A revised edition of the well-received thermodynamics text, this work retains the thorough coverage and excellent organization that made the first edition so popular. Now incorporates industrially relevant microcomputer programs, with which readers can perform sophisticated thermodynamic calculations, including calculations of the type they will encounter in the lab and in industry. Also provides a unified treatment of phase equilibria. Emphasis is on analysis and prediction of liquid-liquid and vapor-liquid equilibria, solubility of gases and solids in liquids, solubility of liquids and solids in gases and supercritical fluids, freezing point depressions and osmotic equilibria, as well as traditional vapor-liquid and chemical reaction equilibria. Contains many new illustrations and exercises.
Chemical engineers face the challenge of learning the difficult concept and application of entropy and the 2nd Law of Thermodynamics. By following a visual approach and offering qualitative discussions of the role of molecular interactions, Koretsky helps them understand and visualize thermodynamics. Highlighted examples show how the material is applied in the real world. Expanded coverage includes biological content and examples, the Equation of State approach for both liquid and vapor phases in VLE, and the practical side of the 2nd Law. Engineers will then be able to use this resource as the basis for more advanced concepts.
Building up gradually from first principles, this unique introduction to modern thermodynamics integrates classical, statistical and molecular approaches and is especially designed to support students studying chemical and biochemical engineering. In addition to covering traditional problems in engineering thermodynamics in the context of biology and materials chemistry, students are also introduced to the thermodynamics of DNA, proteins, polymers and surfaces. It includes over 80 detailed worked examples, covering a broad range of scenarios such as fuel cell efficiency, DNA/protein binding, semiconductor manufacturing and polymer foaming, emphasizing the practical real-world applications of thermodynamic principles; more than 300 carefully tailored homework problems, designed to stretch and extend students' understanding of key topics, accompanied by an online solution manual for instructors; and all the necessary mathematical background, plus resources summarizing commonly used symbols, useful equations of state, microscopic balances for open systems, and links to useful online tools and datasets.
One of the goals of An Introduction to Applied Statistical Thermodynamics is to introduce readers to the fundamental ideas and engineering uses of statistical thermodynamics, and the equilibrium part of the statistical mechanics. This text emphasises on nano and bio technologies, molecular level descriptions and understandings offered by statistical mechanics. It provides an introduction to the simplest forms of Monte Carlo and molecular dynamics simulation (albeit only for simple spherical molecules) and user-friendly MATLAB programs for doing such simulations, and also some other calculations. The purpose of this text is to provide a readable introduction to statistical thermodynamics, show its utility and the way the results obtained lead to useful generalisations for practical application. The text also illustrates the difficulties that arise in the statistical thermodynamics of dense fluids as seen in the discussion of liquids.
Designed as an undergraduate-level textbook in Chemical Engineering, this student-friendly, thoroughly class-room tested book, now in its second edition, continues to provide an in-depth analysis of chemical engineering thermodynamics. The book has been so organized that it gives comprehensive coverage of basic concepts and applications of the laws of thermodynamics in the initial chapters, while the later chapters focus at length on important areas of study falling under the realm of chemical thermodynamics. The reader is thus introduced to a thorough analysis of the fundamental laws of thermodynamics as well as their applications to practical situations. This is followed by a detailed discussion on relationships among thermodynamic properties and an exhaustive treatment on the thermodynamic properties of solutions. The role of phase equilibrium thermodynamics in design, analysis, and operation of chemical separation methods is also deftly dealt with. Finally, the chemical reaction equilibria are skillfully explained. Besides numerous illustrations, the book contains over 200 worked examples, over 400 exercise problems (all with answers) and several objective-type questions, which enable students to gain an in-depth understanding of the concepts and theory discussed. The book will also be a useful text for students pursuing courses in chemical engineering-related branches such as polymer engineering, petroleum engineering, and safety and environmental engineering. New to This Edition • More Example Problems and Exercise Questions in each chapter • Updated section on Vapour–Liquid Equilibrium in Chapter 8 to highlight the significance of equations of state approach • GATE Questions up to 2012 with answers
This book covers the fundamentals of the rapidly growing field of biothermodynamics, showing how thermodynamics can best be applied to applications and processes in biochemical engineering. It describes the rigorous application of thermodynamics in biochemical engineering to rationalize bioprocess development and obviate a substantial fraction of t
