The book follows the 2002 edition of Catalysis by Ceria and Related Materials, which was the first book entirely devoted to ceria and its catalytic properties. It covers fundamental and applied aspects of the latest advances in ceria-based materials with a special focus on structural, redox and catalytic features of nano-engineered systems. In addition, it presents recent advances of traditional large-scale applications of ceria in catalysis, such as the treatment of emissions from mobile sources (including diesel and gasoline engines).
The use of CeO2-based materials in catalysis has attracted considerable attention in recent years, particularly in applications like environmental catalysis, where ceria has shown great potential. This book critically reviews the most recent advances in the field, with the focus on both fundamental and applied issues. The first few chapters cover structural and chemical properties of ceria and related materials, i.e. phase stability, reduction behaviour, synthesis, interaction with probe molecules (CO, O2, NO), and metal-support interaction — all presented from the viewpoint of catalytic applications. The use of computational techniques and ceria surfaces and films for model catalytic studies are also reviewed. The second part of the book provides a critical evaluation of the role of ceria in the most important catalytic processes: three-way catalysis, catalytic wet oxidation and fluid catalytic cracking. Other topics include oxidation-combustion catalysts, electrocatalysis and the use of cerium catalysts/additives in diesel soot abatement technology.
This book follows the 2002 edition of Catalysis by Ceria and Related Materials, which was the first book entirely devoted to ceria and its catalytic properties. In the ten years since the first edition a massive amount of work has been carried out in the field, and ceria has gained a prominent position in catalysis as one of the most valuable material for several applications. This second edition covers fundamental and applied aspects of the latest advances in ceria-based materials with a special focus on structural, redox and catalytic features. Special emphasis is given to nano-engineered and nano-shaped systems which are a key factor in the predictive and rational design of ceria with novel properties.In addition, the book presents recent advances in emerging and traditional large-scale applications of ceria in catalysis, such as the treatment of emissions from mobile sources (including diesel and gasoline engines). The primary readership includes catalysis and material science researchers from academy and industry and postdoctorate and graduate students in chemistry, chemical engineering and physics.
This book follows the 2002 edition of Catalysis by Ceria and Related Materials, which was the first book entirely devoted to ceria and its catalytic properties. In the ten years since the first edition a massive amount of work has been carried out in the field, and ceria has gained a prominent position in catalysis as one of the most valuable material for several applications. This second edition covers fundamental and applied aspects of the latest advances in ceria-based materials with a special focus on structural, redox and catalytic features. Special emphasis is given to nano-engineered and nano-shaped systems which are a key factor in the predictive and rational design of ceria with novel properties.In addition, the book presents recent advances in emerging and traditional large-scale applications of ceria in catalysis, such as the treatment of emissions from mobile sources (including diesel and gasoline engines). The primary readership includes catalysis and material science researchers from academy and industry and postdoctorate and graduate students in chemistry, chemical engineering and physics.
Catalysis by Materials with Well-Defined Structures examines the latest developments in the use of model systems in fundamental catalytic science. A team of prominent experts provides authoritative, first-hand information, helping readers better understand heterogeneous catalysis by utilizing model catalysts based on uniformly nanostructured materials. The text addresses topics and issues related to material synthesis, characterization, catalytic reactions, surface chemistry, mechanism, and theoretical modeling, and features a comprehensive review of recent advances in catalytic studies on nanomaterials with well-defined structures, including nanoshaped metals and metal oxides, nanoclusters, and single sites in the areas of heterogeneous thermal catalysis, photocatalysis, and electrocatalysis. Users will find this book to be an invaluable, authoritative source of information for both the surface scientist and the catalysis practitioner - Outlines the importance of nanomaterials and their potential as catalysts - Provides detailed information on synthesis and characterization of nanomaterials with well-defined structures, relating surface activity to catalytic activity - Details how to establish the structure-catalysis relationship and how to reveal the surface chemistry and surface structure of catalysts - Offers examples on various in situ characterization instrumental techniques - Includes in-depth theoretical modeling utilizing advanced Density Functional Theory (DFT) methods
"Spillover and Mobility of Species and Solid Surfaces" collects the papers which were presented at the Fifth International Conference Spillover, either as oral or poster contributions, as well as the summaries of the invited lectures. This congress and its publication in the Studies on Surface Science and Catalysis series follow the tradition of previous conferences on spillover, initiated in Lyon, 1983, and continued in Leipzig, 1989, Kyoto 1993 and Dalian, 1997. For the fifth conference, held in S.L. el Escorial (Madrid), the organising committee has attempted to compile representative contributions which illustrate the advances in understanding the spillover phenomenon since 1997. Spillover is a process taking place during the interface of gas reactant molecules (mainly hydrogen and oxygen) on solid surfaces. However, different contributions to the more general area of the chemistry at surfaces, related with the mobility and migration of species, diffusion through membranes, fuel cell catalysts, etc., have also been included. In fact the title of the present volume summarizes this attempt to extend the conference topics towards dynamics at surfaces.Among the 70 contributions received, the 56 accepted papers were selected on the basis of the reports of at least two international reviewers, according to standards comparable to those applied for other specialised journals. These papers are from 21 different countries.
