The replacement of polyols synthesized from petrochemical by polyols originating from natural products, notably from vegetable oils and animal fats, has been the subject of research projects for a number of decades. Very recently, however, the polymers industry has intensified its efforts to include the "green products", such as biobased polyols, in applications already available in the market. Examples of such applications include polyurethane foams, elastomers and epoxides. This book describes the extraction of the natural constituents of several fruits and plants as well as their chemical conversion to polyols. In addition to the chemistry involved in the process, particular emphasis is attributed to their applications.
This brief outlines the most recent advances in the production of polyols and polyurethanes from renewable resources, mainly vegetable oils, lignocellulosic biomass, starch, and protein. The typical processes for the production of polyols from each of the above mentioned feedstocks are introduced and the properties of the resultant polyols and polyurethanes are also discussed.
This ACS Symposium Series is the product of a symposium held at the 241st National Meeting of the American Chemical Society. 2011. It includes chapters on new biobased building blocks such as the furandicarboxylic acid, polyesters and polyamides from adipic, succinic and sebacic acids with aliphatic diols such as 1,3-propylene glycol, 1,4-butanediol, 1,12-dodecylenediol and isosorbide.
Bio-based Plant Oil Polymers and Composites provides engineers and materials scientists a useful framework to help take advantage of the latest research conducted in this rapidly advancing field—enabling them to develop and commercialize their own products quickly and more successfully. Plant oil is one of the most attractive options as a substitute for non-renewable resources in polymers and composites, and is producing materials with very promising thermomechanical properties relative to traditional, petroleum-based polymers. In addition to critical processing and characterization information, the book assists engineers in deciding whether or not they should use a plant oil-based polymer over a petroleum-based polymer, discussing sustainability concerns, biodegradability, associated costs, and recommended applications. The book details the advancements in the development of polymeric materials and composites from plant oils, and provides a critical review of current applications in various fields, including packaging, biomedical, and automotive applications. Also includes the latest progress in developing multifunctional biobased polymers—by increasing thermal conductivity or adding antibacterial properties, for example. - Essential coverage of processing, characterization, and the latest research into polymeric materials and composites derived from plant oils (thermoplastics, thermosets, nanocomposites, and fiber reinforced composites) - Critically reviews the potential applications of plant oil-based polymers, including sensors, structural parts, medical devices, and automotive interiors - Includes the latest developments in multifunctional bio-based polymer composites
Reactive Polymers: Fundamentals and Applications: A Concise Guide to Industrial Polymers, Third Edition introduces engineers and scientists to a range of reactive polymers and then details their applications and performance benefits. Basic principles and industrial processes are described for each class of reactive resin (thermoset), as well as additives, the curing process, applications and uses. The initial chapters are devoted to individual resin types (e.g., epoxides, cyanacrylates), followed by more general chapters on topics such as reactive extrusion and dental applications. Injection molding of reactive polymers, radiation curing, thermosetting elastomers, and reactive extrusion equipment are covered as well. The use of reactive polymers enables manufacturers to make chemical changes at a late stage in the production process, which, in turn, cause changes in performance and properties. Material selection and control of the reaction are essential to achieve optimal performance. Material new to this edition includes the most recent developments, applications and commercial products for each chemical class of thermosets, as well as sections on fabrication methods, reactive biopolymers, recycling of reactive polymers and case studies. - Covers the basics and most recent developments, including reactive biopolymers, recycling of reactive polymers, nanocomposites and fluorosilicones - Offers an indispensable guide for engineers and advanced students alike - Provides extensive literature and patent review - Reflects a thorough review of all literature published in this area since 2014 - Features revised and updated chapters to reflect the latest research in reactive polymers
The polyurethane industry is among the fastest growing, with polyurethanes used in consumer as well as industrial sectors. Waterborne polyurethanes (WPUs) exhibit many advantages over conventional volatile organic compounds (VOCs) based polyurethanes and have emerged as an environmentally friendly alternative. WPUs offer an opportunity to use sustainable raw materials to produce environmentally sustainable polymers, particularly, polyols derived from vegetable oils. Eco-Friendly Waterborne Polyurethanes: Synthesis, Properties, and Applications provides state-of-the-art knowledge of the synthesis, application, and property enhancement of WPUs. Covers various types of eco-friendly materials and technologies used to synthesize WPUs Presents an overview and applications of WPUs in several advanced research areas Provides fundamentals of synthetic processes and their chemistries for specific applications Elaborates on advanced approaches used to convert renewable resources into polymers Offers new direction to scientists, researchers, and students to better understand the chemistry, technologies, and applications Written for polymer chemists, materials scientists, and other researchers and industry, this book serves as a comprehensive reference for readers interested in the development and application of sustainable polymers.
Bio-Based Packaging Bio-Based Packaging An authoritative and up-to-date review of sustainable packaging development and applications Bio-Based Packaging explores using renewable and biodegradable materials as sustainable alternatives to non-renewable, petroleum-based packaging. This comprehensive volume surveys the properties of biopolymers, the environmental and economic impact of bio-based packaging, and new and emerging technologies that are increasing the number of potential applications of green materials in the packaging industry. Contributions address the advantages and challenges of bio-based packaging, discuss new materials to be used for food packaging, and highlight cutting-edge research on polymers such as starch, protein, polylactic acid (PLA), pectin, nanocellulose, and their nanocomposites. In-depth yet accessible chapters provide balanced coverage of a broad range of practical topics, including life cycle assessment (LCA) of bio-based packaging products, consumer perceptions and preferences, supply chains, business strategies and markets in biodegradable food packaging, manufacturing of bio-based packaging materials, and regulations for food packaging materials. Detailed discussions provide valuable insight into the opportunities for biopolymers in end-use sectors, the barriers to biopolymer-based concepts in the packaging market, recent advances made in the field of biopolymeric composite materials, the future of bio-plastics in commercial food packaging, and more. This book: Provides deep coverage of the bio-based packaging development, characterization, regulations and environmental and socio-economic impact Contains real-world case studies of bio-based packaging applications Includes an overview of recent advances and emerging aspects of nanotechnology for development of sustainable composites for packaging Discusses renewable sources for packaging material and the reuse and recycling of bio-based packaging products Bio-Based Packaging is essential reading for academics, researchers, and industry professionals working in packaging materials, renewable resources, sustainability, polymerization technology, food technology, material engineering, and related fields. For more information on the Wiley Series in Renewable Resources, visit www.wiley.com/go/rrs
Bio-Based Polymers and Composites is the first book systematically describing the green engineering, chemistry and manufacture of biobased polymers and composites derived from plants. This book gives a thorough introduction to bio-based material resources, availability, sustainability, biobased polymer formation, extraction and refining technologies, and the need for integrated research and multi-disciplinary working teams. It provides an in-depth description of adhesives, resins, plastics, and composites derived from plant oils, proteins, starches, and natural fibers in terms of structures, properties, manufacturing, and product performance. This is an excellent book for scientists, engineers, graduate students and industrial researchers in the field of bio-based materials.* First book describing the utilization of crops to make high performance plastics, adhesives, and composites* Interdisciplinary approach to the subject, integrating genetic engineering, plant science, food science, chemistry, physics, nano-technology, and composite manufacturing.* Explains how to make green materials at low cost from soyoil, proteins, starch, natural fibers, recycled newspapers, chicken feathers and waste agricultural by-products.
