Classical Thermodynamics of Non-Electrolyte Solutions

Classical Thermodynamics of Non-Electrolyte Solutions

Author: H. C. Van Ness

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 176

ISBN-13: 148322547X

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Classical Thermodynamics of Non-Electrolyte Solutions covers the historical development of classical thermodynamics that concerns the properties of vapor and liquid solutions of non-electrolytes. Classical thermodynamics is a network of equations, developed through the formal logic of mathematics from a very few fundamental postulates and leading to a great variety of useful deductions. This book is composed of seven chapters and begins with discussions on the fundamentals of thermodynamics and the thermodynamic properties of fluids. The succeeding chapter presents the equations of state for the calculation of the thermodynamic behavior of constant-composition fluids, both liquid and gaseous. These topics are followed by surveys of the mixing of pure materials to form a solution under conditions of constant temperature and pressure. The discussion then shifts to general equations for calculation of partial molal properties of homogeneous binary systems. The last chapter considers the approach to equilibrium of systems within which composition changes are brought about either by mass transfer between phases or by chemical reaction within a phase, or by both.


Chemical Thermodynamics

Chemical Thermodynamics

Author: M L McGlashan

Publisher: Royal Society of Chemistry

Published: 2007-10-31

Total Pages: 376

ISBN-13: 1847555829

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Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.


Molecular Thermodynamics Of Electrolyte Solutions (Second Edition)

Molecular Thermodynamics Of Electrolyte Solutions (Second Edition)

Author: Lloyd L Lee

Publisher: World Scientific

Published: 2021-01-07

Total Pages: 295

ISBN-13: 9811233012

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Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications — natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.


CRC Handbook of Applied Thermodynamics

CRC Handbook of Applied Thermodynamics

Author: David A. Palmer

Publisher: CRC Press

Published: 2019-07-23

Total Pages: 381

ISBN-13: 1351087886

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This practical handbook features an overview of the importance of physical properties and thermodynamics; and the use of thermo-dynamics to predict the extent of reaction in proposed new chem-ical combinations. The use of special types of data and pre-diction methods to develop flowsheets for probing projects; and sources of critically evaluated data, dividing the published works into three categories depending on quality are given. Methods of doing one's own critical evaluation of literature, a list of known North American contract experimentalists with the types of data mea-sured by each, methods for measuring equilibrium data, and ther-modynamic concepts to carry out process opti-mization are also featured.


The Chemical Reactor from Laboratory to Industrial Plant

The Chemical Reactor from Laboratory to Industrial Plant

Author: Elio Santacesaria

Publisher: Springer

Published: 2018-11-04

Total Pages: 574

ISBN-13: 3319974394

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This graduate textbook, written by a former lecturer, addresses industrial chemical reaction topics, focusing on the commercial-scale exploitation of chemical reactions. It introduces students to the concepts behind the successful design and operation of chemical reactors, with an emphasis on qualitative arguments, simple design methods, graphical procedures, and frequent comparison of capabilities of the major reactor types. It starts by discussing simple ideas before moving on to more advanced concepts with the support of numerous case studies. Many simple and advanced exercises are present in each chapter and the detailed MATLAB code for their solution is available to the reader as supplementary material on Springer website. It is written for MSc chemical engineering students and novice researchers working in industrial laboratories.


Thermodynamics of Chemical Systems

Thermodynamics of Chemical Systems

Author: Scott Emerson Wood

Publisher: Cambridge University Press

Published: 1990-03-30

Total Pages: 461

ISBN-13: 0521330416

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The aim of this book is to develop the concepts and relations pertinent to the solution of many thermodynamic problems encountered in multi-phase, multi-component systems. In doing so, it emphasizes a comprehension and development of general expressions for solving such problems, rather than ready-made equations for particular applications. Throughout the book, the methods of Gibbs are used with emphasis on the chemical potential.


Volume Properties

Volume Properties

Author: Emmerich Wilhelm

Publisher: Royal Society of Chemistry

Published: 2014-11-25

Total Pages: 645

ISBN-13: 1782627049

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Volumetric properties play an important role in research at the interface of physical chemistry and chemical engineering, but keeping up with the latest developments in the field demands a broad view of the literature. Presenting a collection of concise, focused chapters, this book offers a comprehensive guide to the latest developments in the field and a starting point for more detailed research. The chapters are written by acknowledged experts, covering theory, experimental methods, techniques, and results on all types of liquids and vapours. The editors work at the forefront of thermodynamics in mixtures and solutions and have brought together contributions from all areas related to volume properties, offering a synergy of ideas across the field. Graduates, researchers and anyone working in the field of volumes will find this book to be their key reference.


Vapour–Liquid Equilibrium

Vapour–Liquid Equilibrium

Author: Eduard Hála

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 624

ISBN-13: 1483160866

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Vapor-Liquid Equilibrium, Second Edition covers the theoretical principles and methods of calculation of equilibrium conditions from various experimental data and the elements of measuring technique, as well as the instruments for the direct determination of the equilibrium compositions of the liquid and vapor phases of the system. The book discusses the relations necessary for the thermodynamic treatment of the equilibrium between the liquid and vapor phase of a system; the concept of an ideal solution and auxiliary thermodynamic functions; and the activity and the activity coefficient. The text also describes vapor-liquid equilibrium in real systems (electrolytes and non-electrolytes) and in systems whose components (i.e. temperature, pressure, and composition of phases) mutually react according to several stoichiometric equations. The criteria of purity of substances and the methods of measuring temperature; low, medium, and high pressures; the pressures of the saturated vapors at given temperatures; and the boiling points at given pressures used in laboratory work in the field of vapor-liquid equilibrium are considered. The book also tackles the methods for the direct determination of equilibrium data (distillation, circulation, static, dew and bubble point, and flow methods). The text concludes with a review of the literature on the systems whose vapor-liquid equilibrium data had been measured and reported to the beginning of 1954. Workers in the chemical industry who deal with problems of distillation and rectification will find the book useful.