Industrial Catalysis provides an excellent introduction to catalytic principles and processes, addressing the applications of inorganic-, organic- and biocatalysts in industrial chemistry. Each chapter is focussed on one catalytic process and discusses its life cycle from source materials, catalyst synthesis, the catalytic process, lifetime and recovery. The book also includes a comprehensive overview on industrial processes employing catalysis.
With well over 90% of all processes in the industrial chemical production being of catalytic nature, catalysis is a mature though ever interesting topic. The idea of this book is to tackle various aspects of heterogeneous catalysis from the engineering point of view and go all the way from engineering of catalysis, catalyst preparation, characterization, reaction kinetics, mass transfer to catalytic reactors and the implementation of catalysts in chemical technology. Aimed for graduate students it is also a useful resource for professionals coming from the more academic side.
Immobilization of chiral catalysts is an important tool for improving overall efficiency of catalytic processes. However, heterogeneous catalysts often suffer from decreased activities and supported but still homogeneous catalysts can help overcome this issue. This book covers the most important concepts of homogeneous supported catalysis with an emphasis on enantioselective processes. It describes the state-of-the-art and latest developments in each area whilst critically evaluating the strengths and weaknesses of this important method. The book encompasses ionically-tagged catalysts, supported organocatalysts, supported ionic liquid phases, catalysis using soluble polymers, catalytic dendrimers, fluorous catalysts, water soluble catalysts and non-covalent immobilization methods. Potential developments and ideas for the future are also highlighted. There is a growing demand for effective and recyclable catalysts so this book, covering all the important methods in the field of supported homogeneous catalysis, will appeal to many researchers in academia and industry.
The current book brings together cutting-edge research in the area of heterogeneous catalytic redox processes. The first part of the book covers the catalytic properties of transition metal oxides and the techniques for catalysts preparation, such as mechanochemistry, plasmochemistry, hydrothermal treatment, etc. Further the authors focus on mechanisms of heterogeneous redox reactions followed by the overview of industrial applications.
A wide range of chemical products (especially fine chemicals) are important for a healthy and enjoyable modern life; therefore efficient syntheses of these materials are essential. Traditional stoichiometric processes need to be replaced by modern catalytical methods in the change to sustainable chemistry and the production of lower amounts of waste. This book summarizes the wide variety of catalytic methods that have been developed and applied on an industrial scale in recent years to fulfill this goal. The synthesis of compound classes such as pharmaceuticals, agrochemicals, flavoring, and fragrance compounds as well as food additives such as vitamins exemplify the use of these modern catalytic methods in the modern chemical industry.
The aim of this book is to present in a single volume an up-to-date account of the chemistry and chemical engineering which underlie the major areas of the chemical process industry. This most recent edition includes several new chapters which comprise important threads in the industry's total fabric. These new chapters cover waste minimization, safety considerations in chemical plant design and operation, emergency response planning, and statistical applications in quality control and experimental planning. Together with the chapters on chemical industry economics and wastewater treatment~ they provide a unifying base on which the reader can most effectively apply the information provided in the chapters which describe the various areas of the chemical process industries. The ninth edition of this established reference work contains the contributions of some fifty experts from industry, government, and academe. I have been humbled by the breadth and depth of their knowledge and expertise and by the willingness and enthusiasm with which they shared their knowledge and insights. They have, without exception, been unstinting in their efforts to make their respective chapters as complete and informative as possible within the space available. Errors of omission, duplication, and shortcomings in organization are mine. Grateful acknowledgment is made to the editors of technical journals and publishing houses for permission to reproduce illustrations and other materials and to the many industrial concerns which contributed drawings and photographs. Comments and criticisms by readers will be welcome.