Problem Solving in Chemical and Biochemical Engineering with POLYMATH", Excel, and MATLAB , Second Edition, is a valuable resource and companion that integrates the use of numerical problem solving in the three most widely used software packages: POLYMATH, Microsoft Excel, and MATLAB. Recently developed POLYMATH capabilities allow the automatic creation of Excel spreadsheets and the generation of MATLAB code for problem solutions. Students and professional engineers will appreciate the ease with which problems can be entered into POLYMATH and then solved independently in all three software packages, while taking full advantage of the unique capabilities within each package. The book includes more than 170 problems requiring numerical solutions. This greatly expanded and revised second edition includes new chapters on getting started with and using Excel and MATLAB. It also places special emphasis on biochemical engineering with a major chapter on the subject and with the integration of biochemical problems throughout the book. General Topics and Subject Areas, Organized by Chapter Introduction to Problem Solving with Mathematical Software Packages Basic Principles and Calculations Regression and Correlation of Data Introduction to Problem Solving with Excel Introduction to Problem Solving with MATLAB Advanced Problem-Solving Techniques Thermodynamics Fluid Mechanics Heat Transfer Mass Transfer Chemical Reaction Engineering Phase Equilibrium and Distillation Process Dynamics and Control Biochemical Engineering Practical Aspects of Problem-Solving Capabilities Simultaneous Linear Equations Simultaneous Nonlinear Equations Linear, Multiple Linear, and Nonlinear Regressions with Statistical Analyses Partial Differential Equations (Using the Numerical Method of Lines) Curve Fitting by Polynomials with Statistical Analysis Simultaneous Ordinary Differential Equations (Including Problems Involving Stiff Systems, Differential-Algebraic Equations, and Parameter Estimation in Systems of Ordinary Differential Equations) The Book's Web Site (http://www.problemsolvingbook.com) Provides solved and partially solved problem files for all three software packages, plus additional materials Describes discounted purchase options for educational version of POLYMATH available to book purchasers Includes detailed, selected problem solutions in Maple", Mathcad , and Mathematica"
The only textbook that applies thermodynamics to real-world process engineering problems This must-read for advanced students and professionals alike is the first book to demonstrate how chemical thermodynamics work in the real world by applying them to actual engineering examples. It also discusses the advantages and disadvantages of the particular models and procedures, and explains the most important models that are applied in process industry. All the topics are illustrated with examples that are closely related to practical process simulation problems. At the end of each chapter, additional calculation examples are given to enable readers to extend their comprehension. Chemical Thermodynamics for Process Simulation instructs on the behavior of fluids for pure fluids, describing the main types of equations of state and their abilities. It discusses the various quantities of interest in process simulation, their correlation, and prediction in detail. Chapters look at the important terms for the description of the thermodynamics of mixtures; the most important models and routes for phase equilibrium calculation; models which are applicable to a wide variety of non-electrolyte systems; membrane processes; polymer thermodynamics; enthalpy of reaction; chemical equilibria, and more. -Explains thermodynamic fundamentals used in process simulation with solved examples -Includes new chapters about modern measurement techniques, retrograde condensation, and simultaneous description of chemical equilibrium -Comprises numerous solved examples, which simplify the understanding of the often complex calculation procedures, and discusses advantages and disadvantages of models and procedures -Includes estimation methods for thermophysical properties and phase equilibria thermodynamics of alternative separation processes -Supplemented with MathCAD-sheets and DDBST programs for readers to reproduce the examples Chemical Thermodynamics for Process Simulation is an ideal resource for those working in the fields of process development, process synthesis, or process optimization, and an excellent book for students in the engineering sciences.
This book develops the theory of chemical thermodynamics from first principles, demonstrates its relevance across scientific and engineering disciplines, and shows how thermodynamics can be used as a practical tool for understanding natural phenomena and developing and improving technologies and products. Concepts such as internal energy, enthalpy, entropy, and Gibbs energy are explained using ideas and experiences familiar to students, and realistic examples are given so the usefulness and pervasiveness of thermodynamics becomes apparent. The worked examples illustrate key ideas and demonstrate important types of calculations, and the problems at the end of chapters are designed to reinforce important concepts and show the broad range of applications. Most can be solved using digitized data from open access databases and a spreadsheet. Answers are provided for the numerical problems. A particular theme of the book is the calculation of the equilibrium composition of systems, both reactive and non-reactive, and this includes the principles of Gibbs energy minimization. The overall approach leads to the intelligent use of thermodynamic software packages but, while these are discussed and their use demonstrated, they are not the focus of the book, the aim being to provide the necessary foundations. Another unique aspect is the inclusion of three applications chapters: heat and energy aspects of processing; the thermodynamics of metal production and recycling; and applications of electrochemistry. This book is aimed primarily at students of chemistry, chemical engineering, applied science, materials science, and metallurgy, though it will be also useful for students undertaking courses in geology and environmental science. A solutions manual is available for instructors.