Cerium Oxide (CeO2): Synthesis, Properties and Applications provides an updated and comprehensive account of the research in the field of cerium oxide based materials. The book is divided into three main blocks that deal with its properties, synthesis and applications. Special attention is devoted to the growing number of applications of ceria based materials, including their usage in industrial and environmental catalysis and photocatalysis, energy production and storage, sensors, cosmetics, radioprotection, glass technology, pigments, stainless steel and toxicology. A brief historical introduction gives users background, and a final chapter addresses future perspectives and outlooks to stimulate future research. The book is intended for a wide audience, including students, academics and industrial researchers working in materials science, chemistry and physics. - Addresses a wide range of applications of ceria-based materials, including catalysis, energy production and storage, sensors, cosmetics and toxicology - Provides the fundamentals of ceria-based materials, including synthesis methods, materials properties, toxicology and surface chemistry - Includes nanostructured ceria-based materials and a discussion of future prospects and outlooks
Binary Rare Earth Oxides is the first book in the field of rare earth oxides that provides coverage from the basic science through to recent advances. This book introduces the unique characteristics of the binary rare earth oxides with their chemistry, physics and applications. It provides a comprehensive review of all the characteristics of rare earth oxides, essential for scientists and engineers involved with rare earths, oxides, inorganic materials, ceramics, and structures. The binary rare earth oxides bring us a variety of interesting characteristics. Understanding their fundamental mechanisms builds a bridge between solid-state chemistry and materials science. The book begins with a brief introduction to binary rare earth oxides, their physical and chemical stabilities, polymorphism, crystal structures and phase transformation and the association with current applications. The book goes on to present the band structure of the oxides using several quantum chemical calculations, which belong to a newly developed area in the binary rare earth oxides. Central to this chapter are the characterizations of electrical, magnetic and optical properties, as well as details of single crystal growth and particle preparation methods that have progressed in recent years. Later chapters concentrate on thermo-chemical properties and trace determination techniques. The final chapter contains a variety of useful applications in various fields such as phosphors, glass abrasives, automotive catalysts, fuel cells, solid electrolytes, sunscreens, iron steels, and biological materials. This book is an invaluable resource for materials scientists and solid-state physicists and chemists with an interest in rare earth oxides, as well as advanced students and graduates who require an approach to familiarize them with this field. This book provides guidance through a comprehensive review of all the characteristics of binary rare earth oxides.
This book gives an introduction to nanostructured materials and guides the reader through their different engineering applications. It addresses the special phenomena and potentials involved in the applications without going into too much scientific detail of the physics and chemistry involved, which makes the reading interesting for beginners in the field. Materials for different applications in engineering are described, such as those used in opto-electronics, energy, tribology, bio-applications, catalysis, reinforcement and many more. In each application chapter, the reader will learn about the phenomena involved in the application, the nanostructured materials used in the field and their processing, besides finding some practical examples of their use in laboratories and in industry.The clear language and the application-oriented perspective of the book makes it suitable for both engineers and students who want to learn about applications of nanostructured materials in Engineering.
(Selected) -- Plenary Lecures: New Catalysts for Controlled/Living Atom Transfer Radical Polymerization (ATRP; Catalysis and Applications of Gold Nanoparticles -- Oral Presentations: Ionic Liquids as New Solvents and Catalysis for Petrochemical and Refining Processes; High Throughput Experiment on the Investigation of Oxidation Catalysts with Gas Sensor System -- Poster Presentations: Development of a Low-Temperature Dioxin Decomposition Catalyst; Studies on Unique Properties of Polyolefins Prepared with Metallocene Catalyst Systems -- Index.