Substantially revising and updating the classic reference in the field, this handbook offers a valuable overview and myriad details on current chemical processes, products, and practices. No other source offers as much data on the chemistry, engineering, economics, and infrastructure of the industry. The Handbook serves a spectrum of individuals, from those who are directly involved in the chemical industry to others in related industries and activities. It provides not only the underlying science and technology for important industry sectors, but also broad coverage of critical supporting topics. Industrial processes and products can be much enhanced through observing the tenets and applying the methodologies found in chapters on Green Engineering and Chemistry (specifically, biomass conversion), Practical Catalysis, and Environmental Measurements; as well as expanded treatment of Safety, chemistry plant security, and Emergency Preparedness. Understanding these factors allows them to be part of the total process and helps achieve optimum results in, for example, process development, review, and modification. Important topics in the energy field, namely nuclear, coal, natural gas, and petroleum, are covered in individual chapters. Other new chapters include energy conversion, energy storage, emerging nanoscience and technology. Updated sections include more material on biomass conversion, as well as three chapters covering biotechnology topics, namely, Industrial Biotechnology, Industrial Enzymes, and Industrial Production of Therapeutic Proteins.
This introductory textbook covers all aspects of catalysis. It also bridges computational methods, industrial applications and green chemistry, with over 600 references. The book is aimed at chemistry and chemical engineering students, and is suitable for both senior undergraduate- and graduate-level courses, with many examples and hands-on exercises. The author, a renowned researcher in catalysis, is well known for his clear teaching and writing style (he was voted "lecturer of the year" by the chemistry students). Following an introduction to green chemistry and the basics of catalysis, the book covers the principles and applications of homogeneous catalysis, heterogeneous catalysis and biocatalysis. Each chapter includes up-to-date industrial examples, that demonstrate how catalysis helps our society reach the goals of sustainable development. Since its publication in 2008, Catalysis: Concepts and Green Applications has become the most popular textbook in catalysis. This second edition is updated with the latest developments in catalysis research in academia and industry. It also contains 50 additional exercises, based on the suggestions of students and teachers of chemistry and chemical engineering from all over the world. The book is also available in the Chinese language (https://detail.tmall.com/item.htm?spm=a212k0.12153887.0.0.4e60687dUTEDKm&id=619581126247). Additional teaching material (original figures as PowerPoint lecture slides) is freely available in the Supplementary Material.
Catalytic Kinetics: Chemistry and Engineering, Second Edition offers a unified view that homogeneous, heterogeneous, and enzymatic catalysis form the cornerstone of practical catalysis. The book has an integrated, cross-disciplinary approach to kinetics and transport phenomena in catalysis, but still recognizes the fundamental differences between different types of catalysis. In addition, the book focuses on a quantitative chemical understanding and links the mathematical approach to kinetics with chemistry. A diverse group of catalysts is covered, including catalysis by acids, organometallic complexes, solid inorganic materials, and enzymes, and this fully updated second edition contains a new chapter on the concepts of cascade catalysis. Finally, expanded content in this edition provides more in-depth discussion, including topics such as organocatalysis, enzymatic kinetics, nonlinear dynamics, solvent effects, nanokinetics, and kinetic isotope effects. - Fully revised and expanded, providing the latest developments in catalytic kinetics - Bridges the gaps that exist between hetero-, homo- and enzymatic-catalysis - Provides necessary tools and new concepts for researchers already working in the field of catalytic kinetics - Written by internationally-renowned experts in the field - Examples and exercises following each chapter make it suitable as an advanced course book
The editors and authors, with backgrounds in academia and industry, tie together recent and established technologies for the upcoming change to sustainable industrial chemistry. The extensive worldwide activities towards that goal are exemplified with a series of green processes. Some of these processes are already commercially applied (squalene to squalane, hydraulic fluids from vegetable oils, biosourced polycarbonates), others are ready for a large scale implementation (glycerol to acrylic acid, biosourced acrylonitrile and levulinic acid, polyamides from fatty nitriles-esters hydrogenation, butadiene from bioethanol) or are being developed (cyclic carbonates from epoxides, selective pyrolysis of biomass). This book is an indispensable source for the researchers and professionals who work for a greener chemical industry. The chapters have been arranged to guide students through the design of new processes for more sustainable chemistry, using case studies as examples.
