Physical and Chemical Properties of Aerosols

Physical and Chemical Properties of Aerosols

Author: Ian Colbeck

Publisher: Springer

Published: 1998

Total Pages: 488

ISBN-13:

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An aerosol is a suspension of fine particles in a gas, usually air, and is generally taken to include both solid and liquid particles with dimensions ranging from a few nanometres up to around 100 micrometres in diameter. Aerosol sicence is the study of the physics and chemistry of aerosol behaviour and this includes techniques of generating particles of nanometre and micrometre dimensions: size classification and measurement, transport and deposition properties: chemical properties of aerosols in the atmosphere and in industry, as well as health effects from inhalation and industrial gas cleaning technology. Aerosols have important commercial implications, e.g. pressure-packaged `aerosol' products, agricultural sprays, atmospheric visibility and high technology materials and knowledge of aerosol properties is important in a wide range of disciplines, including industrial hygiene, air pollution, medicine, agriculture, meteorology and geochemistry. Written by an international team of contributors, this book forms a timely, concise and accessible overview of aerosol science and technology. Chemists, technologists and engineers new to aerosol science will find this book an essential companion in their studies of the subject. Those more familiar with aerosols will use it as an essential source of reference.


Investigation of Aerosol Optical and Chemical Properties Using Humidity Controlled Cavity Ring-Down Spectroscopy

Investigation of Aerosol Optical and Chemical Properties Using Humidity Controlled Cavity Ring-Down Spectroscopy

Author:

Publisher:

Published: 2017

Total Pages: 113

ISBN-13:

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Scientists have been observing a change in the climate since the beginning of the 20th century that cannot be attributed to any of the natural influences of the past. Natural and anthropogenic substances and processes perturb the Earth's energy budget, contributing to climate change. In particular, aerosols (particles suspended in air) have long been recognized to be important in processes throughout the atmosphere that affect climate. They directly influence the radiative balance of the Earth's atmosphere, affect cloud formation and properties, and are also key air pollutants that contribute to a variety of respiratory and cardiovascular diseases. Despite their importance, aerosol particles are less well-characterized than greenhouse gases with respect to their sources, temporal and spatial concentration distribution, and physical and chemical properties. This uncertainty is mainly caused by the variable and insufficiently understood sources, formation and transformation processes, and complex composition of atmospheric particles. Instruments that can precisely and accurately measure and characterize the aerosol physical and chemical properties are in great demand. Atmospheric relative humidity (RH) has a crucial impact on the particles' optical properties; the RH dependence of the particle extinction coefficient is an important parameter for radiative forcing and thus climate change modeling. In this work a Humidity-Controlled Cavity Ring-Down (HC-CRD) aerosol optical instrument is described and its ability to measure RH dependent extinction coefficients and related hygroscopicity parameters is characterized.


Measurements of the Chemical, Physical, and Optical Properties of Single Aerosol Particles

Measurements of the Chemical, Physical, and Optical Properties of Single Aerosol Particles

Author: Ryan Christopher Moffet

Publisher:

Published: 2007

Total Pages: 340

ISBN-13:

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Knowledge of aerosol physical, chemical, optical properties is essential for judging the effect that particulates have on human health, climate and visibility. The aerosol time-of-flight mass spectrometer (ATOFMS) is capable of measuring, in real-time, the size and chemical composition of atmospheric aerosols. This was exemplified by the recent deployments of the ATOFMS to Mexico City and Riverside. The ATOFMS provided rapid information about the major particle types present in the atmosphere. Industrial sources of particles, such as fine mode particles containing lead, zinc and chloride were detected in Mexico City. The rapid time response of the ATOFMS was also exploited to characterize a coarse particle concentrator used in human health effects studies. The ATOFMS showed the ability to detect changes in particle composition with a time resolution of 15 min during short 2 hour human exposure studies.


Aerosol Optics

Aerosol Optics

Author: Alexander A. Kokhanovsky

Publisher: Springer Science & Business Media

Published: 2008-03-18

Total Pages: 154

ISBN-13: 3540499091

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This new text offers experienced students a comprehensive review of available techniques for the remote sensing of aerosols. These small particles influence both atmospheric visibility and the thermodynamics of the atmosphere. They are also of great importance in any consideration of climate change problems. Aerosols may also be responsible for the loss of harvests, human health problems and ecological disasters. Thus, this detailed study of aerosol properties on a global scale could not be more timely.


Analytical Chemistry of Aerosols

Analytical Chemistry of Aerosols

Author: Kvetoslav R. Spurny

Publisher: CRC Press

Published: 2017-11-22

Total Pages: 499

ISBN-13: 1351466585

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Until the 1980s, researchers studied and measured only the physical properties of aerosols. Since the 80s, however, interest in the physicochemcal properties of aerosols has grown tremendously. Scientists in environmental hygiene, medicine, and toxicology have recognized the importance held by the chemical composition and properties of aerosols and the interactions of inhaled, "bad" aerosols. This book offers the first comprehensive treatment of modern aerosol analytical methods, sampling and separation procedures, and environmental applications, and offers critical reviews of the latest literature. This important field has developed rapidly in the last 15 years, but until now, no book effectively summarized or analyzed the existing research. Analytical Chemistry of Aerosols reviews procedures, techniques, and trends in the measurement and analysis of atmospheric aerosols. With contributions from acknowledged, international experts, the book discusses various methods of bulk analysis, single particle analysis, and the analysis of special aerosol systems, including fibrous and bacterial aerosols.


A Plan for a Research Program on Aerosol Radiative Forcing and Climate Change

A Plan for a Research Program on Aerosol Radiative Forcing and Climate Change

Author: Panel on Aerosol Radiative Forcing and Climate Change

Publisher: National Academies Press

Published: 1996-05-01

Total Pages: 180

ISBN-13: 0309588871

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This book recommends the initiation of an "integrated" research program to study the role of aerosols in the predicted global climate change. Current understanding suggest that, even now, aerosols, primarily from anthropogenic sources, may be reducing the rate of warming caused by greenhouse gas emissions. In addition to specific research recommendations, this book forcefully argues for two kinds of research program integration: integration of the individual laboratory, field, and theoretical research activities and an integrated management structure that involves all of the concerned federal agencies.


The Stratospheric Aerosol Layer

The Stratospheric Aerosol Layer

Author: R.C. Whitten

Publisher: Springer Science & Business Media

Published: 2013-03-07

Total Pages: 163

ISBN-13: 3642817572

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It is now a quarter of a century since Junge and his coworkers recovered the first sample from the sulfate aerosol layer in the stratosphere. Since that time vast strides have been made in determining its physical properties and morphology. These investigations have been performed with instruments on board aircraft and balloon platforms as in the early days, with ground-based lidar (optical radar), and most recently with satellite-borne optical instruments. It will become evident in Chapter 2 that in situ measurements by aircI'aft and ,balloon sensors complement rather than duplicate the remote techniques (lidar and satellite). Hence future programs will probably continue to utilize direct as well as indirect experimental techniques. Concurrently, with the observations of the gross properties of the aerosol layer, la~oratory and theoretical studies have sought to elucidate the chemical and micro physical processes which influence the formation and growth of the aerosol par ticles. The laboratory investigations have included studies of gas phase chemistry, and particle nucleation and growth mechanisms. Theoretical studies have revolved mainly around a series of models developed by atmospheric scientists. The earliest of these models was constructed by Junge and his colleagues. With the advent of third- and fourth-generation computers, the capacity to solve the quite complex continuity equations whi~h govern particle formation, growth, and removal has ad vanced to the point where most of the particle properties can be simulated with reasonable confidence.