As a new and rapidly growing science, the applications of ultrasound methods in environmental technology hold a promising future. Compared to conventional methods, ultrasonication can bring several benefits such as being environmentally friendly (no toxic chemical are used or produced), low cost, and compact, allowing on-site treatment. Besides an overview featuring the background behind ultrasonic technology, this brief summarizes the main studies and innovations reported in recent research that has utilized ultrasound methods in environmental analysis, water, and sludge treatment, soil and sediment remediation to air purification.
Traditionally heat and light are thought as energy sources to drive a particular chemical reaction, but now ultrasound is a promising energy source for this purpose. The collapse of a bubble generates a wide range of high temperatures and pressures, and therefore, use of ultrasound has a considerable potential in chemical and allied sciences. Ultrasound-assisted reactions are green and economically viable alternatives to conventional techniques. This new volume presents a complete picture of ultrasound-assisted reactions and technologies that can be used in organic synthesis, polymer synthesis and degradation, nanomaterials, wastewater treatment, food ingredients and products, pharmaceutical applications, bioenergy applications, and more. This volume aims to shed light on the diversified applications of ultrasound and its significant role as a green chemical pathway. Sonochemistry deals with the effect of ultrasonic waves on chemical systems. It has green value because of non-hazardous acoustic radiation and is therefore duly recognized as a green chemistry by synthetic chemists as well as environmentalists. There is no direct interaction of ultrasound with molecular species, but the observed chemical and physical effects of ultrasound are due to the cavitational collapse, which produces drastic conditions of temperature and pressure locally. It induces the formation of various chemical species, which cannot be easily attained under conventional conditions. Sometimes, these species are responsible for driving towards an unusual reactivity in molecular entities. This book, Sonochemistry: An Emerging Green Technology, provides the complete development of sonochemistry, starting with an introduction and basic concepts of sonochemistry and proceeding on to different types of sonochemical reactions, instrumentation, use of ultrasound in driving particular chemical reactions, and its applications in various fields, such as polymer synthesis, decontamination of water and wastewater, preparation of nanomaterials, food technology, pharmaceutical sciences, etc. The book also briefly discusses some areas that utilize ultrasounds of different frequencies. These include food products and their processing; anaerobic digestion of waste; and medical applications such as ultrasonography, sonodynamic therapy, drug delivery, etc. Sonochemistry will be successfully used on an industrial scale in pharmaceutical drugs, polymers, nanomaterials, food technology, material science, biogas production, etc. in years to come and will be an established green chemical technology of the future.
Mit Ultraschall kann man den Fortgang von Reaktionen verfolgen und Arbeitsschritte in der Analytik beschleunigen. Neben den klassischen Anwendungen in der Extraktion stellt dieser Band auch moderne Einsatzgebiete, unter anderem in der Proteomforschung und Polymertechnik, vor. Spezielle Kapitel widmen sich den erforderlichen Instrumenten wie Ultraschallbädern und -sonden.
Power ultrasound has been used for many years in two specific industrial areas: cleaning and plastic welding. Over the last ten years an increasing interest has been shown in its potential for use over a much wider range of chemistry and processing which has been grouped together under the general title of sonochemistry. Most of these uses depend on the generation of acoustic cavitation in liquid media but this text, while underlining the importance of the physics and mathematics of cavitation, mainly concentrates on applications of the technology. After an introduction to the topic and some historical background to the uses of power ultrasound the general principles of acoustic cavitation are explored including some background physics, bubble dynamics and factors which influence cavitation. The remainder of the book incorporates a series of applications of sonochemistry which illustrate the types of physical and chemical effects of ultrasonically induced cavitation which will interest chemists and engineers alike. Amongst the major topics included are chemical synthesis, environmental protection and remediation of water, sewage and soils, polymer synthesis and processing, electrochemistry including both analytical and synthetic aspects and plating. The final chapter reviews the range of ultrasonic equipment available in the laboratory and the progress made towards the scale-up of sonochemistry. The level is introductory to semi-advanced and no topic has been taken to a particularly specialist level since it is intended that this should be of general interest to readers with a scientific background.
The application of ultrasound waves to chemical reactions — sonochemistry — has huge potential for innovation in eco-friendly and eco-efficient chemistry. Sonochemistry: New Opportunities for Green Chemistry first introduces the basics of ultrasonic waves and the history of sonochemistry before moving on to look at acoustic cavitation and the estimation of ultrasonic parameters. After this comes a discussion of the equipment needed for experimentation with sonochemistry. Finally there is an in-depth look at green sonochemistry in different fields of research, covering concepts such as new combinations of ultrasound with ionic liquids, microwave irradiation, enzyme combination, and sono-assisted electrochemistry. In conclusion, distinguished sonochemists from around the world share their opinions on the green sonochemistry, and their predictions in the field.Undergraduate and graduate students in chemistry, and practitioners of ultrasonic technology will gain a unique insight into the opportunities and challenges facing sonochemistry today in its theoretical and practical implementation.
Ultrasonic irradiation and the associated sonochemical and sonophysical effects are complementary techniques for driving more efficient chemical reactions and yields. Sonochemistry-the chemical effects and applications of ultrasonic waves-and sustainable (green) chemistry both aim to use less hazardous chemicals and solvents, reduce energy consumpt
The effects of heat and light on chemical reactions have long been known and un derstood. Ultrasound has been known to promote chemical reactions for the past 60 years, but despite this, it did not attract the attention of synthetic chemists until recently. This arose historically from early studies which concentrated almost exclu sively on reactions in aqueous media and was also, in some measure, due to the availability of suitable technology. Since the early 1980s a plethora of literature has appeared of direct interest to synthetic chemists and the field has been developing rapidly. The aim of this book is to bring the background of this fascinating field to the atten tion of a wider audience. It explores the literature to date and attempts to indicate other areas in which ultrasound may be exploited. It also hopes to explode some of the myths surrounding this area which have hitherto been regarded by the synthetic community as a bit of a black art! Existing books and reviews have tended to concentrate on the physics of sonochem istry and to catalogue the instances in which ultrasound has proved useful in tack ling synthetic problems. Our aim has been to stress the relevance of this technique to synthetic chemists and we have included a section which deals with the practical aspects of carrying out these reactions.
There is an increasing interest in the exploitation of power ultrasound in chemistry and processing (sonochemistry). This text was written as a result of the many requests from potential sonochemists for a practical introduction to the topic.
The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
This updated version of Practical Sonochemistry for advanced students and teachers in chemistry and chemical engineering conveys the increasing growth in applications and equipment to power ultrasound. Equipment now on the market offers a wider range of frequencies with more reproducible experimentation and a variety of scale-up systems. The book provides detailed descriptions of newer ultrasonic equipment and its applications, and practical laboratory uses of ultrasound technology for industrial scale performance.Modern exercises familiarise readers with recent sonochemical operations. The book also includes methods for estimating ultrasonic energy entering the system (dosimetry), which will standardise sonochemical methodology and enable practitioners to reproduce results from other laboratories. Conveys the increasing growth in applications and equipment to power ultrasound Provides detailed descriptions of new ultrasonic equipment and its applications and practical laboratory uses of ultrasound technology for industrial scale performance Includes methods for estimating ultrasonic energy entering the system (dosimetry), which will standardise sonochemical methodology and enable practitioners to reproduce results from other laboratories
