This volume surveys the data available in the literature for solid-fluid solubility equilibria plus selected solid-liquid-vapour equilibria, for binary systems containing alkali and ammonium chlorides in water or heavy water. Solubilities covered are lithium chloride, sodium chloride, potassium chloride, rubidium chloride, caesium chloride and ammonium chloride in water and heavy water.
This volume contains evaluated data on the solubility of beryllium hydroxide, magnesium hydroxide, calcium hydroxide, strontium hydroxide and barium hydroxide in water and in a number of electrolyte and nonelectrolyte solutions in water. The alkaline earth hydroxides can be divided into two groups depending on the hydration of the solid. First, the sparingly soluble anhydrous beryllium, magnesium and calcium hydroxides, whose freshly precipitated solids are poorly crystalline and show decreasing solubility with aging, and whose solubility in water decreases with increasing temperature. Second, the soluble strontium and barium hydroxide octahydrates that form crystalline precipitates which do not show changes in solubility on aging, and whose solubility in water increases with increasing temperature.
This volume is the first of two devoted to esters and water. It includes solubility data for binary systems containing an ester and water up to the end of 1988. The critical evaluations were all prepared by one author and an introductory section has been included to elaborate the philosophy and methodology followed in the evaluations.
Solubility Data Series, Volume 50: Carbon Dioxide in Non-Aqueous Solvents at Pressures Less Than 200 kPa contains evaluated data for the solubility in non-aqueous solvents of carbon dioxide at a partial pressure not greater than 200 kPa. The Solubility Data Series is a project of Commission V.8 (Solubility Data) of the International Union of Pure and Applied Chemistry (IUPAC). The text has as its goal the preparation of a comprehensive and critical compilation of data on solubilities in all physical systems, including gases, liquids and solids. Chapters are devoted to providing data on the solubility of carbon dioxide in compounds such as alkanes, cyclic alkanes and alkenes, alcohols, solvents, other than alcohols, containing carbon, hydrogen and oxygen, and animal and vegetable oils and fats. Chemists will find the text extremely useful.
* Guidelines are provided on the reliability of various methods, as well as information for selecting the appropriate technique. * Unique coverage of the whole range of solubility measurements. * Very useful for investigators interested in embarking upon solubility measurements.
This volume contains tabulated collections and critical evaluations of original data for the solubility of gases in molten salts, gathered from chemical literature through to the end of 1989. Within the volume, material is arranged according to the individual gas. The gases include hydrogen halides, inert gases, oxygen, nitrogen, hydrogen, carbon dioxide, water vapor and halogens. The molten salts consist of single salts, binary mixtures and multicomponent systems. Included also, is a special section on the solubility of gases in molten silicate systems, focussing on slags and fluxes.
This book offers an introduction to the geomechanical issues raised by both the extraction of actual and potential energy resources, and by the treatment of the ensuing environmental concerns. Discussions of the operations of injection of fluids into, and withdrawal from, geological formations link the chapters, each devoted to a particular technical aspect or scientific issue, or to a particular energy resource. Subjects are ordered according to their industrial applications, including enhanced oil and gas recovery, gas hydrates, enhanced geothermal systems, hydraulic fracturing, and carbon dioxide sequestration. An overview of the industrial, research and simulation aspects for each subject is provided. Fluid Injection in Deformable Geological Formations will be of interest to academic and industrial researchers in a wide variety of fields, including computational mechanics, civil engineering, geotechnical engineering and geomechanics, engineering seismology, petroleum engineering, reservoir engineering, and engineering geology.
Explains the current state of the science and points the way to technological advances First developed in the late 1980s, lithium-ion batteries now power everything from tablet computers to power tools to electric cars. Despite tremendous progress in the last two decades in the engineering and manufacturing of lithium-ion batteries, they are currently unable to meet the energy and power demands of many new and emerging devices. This book sets the stage for the development of a new generation of higher-energy density, rechargeable lithium-ion batteries by advancing battery chemistry and identifying new electrode and electrolyte materials. The first chapter of Lithium Batteries sets the foundation for the rest of the book with a brief account of the history of lithium-ion battery development. Next, the book covers such topics as: Advanced organic and ionic liquid electrolytes for battery applications Advanced cathode materials for lithium-ion batteries Metal fluorosulphates capable of doubling the energy density of lithium-ion batteries Efforts to develop lithium-air batteries Alternative anode rechargeable batteries such as magnesium and sodium anode systems Each of the sixteen chapters has been contributed by one or more leading experts in electrochemistry and lithium battery technology. Their contributions are based on the latest published findings as well as their own firsthand laboratory experience. Figures throughout the book help readers understand the concepts underlying the latest efforts to advance the science of batteries and develop new materials. Readers will also find a bibliography at the end of each chapter to facilitate further research into individual topics. Lithium Batteries provides electrochemistry students and researchers with a snapshot of current efforts to improve battery performance as well as the tools needed to advance their own research efforts.
