Modern Thermodynamics

Modern Thermodynamics

Author: Dilip Kondepudi

Publisher: John Wiley & Sons

Published: 2014-12-31

Total Pages: 550

ISBN-13: 111837181X

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Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition presents a comprehensive introduction to 20th century thermodynamics that can be applied to both equilibrium and non-equilibrium systems, unifying what was traditionally divided into ‘thermodynamics’ and ‘kinetics’ into one theory of irreversible processes. This comprehensive text, suitable for introductory as well as advanced courses on thermodynamics, has been widely used by chemists, physicists, engineers and geologists. Fully revised and expanded, this new edition includes the following updates and features: Includes a completely new chapter on Principles of Statistical Thermodynamics. Presents new material on solar and wind energy flows and energy flows of interest to engineering. Covers new material on self-organization in non-equilibrium systems and the thermodynamics of small systems. Highlights a wide range of applications relevant to students across physical sciences and engineering courses. Introduces students to computational methods using updated Mathematica codes. Includes problem sets to help the reader understand and apply the principles introduced throughout the text. Solutions to exercises and supplementary lecture material provided online at http://sites.google.com/site/modernthermodynamics/. Modern Thermodynamics: From Heat Engines to Dissipative Structures, Second Edition is an essential resource for undergraduate and graduate students taking a course in thermodynamics.


Structural Stability in Physics

Structural Stability in Physics

Author: G. Güttinger

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 309

ISBN-13: 3642673635

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This volume is the record and product of two International Symposia on the Appli cation of Catastrophe Theory and Topological Concepts in Physics, held in May and December 1978 at the Institute for Information Sciences, University of TUbingen. The May Symposium centered around the conferral of an honorary doctorate upon Professor Rene Thom, Paris, by the Faculty of Physics of the University of TUbingen in recognition of his discovery of universal structure principles and the new di mension he has added to scientific knowledge by his pioneering work on structural stability and morphogenesis. Owing to the broad scope and rapid development of the field, the May Sympos,ium was followed in December by a second one on the same sub jects. The symposia, attended by more than 50 scientists, brought together mathe maticians, physicists, chemists and biologists to exchange ideas about the recent faSCinating impact of topological concepts on the physical sciences, and also to introduce young scientists to the field. The contributions, covering a wide spectrum, are summarized in the subsequent Introduction. The primary support of the Symposia was provided by the "Vereinigung der Freunde der Univertat TUbingen" (Association of the Benefactors of the University). We are particularly indebted to Dr. H. Doerner for his personal engagement and efficient help with the projects, both in his capacity as Secretary of the Association and as Administrative Director of the University.


Self-Organization in Nonequilibrium Systems

Self-Organization in Nonequilibrium Systems

Author: Gregoire Nicolis

Publisher: Wiley-VCH

Published: 1977-05-13

Total Pages: 520

ISBN-13:

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Membranes, Dissipative Structures, and Evolution Edited by G. Nicolis & R. Lefever Focuses on the problem of the emergence/maintenance of biological order at successively higher levels of complexity. Covers the spatiotemporal organization of simple biochemical networks; the formation of pluricellular or macromolecular assemblies; the evolution of these structures; and the functions of specific biological structures. Volume 29 in Advances in Chemical Physics Series, I. Prigogine & Stuart A. Rice, Editors. 1975 Theory and Applications of Molecular Paramagnetism Edited by E. A. Boudreaux & L. N. Mulay Comprehensively treats the basic theory of paramagnetic phenomena from both the classical and mechanical vantages. It examines the magnetic behavior of Lanthanide and Actinide elements as well as traditional transition metals. For each class of compounds, appropriate details of descriptive and mathematical theory are given before their applications. 1976 Theory and Aapplications of Molecular Diamagnetism Edited by L. N. Mulay & E. A. Boudreaux An invaluable reference for solving chemical problems in magnetics, magnetochemistry, and related areas where magnetic data are important, such as solid-state physics and optical spectroscopy. 1976


Thermodynamics of Systems Containing Flexible-Chain Polymers

Thermodynamics of Systems Containing Flexible-Chain Polymers

Author: V.J. Klenin

Publisher: Elsevier

Published: 1999-06-03

Total Pages: 851

ISBN-13: 0080542832

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This book deals with the problems of the thermodynamics of systems containing flexible-chain polymers as the basis of polymer material science. The main thermodynamic quantities and concepts are introduced and discussed in the order of the objects getting more and more complicated: gases, magnets, low-molecular-weight substances and mixtures, and finally, polymers and polymer blends.All topics are considered in a common clue, using the principle of universality. The stability conditions for the one-phase state of multi-component systems are given. Phase separation is regarded as a result of loss in stability. The critical state of a system, with the one-phase state being close to the boundary of stability conditions breaking, is discussed in detail. The effects of both light scattering (elastic and dynamic) and diffusion, as directly depending on the thermodynamic parameters characterizing the one-phase state stability, are considered in detail. One of the versions of colloid scattering, namely, the turbidity spectrum method, is described as useful for the characterization of various heterogeneous structures and for the phase analysis of polymer systems. In the approximation of mean field theories and advanced field theory, formalisms expound the following divisions of the thermodynamics of binary and polynary systems with flexible-chain polymers: conformation of the polymer coil, composition fluctuations, elastic and dynamic light scattering, diffusion in the one-phase state (including the critical range), phase separation, polymer fractionation, the coil-globule transition, phase equilibrium and separation in the system network polymer + low-molecular-weight liquid, polymer blends and multiphase separation.


Thermodynamic Approaches in Engineering Systems

Thermodynamic Approaches in Engineering Systems

Author: Stanislaw Sieniutycz

Publisher: Elsevier

Published: 2016-05-20

Total Pages: 740

ISBN-13: 0128093390

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Thermodynamic Approaches in Engineering Systems responds to the need for a synthesizing volume that throws light upon the extensive field of thermodynamics from a chemical engineering perspective that applies basic ideas and key results from the field to chemical engineering problems. This book outlines and interprets the most valuable achievements in applied non-equilibrium thermodynamics obtained within the recent fifty years. It synthesizes nontrivial achievements of thermodynamics in important branches of chemical and biochemical engineering. Readers will gain an update on what has been achieved, what new research problems could be stated, and what kind of further studies should be developed within specialized research. - Presents clearly structured chapters beginning with an introduction, elaboration of the process, and results summarized in a conclusion - Written by a first-class expert in the field of advanced methods in thermodynamics - Provides a synthesis of recent thermodynamic developments in practical systems - Presents very elaborate literature discussions from the past fifty years


Statistical Thermodynamics of Nonequilibrium Processes

Statistical Thermodynamics of Nonequilibrium Processes

Author: Joel Keizer

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 517

ISBN-13: 1461210542

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The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.