Emulsion Polymerization of Vinyl Acetate

Emulsion Polymerization of Vinyl Acetate

Author: Mohamed S. El-Aasser

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 250

ISBN-13: 9400981147

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It is particularly appropriate that this symposium on the emulsion polymeriza tion of vinyl acetate was held in recognition of the industrial importance of poly(vinyl acetate) and vinyl acetate copolymers, and their rather unique properties among emulsion polymers in general. Poly( vinyl acetate) latexes were the first synthetic polymer latexes to be made on a commercial scale: their production using polyvinyl alcohol as emulsifier began in Germany during the mid-1930s and has continued to the present day, growing steadily with the years. Indeed, poly(vinyl acetate) latexes prepared with polyvinyl alcohol are still one of the mainstays of the adhesives industry. With the passing of time, however, vinyl acetate copolymers have been developed: copolymers with maleate esters such as dibutyl maleate, acrylate esters such as ethyl acrylate and butyl acrylate, versatic acid esters, and, more recently, ethylene. These versatile copolymers have found increasing use in more sophisticated adhesives with specialized properties, adhesives for clay coatings on paper, carpet backing, and interior and exterior paints. Thus more than 45 years after the first commercial production of vinyl acetate latexes, their use is still growing, both in actual quantities and different applications. The industrial importance of vinyl acetate latexes makes the mechanism and kinetics of their emulsion polymerization of practical as well as scientific interest.


Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers

Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers

Author: Yildirim H. Erbil

Publisher: CRC Press

Published: 2000-03-22

Total Pages: 338

ISBN-13: 142003880X

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The versatility of the emulsion copolymerization reaction and the ability to control the properties of the final latices have led to rapid expansion both in the quantity of polyvinylacetate and vinyl acetate-acrylic copolymer latices and in their applications. Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers provides


Handbook of Thermoplastics

Handbook of Thermoplastics

Author: Olagoke Olabisi

Publisher: CRC Press

Published: 1997-03-19

Total Pages: 1080

ISBN-13: 9780824797973

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Offers coverage of all known commodity, transitional, engineering, high-temperature and high-performance thermoplastics, and analyzes emerging developments in the creation of new thermoplastics. The text examines: important issues in the field for each substance discussed, including history, development and commercialization; polymer formation mechanisms and process technologies; the affect of structural and phase characteristics on properties; the commercial relevance of thermoplastic blends, alloys, copolymers and composites; and more.


Nanocomposite Structures and Dispersions

Nanocomposite Structures and Dispersions

Author: Ignac Capek

Publisher: Elsevier

Published: 2019-07-20

Total Pages: 460

ISBN-13: 0444637559

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Nanocomposite Structures and Dispersions deals with the preparation of gelled, branched and crosslinked nanostructured polymers in the solution free radical polymerization and controlled/living radical polymerization and polymer and composite nanoparticles and nanostructures in disperse systems, the kinetics of direct and inverse disperse polymerizations (microemulsion, miniemulsion, emulsion, dispersion and suspension polymerization), the bottom-up approach building of functionalized nanoparticles, modelling of radical microemulsion polymerization, the characterization of traditional and non-traditional polymer dispersions, the collective properties of nanomaterials and their (bio)applications.This book is designed to bridge that gap and offers several unique features. First, it is written as an introduction to and survey of nanomaterials with a careful balance between basics and advanced topics. Thus, it is suitable for both beginners and experts, including graduate and upper-level undergraduate students. Second, it strives to balance the colloidal aspects of nanomaterials with physical principles. Third, the book highlights nanomaterial based architectures including composite or hybrid conjugates rather than only isolated nanoparticles. A number of ligands have been utilized to biodecorate the polymer and composite nanocarriers. Finally, the book provides an in depth discussion of important examples of reaction mechanisms of bottom-up building of functionalized nanoparticles, or potential applications of nanoarchitectures, ranging from physical to chemical and biological systems. - Free radical (controlled) polymerization, branching, crosslinking and gelling - Kinetics and mechanism of polymer nanoparticles formation - Modelling of radical polymerization in disperse systems - Polymer, composite and metal nanoparticles, nanostructures and nanomaterials - Smart nanostructures, biodecorated particles, nanocarriers and therapeutics


