Optimizing Chloramine Treatment
Optimizing Chloramine Treatment

Author: Gregory J. Kirmeyer

Publisher: American Water Works Association

Published: 2004

Total Pages: 278

ISBN-13: 9781583213315

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This manual recommends optimal operational criteria for chloramine application to enhance and protect distribution system water quality. It examines the chemical characteristics of chloramines, documents the use of chloramines with case studies, and provides planning, design, startup, and monitoring strategies for optimizing the use of chloramines.

Disinfection By-Product Formation and Control During Chloramination
Disinfection By-Product Formation and Control During Chloramination

Author: Gerald E. Speitel Jr

Publisher: American Water Works Association

Published: 2005-05-31

Total Pages: 246

ISBN-13: 184339930X

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In response to current and anticipated disinfection by-product (DBP) regulations, many utilities have begun to use chloramines as a secondary disinfectant. Chloramination produces DBPs such as haloacetic acids (HAAs), trihalomethanes (THMs), and haloacetonitriles (HANs) in lower concentrations than chlorination. Previous research has demonstrated that dihalogenated haloacetic acids (DXAAs) are the most commonly formed HAAs during chloramination. Some utilities may have difficulty meeting the new maximum contaminant level (MCL) for HAAs because chloramination does not limit the formation of DXAAs to the same extent as it does other DBPs. The objectives of this project were to: better understand the reactivity of key natural organic matter (NOM) fractions and the effects of treatment processes with respect to dihaloacetic acid (DXAA) formation, better delineate the influence of pH and Cl2/N ratio on DXAA formation, characterize DXAA formation kinetics and the impact of treatment processes on the kinetics, especially the impact of prechlorination, calculate the rate and extent of DXAA formation at elevated summer water temperatures, and determine the effect of bromide concentration on DXAA speciation and kinetics.

Ammonia from Chloramine Decay
Ammonia from Chloramine Decay

Author: Gregory W. Harrington

Publisher: American Water Works Association

Published: 2003

Total Pages: 152

ISBN-13: 9781583212837

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This research report focused on the evaluation of the effects of pH on the inactivation of AOB by chloramines and effects of NOM removal and pH on the rate of ammonia release from the chloramine decay. It was found that water utilities should consider employing pretreatment practices that achieve great stability of chloramine residuals. in order to offset the expenses of periodic strategies to deal with nitrification. Other alternatives to consider for nitrification control are advanced NOM removal strategies or alternative pH values for water entering the distribution system.

Organic Syntheses Based on Name Reactions and Unnamed Reactions
Organic Syntheses Based on Name Reactions and Unnamed Reactions

Author: Alfred Hassner

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 462

ISBN-13: 1483287343

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Synthetically useful organic reactions or reagents are often referred to by the name of the discoverer(s) or developer(s). Older name reactions are described in text books, but more recently developed synthetically useful reactions that may have been associated occasionally with a name are not always well known. For neither of the above are experimental procedures or references easy to find. In this monograph approximately 500 name reactions are included, of which over 200 represent newer name reactions and modern reagents. Each of these reactions are extremely useful for the contemporary organic chemistry researcher in industry or academic institutions. This book provides the information in an easily accessible form. In addition to seminal references and reviews, one or more examples for each name reaction are provided and a complete typical experimental procedure is included, to enable the student or researcher to immediately evaluate reaction conditions. Besides an alphabetical listing of reactions and reagents, cross references permit the organic practitioner to find those name reactions or reagents that enable specific transformations, such as, conversion of amines to nitriles, stereoselective reduction, fluoroalkylation, phenol alkynylation, asymmetric syntheses, allylic alkylation, nucleoside synthesis, cyclopentanation, hydrozirconation, to name a few. Emphasis has been placed on stereoselective and regioselective transformations as well as on enantioselective processes. The listing of reactions and reagents is supported by four indexes.