Analytical Chemistry of Uranium

Analytical Chemistry of Uranium

Author: Zeev Karpas

Publisher: CRC Press

Published: 2014-11-21

Total Pages: 328

ISBN-13: 148222058X

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Accurate uranium analysis, and particularly for isotope measurements, is essential in many fields, including environmental studies, geology, hydrogeology, the nuclear industry, health physics, and homeland security. Nevertheless, only a few scientific books are dedicated to uranium in general and analytical chemistry aspects in particular. Analytical Chemistry of Uranium: Environmental, Forensic, Nuclear, and Toxicological Applications covers the fascinating advances in the field of analytical chemistry of uranium. Exploring a broad range of topics, the book focuses on the analytical aspects of industrial processes that involve uranium, its presence in the environment, health and biological implications of exposure to uranium compounds, and nuclear forensics. Topics include: Examples of procedures used to characterize uranium in environmental samples of soil, sediments, vegetation, water, and air Analytical methods used to examine the rigorous specifications of uranium and its compounds deployed in the nuclear fuel cycle Health aspects of exposure to uranium and the bioassays used for exposure assessment Up-to-date analytical techniques used in nuclear forensics for safeguards in support of non-proliferation, including single particle characterization Each chapter includes an overview of the topic and several examples to demonstrate the analytical procedures. This is followed by sample preparation, separation and purification techniques where necessary. The book supplies readers with a solid understanding of the analytical chemistry approach used today for characterizing the different facets of uranium, providing a good starting point for further investigation into this important element.


Nuclear Techniques in Analytical Chemistry

Nuclear Techniques in Analytical Chemistry

Author: Alfred J. Moses

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 153

ISBN-13: 1483157040

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Nuclear Techniques in Analytical Chemistry discusses highly sensitive nuclear techniques that determine the micro- and macro-amounts or trace elements of materials. With the increasingly frequent demand for the chemical determination of trace amounts of elements in materials, the analytical chemist had to search for more sensitive methods of analysis. This book accustoms analytical chemists with nuclear techniques that possess the desired sensitivity and applicability at trace levels. The topics covered include safe handling of radioactivity; measurement of natural radioactivity; and neutron activation analysis. The positive ion and gamma ray activation analysis; isotope dilution and tracer investigations of analytical techniques; and geo- and cosmochronology and miscellaneous nuclear techniques are also elaborated in this text. This publication is intended for analytical chemists, but is also valuable to students intending to acquire knowledge on nuclear techniques and analytical methods in chemistry.


The Analytical Chemistry of Thorium

The Analytical Chemistry of Thorium

Author: D. I. Ryabchikov

Publisher: Elsevier

Published: 2013-10-22

Total Pages: 331

ISBN-13: 1483156591

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International Series of Monographs on Analytical Chemistry, Volume 10: The Analytical Chemistry of Thorium focuses on the composition, properties, and reactions of thorium. The book first discusses the occurrence of thorium and its properties. Topics include the position of thorium in the periodic system; methods of preparation for metallic thorium; and radioactivity of thorium isotopes. The text surveys the chemical and physical methods in identifying thorium. Gravimetric and fluorescence methods; detection and estimation of thorium by spectroscopic and X-ray analysis; and colorimetric and spectrophotometric methods are discussed. The text also examines the methods of separating thorium from associated elements. The separation of thorium from rare earths, scandium, titanium, uranium, lead, alkali metals, gallium, and beryllium is underscored. The text also discusses the determination of thorium in natural and industrial materials. Regeneration of thorium from industrial waste; isolation of thorium from ores and minerals; and analysis of alloys containing thorium are explained. The book is a valuable source of data for students and chemists wanting to study thorium.


Analytical Applications of Nuclear Techniques

Analytical Applications of Nuclear Techniques

Author:

Publisher: IAEA

Published: 2004

Total Pages: 224

ISBN-13:

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The IAEA has compiled this overview of current applications of nuclear analytical techniques (NATs). The contributions included in this book describe a variety of nuclear techniques and applications, such as those in the fields of environment and health, industrial processes, non-destructive testing, forensic and archaeological investigations, cosmochemistry and method validation. The techniques covered range from classical instrumental neutron activation analysis (INAA), its radiochemical derivative RNAA, in-beam methods such as prompt y neutron activation analysis (PGNAA) and accelerator mass spectrometry (AMS), to X ray fluorescence (XRF) and proton induced X ray emission (PIXE) spectroscopy. Isotopic techniques to investigate element behaviour in biology and medicine, and also to validate other non-nuclear analytical techniques, are described. Destructive and non-destructiveapproaches are presented, along with their use to investigate very small and very large samples, archaeological samples and extraterrestrial samples. Several nuclear analytical applications in industry are described that have considerable socioeconomic impact wherever they can be implemented.


Chemical Thermodynamics of Uranium

Chemical Thermodynamics of Uranium

Author: Ingmar Grenthe

Publisher: Elsevier Science & Technology

Published: 1992

Total Pages: 744

ISBN-13:

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This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.