Principles and Applications of Emulsion Polymerization

Principles and Applications of Emulsion Polymerization

Author: Chorng-Shyan Chern

Publisher: John Wiley & Sons

Published: 2008-10-06

Total Pages: 268

ISBN-13: 0470377933

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Up-to-date coverage of methods of emulsion polymerization This book provides a comprehensive reference on emulsion polymerization methods,focusing on the fundamental mechanisms and kinetics of each process, as well as howthey can be applied to the manufacture of environmentally friendly polymeric materials. Topics covered include: Conventional emulsion polymerization Miniemulsion polymerization Microemulsion polymerization Industrial emulsion polymerization processes (primarily the semibatch and continuous reactions systems) The role of various colloidal phenomena in emulsion polymerization Important end-use properties of emulsion polymer (latex) products Information on industrial applications in paints, coatings, adhesives, paper and board, and more This is a hands-on reference for graduate students and professionals in polymerchemistry, chemical engineering, and materials science who are involved in researchon coatings, adhesives, rubber, latex, paints, finishes, and other materials that can becreated using various methods of emulsion polymerization.


Masters Theses in the Pure and Applied Sciences

Masters Theses in the Pure and Applied Sciences

Author: Wade H. Shafer

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 314

ISBN-13: 1468449192

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Masters Theses in the Pure and Applied Sciences was first conceived, published, and disseminated by the Center for Information and Numerical Data Analysis and Synthesis (CINDAS) * at Purdue University in 1 957, starting its coverage of theses with the academic year 1955. Beginning with Volume 13, the printing and dissemination phases of the activity were transferred to University Microfilms/Xerox of Ann Arbor, Michigan, with the thought that such an arrangement would be more beneficial to the academic and general scientific and technical community. After five years of this joint undertaking we had concluded that it was in the interest of all con cerned if the printing and distribution of the volumes were handled by an interna tional publishing house to assure improved service and broader dissemination. Hence, starting with Volume 18, Masters Theses in the Pure and Applied Sciences has been disseminated on a worldwide basis by Plenum Publishing Cor poration of New York, and in the same year the coverage was broadened to include Canadian universities. All back issues can also be ordered from Plenum. We have reported in Volume 28 (thesis year 1 983) a total of 10,661 theses titles from 26 Canadian and 197 United States universities. We are sure that this broader base for these titles reported will greatly enhance the value of this important annual reference work. While Volume 28 reports theses submitted in-1983, on occasion, certain univer sities do report theses submitted in previous years but not reported at the time.


Polymerization

Polymerization

Author: Ailton De Souza Gomes

Publisher: BoD – Books on Demand

Published: 2012-09-12

Total Pages: 440

ISBN-13: 9535107453

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This book comprises the contributions of several authors in the area of polymer characterization by atomic force microscopy of the polymer network structure formed in Ferroelectric Liquid Crystals Cells; polymerization by microwave irradiation method of starch/acrylic acid/acrylamide; polymerization of olefins; emulsion polymerization; ring opening polymerization; cationic polymerization of vinyl monomers ; block and graft copolymerization by controlled/living polymerization; fabrication of doped microstructures by two-photon polymerization; rheology of biomaterials; plant cell wall polymers; polyADP-Ribosylation in postfertilization and genome reprogramming . We hope that this book will help inspire readers to pursue study and research in this field.


CRC Handbook of Solubility Parameters and Other Cohesion Parameters

CRC Handbook of Solubility Parameters and Other Cohesion Parameters

Author: Allan F.M. Barton

Publisher: Routledge

Published: 2017-10-19

Total Pages: 774

ISBN-13: 1351457187

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The CRC Handbook of Solubility Parameters and Other Cohesion Parameters, Second Edition, which includes 17 new sections and 40 new data tables, incorporates information from a vast amount of material published over the last ten years. The volume is based on a bibliography of 2,900 reports, including 1,200 new citations. The detailed, careful construction of the handbook develops the concept of solubility parameters from empirical, thermodynamic, and molecular points of view and demonstrates their application to liquid, gas, solid, and polymer systems.