Synthesis and Characterization of Bent-shaped Liquid Crystal

Synthesis and Characterization of Bent-shaped Liquid Crystal

Author: Kala a/p Shanku Pillay

Publisher:

Published: 2006

Total Pages: 100

ISBN-13:

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The field of liquid crystal is relatively new area of chemistry, and therefore generates a large frontier of research. The ability of being able to produce high resolution display screens for use in televisions or laptop computers with a very low power consumption, has revolutionised the technological market for this product. As a result of the success of the knowledge already known about liquid crystals and their properties, and their as yet unexplored potential, it is not suprising that there is an extremely large amount of research into the area. In relation to this, in this project, a five ring bent-shaped liquid crystal, which is relatively new compound in liquid crystalline phase, was synthesized using several organic synthesis methods, such as, Diazonium coupling reaction, Williamson ether synthesis, hydrolysis and reaction with resorcinol. The compounds synthesized were characterized through FTIR analysis, melting point, and its physical apperances. Other than that, the percent yield for each compound also have been calculated. The compound synthesized in first step, ethyl4-4-(hydroxyphenylazo)benzoate was a red color solid with melting point at 235 C and the percent yield was 52.07%. In second step 3.542 grams of Ethyl-4-(4-hexadecanoxyphenylazo)benzoate which orange in color with melting point of 135 C was obtained. The percent yield from the reaction was 42.11%. The third compound synthesized was yellow color solid with melting point of 280-290 C and the final compound was 1,3-Phenelyne bis[4-(4-hexadecanoxyphenylazo)benzoate], a pale yellow color solid with melting point at range of 130-135 C was obtained.


Bent-Shaped Liquid Crystals

Bent-Shaped Liquid Crystals

Author: Hideo Takezoe

Publisher: CRC Press

Published: 2017-07-20

Total Pages: 288

ISBN-13: 148224764X

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Bent-Shaped Liquid Crystals: Structures and Physical Properties provides insight into the latest developments in the research on liquid crystals formed by bent-shaped mesogens. After a historical introduction, the expert authors discuss different kinds of mesophase structures formed by bent-shaped molecules. This book devotes the majority of its pages to physical properties such as polar switching, optics and non-linear optics, and behavior in restricted geometries. However, as chemistry is often highly relevant to the emergence of new phases, particularly with reflection symmetry breaking, it also involves a broad spectrum of interesting chemistry viewpoints.


Design of Liquid Crystal Dimers and Trimers

Design of Liquid Crystal Dimers and Trimers

Author: Maria Gabriela Tamba

Publisher:

Published: 2014

Total Pages: 0

ISBN-13:

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Thermotropic liquid crystals; bent-core mesogens; calamitic mesogens; oligomers; chirality; anti(ferroelectricity); polar mesophases; dark-conglomerate-phases; electro-optic switching; X-ray scattering


Liquid Crystals

Liquid Crystals

Author: Tommaso Bellini

Publisher: Springer Science & Business Media

Published: 2012-01-21

Total Pages: 419

ISBN-13: 3642275907

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Fluorinated Liquid Crystals: Design of Soft Nanostructures and Increased Complexity of Self-Assembly by Perfluorinated Segments, by Carsten Tschierske Liquid Crystalline Crown Ethers, by Martin Kaller and Sabine Laschat Star-Shaped Mesogens – Hekates: The Most Basic Star Structure with Three Branches, by Matthias Lehmann DNA-Based Soft Phases, by Tommaso Bellini, Roberto Cerbino and Giuliano Zanchetta Polar and Apolar Columnar Phases Made of Bent-Core Mesogens, by N. Vaupotič, D. Pociecha and E. Gorecka Spontaneous Achiral Symmetry Breaking in Liquid Crystalline Phases, by H. Takezoe Nanoparticles in Liquid Crystals and Liquid Crystalline Nanoparticles, by Oana Stamatoiu, Javad Mirzaei, Xiang Feng and Torsten Hegmann Stimuli-Responsive Photoluminescent Liquid Crystals, by Shogo Yamane, Kana Tanabe, Yoshimitsu Sagara and Takashi Kato