ProQuest
Published: 2007
Total Pages: 354
ISBN-13: 9780549362760
DOWNLOAD EBOOKEmulsion polymerization has significant advantages over bulk and solution polymerization processes. These advantages result mostly from the multiphase and compartmentalized nature of the emulsion polymerization, delivering a high versatility to product qualities but adding to the complexity of the process. The control of the full particle-size distribution (PSD) in emulsion polymerization is vital for industrial applications where the target distributions are usually complex and/or multimodal. Despite the strong need, control of the full PSD presents a challenging task mainly due to the complexity of emulsion polymerization and the lack of adequate on-line measurement instrumentation. In this work, in-batch and batch-to-batch control strategies are developed for the regulation of the full PSD in semibatch emulsion copolymerization of Vinyl Acetate/Butyl Acrylate with nonionic surfactants and a redox initiator pair. These strategies are also applicable for regulation of distributions in other particulate systems governed by population balances.
Author: Bhavin R. Patel
Publisher:
Published: 1987
Total Pages: 162
ISBN-13:
DOWNLOAD EBOOKAuthor: A. M. van Herk
Publisher: John Wiley & Sons
Published: 2013-05-13
Total Pages: 332
ISBN-13: 1118638360
DOWNLOAD EBOOKChemistry and Technology of Emulsion Polymerisation 2e provides a practical and intuitive explanation of emulsion polymerization, in combination with both conventional and controlled radical polymerization. For those working in industry, coupling theory with everyday practice can be difficult. By carefully explaining the principles of the reaction, based on well-designed experimental investigation, the book explains how the principles relate to practical application. The second edition of this book includes a new chapter on morphology of latex particles, a rapidly progressing area where modelling the thermodynamic and kinetic aspects of phase separation and morphology has developed into a mature and powerful tool to predict and control morphology of latex particles. Another area that is rapidly progressing is the application of controlled radical polymerisation in emulsion polymerization. Controlled radical polymerisation is used in aiding encapsulation of inorganic particles like pigment particles and clay platelets. These latest developments are included in the second edition.
Author: Mehdi Rajabi-Hamane
Publisher:
Published: 2007
Total Pages: 144
ISBN-13: 9783832263645
DOWNLOAD EBOOKAuthor: John Carroll Prindle
Publisher:
Published: 1989
Total Pages: 350
ISBN-13:
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