Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II

Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II

Author: Giuliano GIAMBASTIANI

Publisher: Springer Science & Business Media

Published: 2011-05-19

Total Pages: 272

ISBN-13: 9400706960

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Olefin Upgrading Catalysis by Nitrogen-based Metal Complexes II: State-of-the-art and Perspectives provides a critical review of the state-of-the-art developments in industrially relevant processes connected to efficient and selective olefin upgrading. Specific attention is devoted to catalysts containing imine- and amine-based ligands. All the chapters in this book have been designed to provide a systematic account of the vast amount of information available for this type of catalyst as well as to highlight the factors that ultimately control the catalyst’s performance and productivity. A comprehensive panorama of catalyst precursors is presented, spanning from group 10 α-diimine complexes and iron and cobalt 2,6-bis(imino)pyridine derivatives, to vanadium, chromium, titanium, zirconium and lanthanide complexes supported by nitrogen-containing ligands. The authors of this collective work are currently involved in the development of imine-based catalysts for efficient and selective olefin upgrading and the majority of them have dedicated most of their scientific career to this important field. In writing this book, their major goal is to transfer as many ideas and experiences as possible to the global audience of scientists engaged in this area of research.


Metal-Catalyzed Polymerization

Metal-Catalyzed Polymerization

Author: Samir Chikkali

Publisher: CRC Press

Published: 2017-08-03

Total Pages: 188

ISBN-13: 1351649957

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The proposed book focusses on metal mediated/catalyzed “controlled/living radical polymerization” (CRP/LRP) methods. It surveys a wide variety of catalyzed polymerization reactions, making it essentially a “one stop” review in the field. A significant contribution to polymer science is “metathesis polymerization” discovered by Grubbs and others. The book will cover various metathesis polymerization methods and implications in polymer industry.


Organometallic Reactions and Polymerization

Organometallic Reactions and Polymerization

Author: Kohtaro Osakada

Publisher: Springer

Published: 2014-07-15

Total Pages: 307

ISBN-13: 366243539X

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This compilation provides advanced graduate students and researchers with a structured overview of olefin polymerization. Divided into eight chapters written by international experts, this book covers polymerization using various organotransition-metal catalysts, including early and late transition metal complexes, new trends in olefin oligomerization and related reactions. All authors address the historic and scientific backgrounds of the field as well as current research progress and potential for further research. The complete book is designed to present eight independent lectures and, because all authors are well versed in organometallic chemistry, each is based on a profound understanding of the reactions and structures of organotransition metal complexes. This book is an ideal accompaniment for researchers taking courses in olefin polymerization and also serves as a valuable resource for teachers and lecturers of chemistry when planning and researching material for advanced lecture courses.


Stereoselective Polymerization with Single-Site Catalysts

Stereoselective Polymerization with Single-Site Catalysts

Author: Lisa S. Baugh

Publisher: CRC Press

Published: 2007-11-29

Total Pages: 698

ISBN-13: 142001708X

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New synthetic techniques allow chemists to modify polymer microstructures more precisely than ever, making it possible to design materials that meet increasingly demanding performance requirements. Written and edited by experts in the field, Stereoselective Polymerization with Single-Site Catalysts reviews how the relative stereochemistry of


Polyolefin Compounds and Materials

Polyolefin Compounds and Materials

Author: Mariam Al-Ali AlMa'adeed

Publisher: Springer

Published: 2015-12-23

Total Pages: 354

ISBN-13: 3319259822

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This book describes industrial applications of polyolefins from the researchers' perspective. Polyolefins constitute today arguably the most important class of polymers and polymeric materials for widespread industrial applications. This book summarizes the present state of the art. Starting from fundamental aspects, such as the polymerization techniques to synthesize polyolefins, the book introduces the topic. Basic knowledge about polyolefin composites and blends is explained, before applications aspects in different industry sectors are discussed. The spectrum comprises a wide range of applications and industry sectors, such as the packaging and food industry, the textile industry, automotive and buildings, and even biomedical applications. Topics, which are addressed in the various chapters, comprise synthesis and processing of the materials; their classification; mechanical, physical and technical requirements and properties; their characterization; and many more. In the end of the book, even the disposal, degradation and recycling of polyolefins are addressed, and light is shed on their commercial significance and economic value. In this way, the book follows the entire 'lifetime' of polyolefin compounds and materials: from their synthesis and processing, over applications, to the recycling and reuse of disposed or degraded polyolefin substrates.


