This unique approach to the basic concepts of adsorption is written for students, engineers, scientists, and others who need a clear presentation of adsorption processes. Unlike other texts on this subject, which are written for the specialist and rely heavily on advanced mathematics, this unique book helps you solve everyday problems in applications of adsorption, without complex mathematics or computers. The author, a recognized expert in the field, gives you a quick introduction to the underlying physics of absorption and explains how to apply adsorption to solve analytical and design problems. Rich with practical examples and enhanced by illustrations that support the text, this refreshingly straightforward presentation helps you cut through the complexities of adsorption to find fast answers to pressing real-world questions.
Adsorption: it's the most important method for removing organic contaminants from wastewater streams. Students and professionals alike in the fields of water/wastewater treatment and environmental engineering have expressed tremendous interest in learning and understanding adsorption processes. Adsorption Design for Wastewater Treatment fulfills the need for a true textbook on this increasingly important subject . From the basics of the adsorption process to specifics on system design, this overview serves a dual purpose: study manual and design guide. Straightforward explanations and illustrations make Adsorption Design for Wastewater Treatment ideal for junior, senior and graduate-level university courses. Practicing engineers will find the book especially useful for accurate, direct advice on designing batch and fixed-bed adsorption systems. Contaminant removal will be an ever-present challenge to environmental engineers. Gain a clear understanding of one of the most important cleanup methods with Adsorption Design for Wastewater Treatment.
This unique approach to the basic concepts of adsorption is written for students, engineers, scientists, and others who need a clear presentation of adsorption processes. Unlike other texts on this subject, which are written for the specialist and rely heavily on advanced mathematics, this unique book helps you solve everyday problems in applications of adsorption, without complex mathematics or computers. The author, a recognized expert in the field, gives you a quick introduction to the underlying physics of absorption and explains how to apply adsorption to solve analytical and design problems. Rich with practical examples and enhanced by illustrations that support the text, this refreshingly straightforward presentation helps you cut through the complexities of adsorption to find fast answers to pressing real-world questions.
Principles of Adsorption and Reaction on Solid Surfaces As with other books in the field, Principles of Adsorption and Reaction on Solid Surfaces describes what occurs when gases come in contact with various solid surfaces. But, unlike all the others, it also explains why. While the theory of surface reactions is still under active development, the approach Dr. Richard Masel takes in this book is to outline general principles derived from thermodynamics and reaction rate theory that can be applied to reactions on surfaces, and to indicate ways in which these principles may be applied. The book also provides a comprehensive treatment of the latest quantitative surface modeling techniques with numerous examples of their use in the fields of chemical engineering, physical chemistry, and materials science. A valuable working resource and an excellent graduate-level text, Principles of Adsorption and Reaction on Solid Surfaces provides readers with: * A detailed look at the latest advances in understanding and quantifying reactions on surfaces * In-depth reviews of all crucial background material * 40 solved examples illustrating how the methods apply to catalysis, physical vapor deposition, chemical vapor deposition, electrochemistry, and more * 340 problems and practice exercises * Sample computer programs * Universal plots of many key quantities * Detailed, class-tested derivations to help clarify key results The recent development of quantitative techniques for modeling surface reactions has led to a number of exciting breakthroughs in our understanding of what happens when gases come in contact with solid surfaces. While many books have appeared describing various experimental modeling techniques and the results obtained through their application, until now, there has been no single-volume reference devoted to the fundamental principles governing the processes observed. The first book to focus on governing principles rather than experimental techniques or specific results, Principles of Adsorption and Reaction on Solid Surfaces provides students and professionals with a quantitative treatment of the application of principles derived from the fields of thermodynamics and reaction rate theory to the investigation of gas adsorption and reaction on solid surfaces. Writing for a broad-based audience including, among others, chemical engineers, chemists, and materials scientists, Dr. Richard I. Masel deftly balances basic background in areas such as statistical mechanics and kinetics with more advanced applications in specialized areas. Principles of Adsorption and Reaction on Solid Surfaces was also designed to provide readers an opportunity to quickly familiarize themselves with all of the important quantitative surface modeling techniques now in use. To that end, the author has included all of the key equations involved as well as numerous real-world illustrations and solved examples that help to illustrate how the equations can be applied. He has also provided computer programs along with universal plots that make it easy for readers to apply results to their own problems with little computational effort. Principles of Adsorption and Reaction on Solid Surfaces is a valuable working resource for chemical engineers, physical chemists, and materials scientists, and an excellent text for graduate students in those disciplines.
