Ions in Solution and their Solvation

Ions in Solution and their Solvation

Author: Yizhak Marcus

Publisher: John Wiley & Sons

Published: 2015-08-03

Total Pages: 308

ISBN-13: 1118889142

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The book starts with an exposition of the relevant properties of ions and continues with a description of their solvation in the gas phase. The book contains a large amount of factual information in the form of extensive tables of critically examined data and illustrations of the points made throughout. It covers: the relevant properties of prospective liquid solvents for the ions the process of the transfer of ions from the gas phase into a liquid where they are solvated various aspects of the solutions of the ions, such as structural and transport ones and the effects of the ions on the solvent dynamics and structure what happens in cases where the solvent is a mixture selective solvation takes place applications of the concepts expounded previously in fields such as electrochemistry, hydrometallurgy, separation chemistry, biophysics, and synthetic methods


Studies in Ion Solvation in Mixed Solvents

Studies in Ion Solvation in Mixed Solvents

Author:

Publisher:

Published: 1963

Total Pages: 0

ISBN-13:

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Using the appropriate chemical cells, the free energies to transfer of the pairs of ions H(+)Br ( - ) and H(+)I( - ) in the standard state have been determined for transfers from water to 20% mixtures of dioxan and water at 25 degrees. A byproduct of the measurements is the dissociation constant of boric acid in the mixed solvent. Considerable experimental difficulties have been encountered and overcome in these measurements. (Author).


Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents

Solvation, Ionic and Complex Formation Reactions in Non-Aqeuous Solvents

Author: K. Burger

Publisher: Elsevier

Published: 2012-12-02

Total Pages: 269

ISBN-13: 0444597514

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Solvation, Ionic and Complex Formation Reactions in Non-Aqueous Solvents: Experimental Methods for their Investigation presents the available methods and their particular value in investigating solutions composed of non-aqueous solvents. This book is composed of 10 chapters and begins with a brief description of the complexity of the interactions possible n solutions. The subsequent chapters deal with a classification of the solvents and empirical solvent strength scales based on various experimental parameters, together with various correlations empirically describing the solvent effect. Other chapters present the methods for the purification of solvents and ways of checking their purity, as well as the individual results achieved during investigations of the solvent effect, particularly the general regularities recognized. The remaining chapters provide a review of the coordination chemistry of non-aqueous solutions. This book will prove useful to analytical and inorganic chemists.