Provides insights into the composition of petroleum, especially its heavy ends, and presents a review of modern methods for the analysis of heavy petroleum fractions, which are viewed as refinery feedstocks. The concept of an atmospheric equivalent boiling point (AEBP) scale increasing the boiling range almost threefold and allowing for the description of all crude oil fractions is introduced.
Provides insights into the composition of petroleum, especially its heavy ends, and presents a review of modern methods for the analysis of heavy petroleum fractions, which are viewed as refinery feedstocks. The concept of an atmospheric equivalent boiling point (AEBP) scale increasing the boiling range almost threefold and allowing for the description of all crude oil fractions is introduced.
Supported by numerous illustrations and references, this book describes the chemistry and physics that occur during the refinery operations, and how the properties of petroleum can be translated into predictability in refinery scenarios. The chapters discuss such topics as: the composition of petroleum, petroleum analysis and evaluation; metals and heteroatoms in petroleum; asphaltenes and the structure of petroleum, thermal chemistry of petroleum constituents; heavy oil upgrading processes; hydrocracking reactions, catalysts, and processes; and instability and incompatibility of petroleum products.
Although there is a shortage of light petroleum, there is plenty of heavy petroleum rich in macromolecules available, creating an increasing interest for processes that can convert heavy oils to light oils. Process Chemistry of Petroleum Macromolecules provides the scientific basis for such processes, presenting methods to determine improvement potential. Topics include characterization, thermal kinetics, phase behavior, and separation. Revealing that the science of petroleum macromolecules is simpler and more exciting than imagined, it also discusses macromolecules that self-associate, liquid crystalline phases, reactions triggered by phase separation, and both dispersed and dissolved solutes.
The last three chapters of this book deal with application of methods presented in previous chapters to estimate various thermodynamic, physical, and transport properties of petroleum fractions. In this chapter, various methods for prediction of physical and thermodynamic properties of pure hydrocarbons and their mixtures, petroleum fractions, crude oils, natural gases, and reservoir fluids are presented. As it was discussed in Chapters 5 and 6, properties of gases may be estimated more accurately than properties of liquids. Theoretical methods of Chapters 5 and 6 for estimation of thermophysical properties generally can be applied to both liquids and gases; however, more accurate properties can be predicted through empirical correlations particularly developed for liquids. When these correlations are developed with some theoretical basis, they are more accurate and have wider range of applications. In this chapter some of these semitheoretical correlations are presented. Methods presented in Chapters 5 and 6 can be used to estimate properties such as density, enthalpy, heat capacity, heat of vaporization, and vapor pressure. Characterization methods of Chapters 2-4 are used to determine the input parameters needed for various predictive methods. One important part of this chapter is prediction of vapor pressure that is needed for vapor-liquid equilibrium calculations of Chapter 9.
In this first volume, the reader will find, collected and condensed, the information needed to characterize, analyze, and evaluate crude oils from different origins and their corresponding petroleum cuts as well. The characteristics and specifications of all the petroleum products along with their simplified process flowsheets are reviewed.Contents: 1. Composition of crude oils and petroleum products. 2. Fractionation and elemental analysis of crude oils and petroleum cuts. 3. Characterization of crude oils and petroleum fractions. 4. Methods for the calculation of hydrocarbon physical properties. 5. Characteristics of petroleum products for energy use (motor fuels - heating fuels). 6. Characteristics of non-fuel petroleum products. 7. Standards and specifications of petroleum products. 8. Evaluation of crude oils. 9. Additives for motor fuels and lubricants. 10. Introduction to refining. Appendices: Principal characteristics of pure components. Principal standard test methods for petroleum products. References. Index.
A clear presentation of the various aspects of petroleum analysis Petroleum exhibits a wide range of physical properties. Numerous tests have been and continue to be developed to provide an indication of the means by which a particular feedstock should be processed. An initial inspection of the nature of petroleum provides deductions about the most logical means of refining and classifying. Handbook of Petroleum Analysis is a single, comprehensive source that describes the application and interpretation of data resulting from various test methods for petroleum feedstocks and products. The need for the application of analytical techniques to petroleum has increased over the past three decades due to changes in feedstock composition. Handbook of Petroleum Analysis deals with the various aspects of petroleum analysis while providing a detailed explanation of the necessary standard tests and procedures that are applicable to feedstocks. The material also reviews the application of new methods for determining instability and incompatibility, focusing on the analytical methods related to environmental regulations. Most importantly, the book provides details of the meanings of the various test results and how they might be applied to predict feedstock behavior. Where pertinent, new tests that are not yet accepted as standardized are described. Topics covered in Handbook of Petroleum Analysis include: ? Chemical composition ? Physical, thermal, electrical, and optical property testing methods ? Spectroscopic, chemical, fractionation, and chromatographic methods ? Molecular weight ? Use of the data (i.e., mapping and predictability) Handbook of Petroleum Analysis promotes a better understanding of the criteria affecting the quality of petroleum and petroleum products and is a valuable resource for chemists and engineers in the refining industry.
