Flow batteries have received attention in large-scale energy storage due to their flexible design, high safety, high energy efficiency, and environmental friendliness. In recent years, they have been rapidly developed and tested in a variety of scales that prove their feasibility and advantages of use. As energy becomes a global focus, it is important to consider flow battery systems. This book offers a detailed introduction to the function of different kinds of redox flow batteries, including vanadium flow batteries, as well as the electrochemical processes for their development, materials and components, applications, and near future prospects. Redox Flow Batteries: Fundamentals and Applications will give readers a full understanding of flow batteries from fundamentals to commercial applications.
This book presents studies and discussions on anionic redox, which can be used to boost the capacities of cathode electrodes by providing extra electron transfer. This theoretically and practically significant book facilitates the implementation of anionic redox in electrodes for real-world use and accelerates the development of high-energy-density lithium-ion batteries. Lithium-ion batteries, as energy storage systems, are playing a more and more important role in powering modern society. However, their energy density is still limited by the low specific capacity of the cathode electrodes. Based on a profound understanding of band theory, the author has achieved considerable advances in tuning the redox process of lithium-rich electrodes to obtain enhanced electrochemical performance, identifying both the stability mechanism of anionic redox in lithium-rich cathode materials, and its activation mechanism in these electrode systems.
Part of the Encyclopedia of Electrochemistry, this comprehensive, two-volume handbook offers an up-to-date and in-depth review of the battery technologies in use today. It also includes information on the most likely candidates that hold the potential for further enhanced energy and power densities. It contains contributions from a renowned panel of international experts in the field. Batteries are extremely commonplace in modern day life. They provide electrochemically stored energy in the form of electricity to automobiles, aircrafts, electronic devices and to smart power grids. Comprehensive in scope, 'Batteries' covers information on well-established battery technologies such as charge-carrier-based lead acid and lithium ion batteries. The contributors also explore current developments on new technologies such as lithium-sulfur and -oxygen, sodium ion, and full organic batteries. Written for electrochemists, physical chemists, and materials scientists, 'Batteries' is an accessible compendium that offers a thorough review of the most relevant current battery technologies and explores the technology in the years to come.
A lithium-ion battery comprises essentially three components: two intercalation compounds as positive and negative electrodes, separated by an ionic-electronic electrolyte. Each component is discussed in sufficient detail to give the practising engineer an understanding of the subject, providing guidance on the selection of suitable materials in actual applications. Each topic covered is written by an expert, reflecting many years of experience in research and applications. Each topic is provided with an extensive list of references, allowing easy access to further information. Readership: Research students and engineers seeking an expert review. Graduate courses in electrical drives can also be designed around the book by selecting sections for discussion. The coverage and treatment make the book indispensable for the lithium battery community.
This book covers both the fundamental and applied aspects of advanced Na-ion batteries (NIB) which have proven to be a potential challenger to Li-ion batteries. Both the chemistry and design of positive and negative electrode materials are examined. In NIB, the electrolyte is also a crucial part of the batteries and the recent research, showing a possible alternative to classical electrolytes – with the development of ionic liquid-based electrolytes – is also explored. Cycling performance in NIB is also strongly associated with the quality of the electrode-electrolyte interface, where electrolyte degradation takes place; thus, Na-ion Batteries details the recent achievements in furthering knowledge of this interface. Finally, as the ultimate goal is commercialization of this new electrical storage technology, the last chapters are dedicated to the industrial point of view, given by two startup companies, who developed two different NIB chemistries for complementary applications and markets.
The Essential Reference for the Field, Featuring Protocols, Analysis, Fundamentals, and the Latest Advances Impedance Spectroscopy: Theory, Experiment, and Applications provides a comprehensive reference for graduate students, researchers, and engineers working in electrochemistry, physical chemistry, and physics. Covering both fundamentals concepts and practical applications, this unique reference provides a level of understanding that allows immediate use of impedance spectroscopy methods. Step-by-step experiment protocols with analysis guidance lend immediate relevance to general principles, while extensive figures and equations aid in the understanding of complex concepts. Detailed discussion includes the best measurement methods and identifying sources of error, and theoretical considerations for modeling, equivalent circuits, and equations in the complex domain are provided for most subjects under investigation. Written by a team of expert contributors, this book provides a clear understanding of impedance spectroscopy in general as well as the essential skills needed to use it in specific applications. Extensively updated to reflect the field’s latest advances, this new Third Edition: Incorporates the latest research, and provides coverage of new areas in which impedance spectroscopy is gaining importance Discusses the application of impedance spectroscopy to viscoelastic rubbery materials and biological systems Explores impedance spectroscopy applications in electrochemistry, semiconductors, solid electrolytes, corrosion, solid state devices, and electrochemical power sources Examines both the theoretical and practical aspects, and discusses when impedance spectroscopy is and is not the appropriate solution to an analysis problem Researchers and engineers will find value in the immediate practicality, while students will appreciate the hands-on approach to impedance spectroscopy methods. Retaining the reputation it has gained over years as a primary reference, Impedance Spectroscopy: Theory, Experiment, and Applications once again present a comprehensive reference reflecting the current state of the field.
The electrochemical energy storage is a means to conserve electrical energy in chemical form. This form of storage benefits from the fact that these two energies share the same vector, the electron. This advantage allows us to limit the losses related to the conversion of energy from one form to another. The RS2E focuses its research on rechargeable electrochemical devices (or electrochemical storage) batteries and supercapacitors. The materials used in the electrodes are key components of lithium-ion batteries. Their nature depend battery performance in terms of mass and volume capacity, energy density, power, durability, safety, etc. This book deals with current and future positive and negative electrode materials covering aspects related to research new and better materials for future applications (related to renewable energy storage and transportation in particular), bringing light on the mechanisms of operation, aging and failure.
This new volume covers the latest developments in the field of electrochemistry. It addresses a variety of topics including new materials development, materials synthesis, processing, characterization, property measurements, structure-property relationships, and device performance. A broader view of various electrochemical energy conversion devices make this book a critical read for scientists and engineers working in related fields. Papers from the symposium at the 102nd Annual Meeting of The American Ceramic Society, April 29-May 3, 2000, Missouri and the 103rd Annual Meeting, April 22-25, 2001, Indiana.
Energy Storage explains the underlying scientific and engineering fundamentals of all major energy storage methods. These include the storage of energy as heat, in phase transitions and reversible chemical reactions, and in organic fuels and hydrogen, as well as in mechanical, electrostatic and magnetic systems. Updated coverage of electrochemical storage systems considers exciting developments in materials and methods for applications such as rapid short-term storage in hybrid and intermittent energy generation systems, and battery optimization for increasingly prevalent EV and stop-start automotive technologies. This nuanced coverage of cutting-edge advances is unique in that it does not require prior knowledge of electrochemistry. Traditional and emerging battery systems are explained, including lithium, flow and liquid batteries. Energy Storage provides a comprehensive overview of the concepts, principles and practice of energy storage that is useful to both students and professionals.
Starting out with an introduction to the fundamentals of lithium ion batteries, this book begins by describing in detail the new materials for all four major uses as cathodes, anodes, separators, and electrolytes. It then goes on to address such critical issues as self-discharge and passivation effects, highlighting lithium ion diffusion and its profound effect on a battery's power density, life cycle and safety issues. The monograph concludes with a detailed chapter on lithium ion battery use in hybrid electric vehicles. Invaluable reading for materials scientists, electrochemists, physicists, and those working in the automobile and electrotechnical industries, as well as those working in computer hardware and the semiconductor industry.