Iron and Cobalt Catalysts

Iron and Cobalt Catalysts

Author: Wilson D. Shafer

Publisher: MDPI

Published: 2020-06-23

Total Pages: 414

ISBN-13: 303928388X

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Since the turn of the last century when the field of catalysis was born, iron and cobalt have been key players in numerous catalysis processes. These metals, due to their ability to activate CO and CH, haev a major economic impact worldwide. Several industrial processes and synthetic routes use these metals: biomass-to-liquids (BTL), coal-to-liquids (CTL), natural gas-to-liquids (GTL), water-gas-shift, alcohol synthesis, alcohol steam reforming, polymerization processes, cross-coupling reactions, and photocatalyst activated reactions. A vast number of materials are produced from these processes, including oil, lubricants, waxes, diesel and jet fuels, hydrogen (e.g., fuel cell applications), gasoline, rubbers, plastics, alcohols, pharmaceuticals, agrochemicals, feed-stock chemicals, and other alternative materials. However, given the true complexities of the variables involved in these processes, many key mechanistic issues are still not fully defined or understood. This Special Issue of Catalysis will be a collaborative effort to combine current catalysis research on these metals from experimental and theoretical perspectives on both heterogeneous and homogeneous catalysts. We welcome contributions from the catalysis community on catalyst characterization, kinetics, reaction mechanism, reactor development, theoretical modeling, and surface science.


Polymeric Materials for Clean Water

Polymeric Materials for Clean Water

Author: Rasel Das

Publisher: Springer

Published: 2018-09-27

Total Pages: 194

ISBN-13: 303000743X

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This book gives an overview of recent developments in the synthesis of macromolecules for water purification applications. The preparation of these polymers from organic and inorganic starting materials is described. Important post-polymerization modifications, introduction of functional groups and production of supramolecular assemblies and nanomaterials are shown. The synthesized materials are presented with their interesting properties and broad areas of applications. A comprehensive discussion about the engineering aspect and the usage in water treatment as well as environmental issues is given. The wide variety of materials and their synthesis techniques will encourage scientists in developing new synthesis routes and materials, whereby engineers will be encouraged to find new possible applications.


Business and Technology of the Global Polyethylene Industry

Business and Technology of the Global Polyethylene Industry

Author: Thomas E. Nowlin

Publisher: John Wiley & Sons

Published: 2014-09-09

Total Pages: 432

ISBN-13: 1118945999

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The history of the business and technology that was responsible for the enormous growth of the global polyethylene industry from the laboratory discovery in 1933 to reach an annual production of over 75 million metric tons in 2012 and become the leading plastic material worldwide. This book is an in-depth look at the history of the scientists and engineers that created the catalysts and the methods used for the modern commercial manufacture of polyethylene and its products. The book outlines the processes used for the manufacture of polyethylene are reviewed which include the high-pressure process and the three low-pressure processes; slurry, solution and the gas-phase methods. The techniques used to fabricate polyethylene into end-use products are reviewed with a discussion of blow-molding, injection molding, rotational molding, blown-film, cast-film and thermoforming are also discussed in detail.


Handbook of Transition Metal Polymerization Catalysts

Handbook of Transition Metal Polymerization Catalysts

Author: Ray Hoff

Publisher: John Wiley & Sons

Published: 2018-04-20

Total Pages: 895

ISBN-13: 1119242215

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Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization