Handbook of Telechelic Polyesters, Polycarbonates, and Polyethers
Handbook of Telechelic Polyesters, Polycarbonates, and Polyethers

Author: Sophie M. Guillaume

Publisher: CRC Press

Published: 2017-03-31

Total Pages: 328

ISBN-13: 1315340798

DOWNLOAD EBOOK

Telechelic polymers have garnered a great deal of scientific interest due to their reactive chain-end functions. This comprehensive book compiles and details the basic principles of and cutting-edge research in telechelic polyesters, polycarbonates, and polyethers, ranging from synthesis to applications. It discusses general strategies toward telechelic polymers, centered on the fundamental aspects of polycondensation reactions, of cationic, anionic, coordination-insertion, and activated monomer mechanisms of the metal-, enzyme-, or otherwise organocatalyzed ring-opening polymerization of cyclic monomers, and of postpolymerization chemical modification methods of polymer precursors. All main classes of polymers are covered separately, comprising polyhydroxyalkanoates, poly(ε-caprolactone)s, poly(lactic acid)s, polylactides, polycarobnates, and polyethers, including synthetic approaches as well as some illustrative, up-to-date examples and uses. The book also addresses applications of hydroxyl, thiol, amino, or acrylate/methacrylate end-capped polymers as starting materials for the preparation of diverse polymer architectures ranging from block, graft, and star-shaped polymers and micelles to precursors for ATRP macroinitiators, polyurethane copolymers, shape-memory polymers, or nanosized drug delivery systems. The book will appeal to advanced undergraduate- and graduate-level students of polymer science; researchers in macromolecular science, especially those with an interest in functional and reactive polymers; and polymer chemists in academia and industry.

Azo Polymers
Azo Polymers

Author: Xiaogong Wang

Publisher: Springer

Published: 2016-10-19

Total Pages: 238

ISBN-13: 366253424X

DOWNLOAD EBOOK

This book explores functional polymers containing aromatic azo chromophores in side-chain, main-chain and other parts of their structures, known as azo polymers and which share common photoresponsive properties. It focuses on the molecular architecture of azo polymers, the synthetic methods and their most important functions, such as photoinduced birefringence and dichroism, surface-relief-grating (SRG) formation, and light-driven deformation of liquid crystal elastomers. It combines a general survey of the subject and in-depth discussions of each topic, including numerous illustrations, figures, and photographs. Offering a balance between an introduction to the core concepts and a snapshot of hot and emerging topics, it is of interest to graduate students and researchers working in this and related fields. Xiaogong Wang is a Professor at the Department of Chemical Engineering, Tsinghua University, China.

Single-Chain Polymer Nanoparticles
Single-Chain Polymer Nanoparticles

Author: José A. Pomposo

Publisher: John Wiley & Sons

Published: 2017-08-18

Total Pages: 504

ISBN-13: 3527806393

DOWNLOAD EBOOK

This first book on this important and emerging topic presents an overview of the very latest results obtained in single-chain polymer nanoparticles obtained by folding synthetic single polymer chains, painting a complete picture from synthesis via characterization to everyday applications. The initial chapters describe the synthetics methods as well as the molecular simulation of these nanoparticles, while subsequent chapters discuss the analytical techniques that are applied to characterize them, including size and structural characterization as well as scattering techniques. The final chapters are then devoted to the practical applications in nanomedicine, sensing, catalysis and several other uses, concluding with a look at the future for such nanoparticles. Essential reading for polymer and materials scientists, materials engineers, biochemists as well as environmental chemists.

Block Copolymers
Block Copolymers

Author: Nikos Hadjichristidis

Publisher: John Wiley & Sons

Published: 2003-04-28

Total Pages: 445

ISBN-13: 0471461342

DOWNLOAD EBOOK

Polymers may be classified as either homopolymers, consisting of one single repeating unit, or copolymers, consisting of two or more distinct repeating units. Block copolymers contain long contiguous blocks of two or more repeating units in the same polymer chain. Covering one of the hottest topics in polymer chemistry, Block Copolymers provides a coherent overview of the synthetic routes, physical properties, and applications of block copolymers. This pioneering text provides not only a guideline for developing synthetic strategies for creating block copolymers with defined characteristics, but also a key to the relationship between the physical properties of block copolymers and the structure and dynamics of materials. Covering features of the chemistry and physics of block copolymers that are not found in comparable texts, Block Copolymers illustrates the structure-activity relationship of block copolymers and offers suggestions for the design of specific applications. Divided into five sections-Block Copolymers includes chapters on: * Block Copolymers by Chemical Modification of Precursor Polymers * Nonlinear Block Copolymers * Adsorption of Block Copolymers at Solid-Liquid Interfaces * Theory of Block Copolymer Segregation * Phase Transformation Kinetics * Block Copolymer Morphology * Block Copolymer Dynamics Polymer chemists, physicists, chemical engineers, and materials scientists, as well as graduate students in polymer science, will find Block Copolymers to be an invaluable text.

