Innovative SANEX process for trivalent actinides separation from PUREX raffinate

Innovative SANEX process for trivalent actinides separation from PUREX raffinate

Author: Michał Sypuła

Publisher: Forschungszentrum Jülich

Published: 2014-03-27

Total Pages: 229

ISBN-13: 3893369279

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Recycling of nuclear spent fuel and reduction of its radiotoxicity by separation of long-lived radionuclides would definitely help to close the nuclear fuel cycle ensuring sustainability of the nuclear energy. Partitioning of the main radiotoxicity contributors followed by their conversion into short-lived radioisotopes is known as partitioning and transmutation strategy. To ensure efficient transmutation of the separated elements (minor actinides) the content of lanthanides in the irradiation targets has to be minimised. This objective can be attained by solvent extraction using highly selective ligands that are able to separate these two groups of elements from each other. The objective of this study was to develop a novel process allowing co-separation of minor actinides and lanthanides from a high active acidic feed solution with subsequent actinide recovery using just one cycle, so-called innovative SANEX process. The conditions of each step of the process were optimised to ensure high actinide separation efficiency. Additionally, screening tests of several novel lipophilic and hydrophilic ligands provided by University of Twente were performed. These tests were aiming in better understanding the influence of the extractant structural modifications onto An(III)/Ln(III) selectivity and complexation properties. ...


Laser Space Communications

Laser Space Communications

Author: David G. Aviv

Publisher: Artech House Publishers

Published: 2006

Total Pages: 220

ISBN-13:

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This groundbreaking resource is the first book to offer you a thorough, practical treatment of laser space communications. The book focuses on the feasibility of laser space communication links between satellites, satellites and airborne platforms, and satellites and ground based stations to achieve worldwide connectivity. You get expert guidance on weather avoidance approaches and adaptive antenna subsystems that help mitigate the effects of turbulence. The book presents simplified, yet highly accurate, engineering expressions of complex mathematics of turbulence that provide you with numerical values in the links' signal power budget. Moreover, you find an entire chapter devoted to noise photons and their effect on the bit error rate. This comprehensive volume covers a wide range of critical topics you need to understand for your work in the field, from a discussion on laser vs. RF communications in space, basic design features of a laser transceiver, and configuration of inter-satellite communication links, to selection of ground station locations, 5th Generation Internet (5-GENIN), and signal modulation schemes. The book is supported with over 70 illustrations and more than 100 equations.


Nucleation of Water

Nucleation of Water

Author: Ari Laaksonen

Publisher: Elsevier

Published: 2021-11-25

Total Pages: 296

ISBN-13: 0128143223

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Nucleation of Water: From Fundamental Science to Atmospheric and Additional Applications provides a comprehensive accounting of the current state-of-the-art regarding the nucleation of water. It covers vapor-liquid, liquid-vapor, liquid-ice and vapor-ice transitions and describes basic kinetic and thermodynamic concepts in a manner understandable to researchers working on specific applications. The main focus of the book lies in atmospheric phenomena, but it also describes engineering and biological applications. Bubble nucleation, although not of major atmospheric relevance, is included for completeness. This book presents a single, go-to resource that will help readers understand the breadth and depth of nucleation, both in theory and in real-world examples. - Offers a single, comprehensive work on water nucleation, including cutting- edge research on ice, cloud and bubble nucleation - Written primarily for atmospheric scientists, but it also presents the theories in such a way that researchers in other disciplines will find it useful - Written by one of the world's foremost experts on ice nucleation


Direct Analysis in Real Time Mass Spectrometry

Direct Analysis in Real Time Mass Spectrometry

Author: Yiyang Dong

Publisher: John Wiley & Sons

Published: 2018-04-09

Total Pages: 370

ISBN-13: 3527341846

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Clear, comprehensive, and state of the art, the groundbreaking book on the emerging technology of direct analysis in real time mass spectrometry Written by a noted expert in the field, Direct Analysis in Real Time Mass Spectrometry offers a review of the background and the most recent developments in DART-MS. Invented in 2005, DART-MS offers a wide range of applications for solving numerous analytical problems in various environments, including food science, forensics, and clinical analysis. The text presents an introduction to the history of the technology and includes information on the theoretical background, for exampleon the ionization mechanism. Chapters on sampling and coupling to different types of mass spectrometers are followed by a comprehensive discussion of a broad range of applications. Unlike most other ionization methods, DART does not require laborious sample preparation, as ionization takes place directly on the sample surface. This makes the technique especially attractive for applications in forensics and food science. Comprehensive in scope, this vital text: -Sets the standard on an important and emerging ionization technique -Thoroughly discusses all the relevant aspects from instrumentation to applications -Helps in solving numerous analytical problems in various applications, for example food science, forensics, environmental and clinical analysis -Covers mechanisms, coupling to mass spectrometers, and includes information on challenges and disadvantages of the technique Academics, analytical chemists, pharmaceutical chemists, clinical chemists, forensic scientists, and others will find this illuminating text a must-have resource for understanding the most recent developments in the field.