Adsorption from Solutions of Non-Electrolytes provides a general discussion of the subject, which has so far been given little or no attention in current textbooks of physical chemistry. A general view of the subject is particularly needed at a time when we wish to see how far it will be possible to use theories of solutions to explain the phenomena of adsorption. The book opens with an introductory chapter on the types of interface, aspects of adsorption from solution, types of adsorption, and classification of systems. This is followed by separate chapters on experimental methods, adsorption at the liquid-solid interface, adsorption from completely miscible and partially liquids, adsorption of gases and solids from solution, adsorption of polymers, and adsorption in multicomponent systems. Subsequent chapters deal with factors influencing competitive adsorption at the liquid-solid interface. adsorption at the liquid-vapor and liquid-liquid interface, kinetics and thermodynamics of adsorption from the liquid phase, the use of columns in adsorption, and use of adsorption from solution to measure surface area.
Adsorption Processes for Water Treatment discusses the application of adsorption in water purification. The book is comprised of 10 chapters that detail the carbon and resin adsorptive processes for potable water treatment. The text first covers the elements of surface chemistry and then proceeds to discussing adsorption models. Chapter 3 tackles the kinetics of adsorption, while Chapter 4 deals with batch systems and fixed fluid beds. Next, the book talks about the physical and chemical properties of carbon. The next two chapters discuss the adsorption of organic compounds and the removal of inorganic compounds, respectively. The eighth chapter presents operational, pilot plant, and case studies. Chapter 9 discusses the biological activated carbon treatment of drinking water, and Chapter 10 covers the adsorption of macroreticular resins. The book will be of great use to both researchers and professionals involved in the research and development of water treatment process.
Despite the large quantity of phenomenological information concerning the bulk properties of nematic phase liquid crystals, little is understood about the origin of the surface energy, particularly the surface, interfacial, and anchoring properties of liquid crystals that affect the performance of liquid crystal devices. Self-contained and unique,
This book is intended to present for the first time experimental methods to measure equilibria states of pure and mixed gases being adsorbed on the surface of solid materials. It has been written for engineers and scientists from industry and academia who are interested in adsorption based gas separation processes and/or in using gas adsorption for characterization of the porosity of solid materials. This book is the result of a fruitful collaboration of a theoretician (JUK) and an experimentalist (RS) over more than twelve years in the field of gas adsorption systems at the Institute of Fluid- and Thermodynamics (IFT) at the University of Siegen, Siegen, Germany. This collaboration resulted in the development of several new methods to measure not only pure gas adsorption, but gas mixture or coadsorption equilibria on inert porous solids. Also several new theoretical results could be achieved leading to new types of so-called adsorption isotherms based on the concepts of molecular association and – phenomenologically speaking – on that of thermodynamic phases of fractal dimension. Naturally, results of international collaboration of the authors over the years (1980-2000) also are included.
Introduction to Adsorption: Basics, Analysis, and Applications presents adsorption basics that are relevant and essential to its application, including data analysis, interpretation and design calculations. The book deliberately keeps background information to a minimum, instead comprehensively covering adsorption of liquid solutions, the difference between equilibrium individual solute uptake and surface excess, a general discussion of adsorbate uptake mechanisms and uptake rate expression, uptake steps, performance models and their generalizations, application of performance models, and design methods based on the constant behavior assumption and unused bed length concept. - Includes adsorption basics and their applications - Discusses gas adsorption equilibrium and equilibrium of liquid adsorption - Gives the various steps of adsorbate uptake and their combination to yield adsorbate uptake rate expression - Presents both rational and empirical design for adsorption processes - Highlights common mistakes found in recent adsorption publications
This text discusses the synthesis, characterization, and application of metal-organic frameworks (MOFs) for the purpose of adsorbing gases. It provides details on the fundamentals of thermodynamics, mass transfer, and diffusion that are commonly required when evaluating MOF materials for gas separation and storage applications and includes a discussion of molecular simulation tools needed to examine gas adsorption in MOFs. Additionally, the work presents techniques that can be used to characterize MOFs after gas adsorption has occurred and provides guidance on the water stability of these materials. Lastly, applications of MOFs are considered with a discussion of how to measure the gas storage capacity of MOFs, a discussion of how to screen MOFs to for filtration applications, and a discussion of the use of MOFs to perform industrial separations, such as olefin/paraffin separations. Throughout the work, fundamental information, such as a discussion on the calculation of MOF surface area and description of adsorption phenomena in packed-beds, is balanced with a discussion of the results from research literature.