Amphiphilic Block Copolymers
Amphiphilic Block Copolymers

Author: P. Alexandridis

Publisher: Elsevier

Published: 2000-10-18

Total Pages: 449

ISBN-13: 0080527108

DOWNLOAD EBOOK

It is the belief of the editors of this book that the recognition of block copolymers as being amphiphilic molecules and sharing common features with other well-studied amphiphiles will prove beneficial to both the surfactant and the polymer communities. An aim of this book is to bridge the two communities and cross-fertilise the different fields. To this end, leading researchers in the field of amphiphilic block copolymer self-assembly, some having a background in surfactant chemistry, and others with polymer physics roots, have agreed to join forces and contribute to this book.The book consists of four entities. The first part discusses theoretical considerations behind the block copolymer self-assembly in solution and in the melt. The second part provides case studies of self-assembly in different classes of block copolymers (e.g., polyethers, polyelectrolytes) and in different environments (e.g., in water, in non-aqueous solvents, or in the absence of solvents). The third part presents experimental tools, ranging from static (e.g., small angle neutron scattering) to dynamic (e.g., rheology), which can prove valuable in the characterization of block copolymer self-assemblies. The fourth part offers a sampling of current applications of block copolymers in, e.g., formulations, pharmaceutics, and separations, applications which are based on the unique self-assembly properties of block copolymers.

Block Copolymers in Solution
Block Copolymers in Solution

Author: Ian W. Hamley

Publisher: John Wiley & Sons

Published: 2005-12-13

Total Pages: 300

ISBN-13: 0470016973

DOWNLOAD EBOOK

This unique text discusses the solution self-assembly of block copolymers and covers all aspects from basic physical chemistry to applications in soft nanotechnology. Recent advances have enabled the preparation of new materials with novel self-assembling structures, functionality and responsiveness and there have also been concomitant advances in theory and modelling. The present text covers the principles of self-assembly in both dilute and concentrated solution, for example micellization and mesophase formation, etc., in chapters 2 and 3 respectively. Chapter 4 covers polyelectrolyte block copolymers - these materials are attracting significant attention from researchers and a solid basis for understanding their physical chemistry is emerging, and this is discussed. The next chapter discusses adsorption of block copolymers from solution at liquid and solid interfaces. The concluding chapter presents a discussion of selected applications, focussing on several important new concepts. The book is aimed at researchers in polymer science as well as industrial scientists involved in the polymer and coatings industries. It will also be of interest to scientists working in soft matter self-assembly and self-organizing polymers.

Alternating Copolymers
Alternating Copolymers

Author: J.M.G. Cowie

Publisher: Springer Science & Business Media

Published: 2013-06-29

Total Pages: 292

ISBN-13: 1475791399

DOWNLOAD EBOOK

Examination of the early literature attests to the fact that the study of copolymerization was initiated when polymer science was in its infancy. It has continued to grow to a subject of major importance and has been a source of interest to both academic and industrialist alike. The wide spectrum of structures and properties available in the statistical copolymer has made this a fruitful field of exploration, but one particular and more restricted form which has held its own fascination for many is the limiting case of the strictly alternating copolymer. This is formed, in the ideal situation, when two monomers in a reaction mixture add consecutively to create a polymer chain with a regular {ABABAB} structure, irrespective of the monomer feed ratio. When this happens the resulting copolymer will always have the same composition, a feature which can be advantageous but also somewhat restrictive, as the ability to vary the properties is then limited. Within a series entitled Speciality Polymers it seems appropriate then to deal with this subject, particularly as no previous attempt has been made to draw together the various facets of alternating copolymerization into one volume. It also seems timely to present a more unified picture of the subject which will also illustrate the progress made.

Smart Light-Responsive Materials
Smart Light-Responsive Materials

Author: Y. Zhao

Publisher: John Wiley & Sons

Published: 2009-04-22

Total Pages: 542

ISBN-13: 0470439084

DOWNLOAD EBOOK

This book reviews the cutting-edge significant research in the field of smart light-responsive materials based on azobenzene polymers and liquid crystals. Emphasis is placed on the discovery of new phenomena from the past 5 years, their underlying mechanisms, new functionalities, and properties achieved through rational design. Edited by leading authorities in the field, Zhao and Ikeda, the chapters are authored by an internationally-recognized team of experts from North America, Europe, and Asia. Smart Light-Responsive Materials will serve to catalyze new research that will lead this field over the next 5-10 years.