Das umfassende Handbuch der Atomspektroskopie jetzt in sorgfältig überarbeiteter, noch besser organisierter zweiter Auflage! Ergänzt wurden Kapitel zu wichtigen neuen Verfahren wie der Plasma-Atomemissionsspektroskopie und der ICP-Massenspektrometrie. Fettgedruckte Stichworte, übersichtliche Diagramme und praktische Übungen erleichtern das Erarbeiten und Vertiefen des Stoffes. (02/98)
This completely revised second edition of the standard work has been expanded by some twenty percent to include more information on the latest developments and new apparatus. In particular, sections have been added on microplasmas and new types of spectrometers, while that on the rapidly expanding field of speciations with practical examples from life and environmental sciences have been included. Still in one handy volume, the book covers all the important modern aspects of atomic fluorescence, emission and absorption spectroscopy as well as plasma mass spectroscopy in a readily comprehensible and practice-oriented manner. A thorough explanation of the physical, theoretical and technical basics, example applications including the concrete execution of analysis and comprehensive cross-references to the latest literature allow even newcomers easy access to the methodologies described.
This book describes both the theory of atomic spectroscopy and all the major atomic spectrometric techniques (AAS, Flame-AES, Plasma AES, AFS, and ICP-MS), including basic concepts, instrumentation and applications. Spectrochemical Analysis by Atomic Absorption and Emission is very wide in scope and will be extremely useful to both undergraduates and lecturers undertaking modern analytical chemistry courses. It contains many figures and tables which illuminate the text, covers various sample preparation methods and gives suggestions for further reading.
The first edition of this book was a first book for atomic spectroscopists to present the basic principles of experimental designs, optimization and multivariate regression. Multivariate regression is a valuable statistical method for handling complex problems (such as spectral and chemical interferences) which arise during atomic spectrometry. However, the technique is underused as most spectroscopists do not have time to study the often complex literature on the subject. This practical introduction uses conceptual explanations and worked examples to give readers a clear understanding of the technique. Mathematics is kept to a minimum but, when required, is kept at a basic level. Practical considerations, interpretations and troubleshooting are emphasized and literature surveys are included to guide the reader to further work. The same dataset is used for all chapters dealing with calibration to demonstrate the differences between the different methodologies. Readers will learn how to handle spectral and chemical interferences in atomic spectrometry in a new, more efficient and cost-effective way.
The book provides an up-to-date account of inductively coupled plasmas and their use in atomic emission spectroscopy and mass spectrometry. Specific applications of the use of these techniques are highlighted including applications in environmental, food and industrial analysis. It is written in a distance learning / open learning style; suitable for self study applications. It contains contain self-assessment and discussion questions, worked examples and case studies that allow the reader to test their understanding of the presented material.
High-resolution continuum source atomic absorption spectrometry (HR-CS AAS) is the most revolutionary innovation since the introduction of AAS in 1955. Here, the authors provide the first complete and comprehensive discussion of HR-CS AAS and its application to the analysis of a variety of difficult matrices. Published just in time with the first commercial instrument available for this new technique, the book is a must for all those who want to know more about HR-CS AAS, and in particular for all future users. The advantages of the new technique over conventional line-source AAS are clearly demonstrated using practical examples and numerous figures, many in full color. HR-CS AAS is overcoming essentially all the remaining limitations of established AAS, particularly the notorious problem of accurate background measurement and correction. Using a continuum radiation source and a CCD array detector makes the spectral environment visible to several tenths of a nanometer on both sides of the analytical line, tremendously facilitating method development and elimination of interferences. Conceived as a supplement to the standard reference work on AAS by B. Welz and M. Sperling, this book does not repeat such fundamentals as the principles of atomizers or atomization mechanisms. Instead, it is strictly focused on new and additional information required to profit from HR-CS AAS. It presents characteristic concentration for flame atomization and characteristic mass data for electrothermal atomization for all elements, as well as listing numerous secondary lines of lower sensitivity for the determination of higher analyte concentrations. The highly resolved molecular absorption spectra of nitric, sulfuric and phosphoric acids, observed in an air-acetylene flame, which are depicted together with the atomic lines of all elements, make it possible to predict potential spectral interferences.
Elemental Analysis is an excellent guide introducing cutting-edge methods for the qualitative and quantitative analysis of elements. Each chapter of the book gives an overview of a certain technique, such as AAS, AFS, ICP-OES, MIP-OES, ICP-MS and XRF. Readers will benefit from a balanced combination of theoretical basics, operational principles of instruments and their practical applications.
This book provides the readers with the full basic knowledge necessary to understand, evaluate and develop critically any ETAAS analysis. The book covers comprehensively all aspects of the theoretical principles, routine and unusual instrumentation, overlapping possibilities with other techniques and different analytical characteristics of ETAAS at an averaged intermediate/high level. This is a good topic for a text book owing to the wide analytical possibilities of ETAAS in academic and industry laboratories. The book is written by a qualified expert with 30 years' experience working on different aspects of ETAAS.The work guides the readers through an in-depth descriptive appraisal of the chemical and physical processes occurring in an ET atomiser. The work compares favourably with other books already published on this subject as this work shows an overview with some different perspectives, focusing mainly on the processes taking place during an ETAAS analysis. An ordered, rigorous and deep description is found in every chapter. The book would be adequate for undergraduate and graduate students in any course of analytical chemistry, researchers in analytical atomic spectrometry and analysts who routinely use ETAAS. Amateurs and specialists in this field will find a good support in the book.
Atomic Emission Spectrometry is a powerful analytical method which is utilized in academia and industry for quantitative and qualitative elemental analysis. This publication is an excellent guide to the technique, explaining the underlying theory and covering practical measurement applications. Extremely well-written and organized, this book is a beneficial instrument for every scientist or professional working with AES.
Spectroscopy is the study of electromagnetic radiation and its interaction with solid, liquid, gas and plasma. It is one of the widely used analytical techniques to study the structure of atoms and molecules. The technique is also employed to obtain information about atoms and molecules as a result of their distinctive spectra. The fast-spreading field of spectroscopic applications has made a noteworthy influence on many disciplines, including energy research, chemical processing, environmental protection and medicine. This book aims to introduce students to the topic of spectroscopy. The author has avoided the mathematical aspects of the subject as far as possible; they appear in the text only when inevitable. Including topics such as time-dependent perturbation theory, laser action and applications of Group Theory in interpretation of spectra, the book offers a detailed coverage of the basic concepts and applications of spectroscopy.
