This unique book gives a timely overview about the fundamentals and applications of supported ionic liquids in modern organic synthesis. It introduces the concept and synthesis of SILP materials and presents important applications in the field of catalysis (e.g. hydroformylation, hydrogenation, coupling reactions, fine chemical synthesis) as well as energy technology and gas separation. Written by pioneers in the field, this book is an invaluable reference book for organic chemists in academia or industry.
Although ionic liquids have only been studied in depth during the last decades, the field is now maturing to such a degree that the focus is on larger scale applications for use in real processes such as catalysis. Current information is scattered across the literature and Catalysis in Ionic Liquids provides a critical analysis of the research published to date on ionic solvents in all areas of the catalytic science. The book covers both catalyst synthesis using ionic liquids as solvents and green syntheses using both ionic liquids as well as mixtures of ionic liquids and carbon dioxide (as a subcritical and supercritical liquid), including enzymatic, homogeneous, and heterogeneous catalysis, electrocatalysis and organocatalysis. As well as the catalysis community, the book will also be of interest to postgraduates, postdoctoral workers and researchers in academia and industry working in organic synthesis, new materials synthesis, renewable sources of energy and electrochemistry. Written by leading experts in the field, this is the reference source to find about catalysis in ionic liquids.
Ionic Liquids in Separation Technology reports on the most important fundamental and technological advances in separation processes using ionic liquids. It brings together the latest developments in this fascinating field, supplements them with numerous practical tips, and thus provides those working in both research and industry with an indispensable source of information. The book covers fundamental topics of physical, thermal, and optical properties of ionic liquids, including green aspects. It then moves on to contexts and applications, including separation of proteins, reduction of environmental pollutants, separation of metal ions and organic compounds, use in electrochromic devices, and much more. For the specialist audience the book serves as a recompilation of the most important knowledge in this field, whereas for starting researchers in ionic liquid separation technology the book is a great introduction to the field. First book in the marketplace dedicated to ionic liquids in separation technology Contributions from scientists in academia and researchers in industry ensure the coverage of both scientific fundamentals and industrial applications Covers a broad collection of applications in separation technology which makes the book a single source of information Includes many practical tips for researchers in industry and scientists who apply ionic liquids in their work
Written by experts who have been part of this field since its beginnings in both research and academia, this textbook introduces readers to this evolving topic and the broad range of applications that are being explored. The book begins by examining what it is that defines ionic liquids and what sets them apart from other materials. Chapters describe the various types of ionic liquids and the different techniques used to synthesize them, as well as their properties and some of the methods used in their measurement. Further chapters delve into synthetic and electrochemical applications and their broad use as "Green" solvents. Final chapters examine important applications in a wide variety of contexts, including such devices as solar cells and batteries, electrochemistry, and biotechnology. The result is a must-have resource for any researcher beginning to work in this growing field, including senior undergraduates and postgraduates.
This book provides an overview of the current and emerging industrial applications of ionic liquids, covering the core processes, the practical implementation and technical challenges involved, and exploring potential future directions for research and development. The introductory chapter describes the unique physical and chemical properties of ionic liquids, and illustrates the vast potential for application of these materials across the industrial landscape. Following this, individual chapters written by leading figures from industry and academia address specific processes and products, such as the development of a new chloroaluminate ionic liquid as an alkylation catalyst and a new class of capillary gas chromatography (GC) columns with stationary phases based on ionic liquids. Over the past twenty years, ionic liquids have moved from being considered as mere academic curiosities to having genuine applications in fields as wide-ranging as biotechnology, biorefineries, catalysis, pharmaceuticals, renewable fuels, and sustainable energy. This book highlights several commercial products and processes that use or will soon be using ionic liquids.
This unique book gives a timely overview about the fundamentals and applications of supported ionic liquids in modern organic synthesis. It introduces the concept and synthesis of SILP materials and presents important applications in the field of catalysis (e.g. hydroformylation, hydrogenation, coupling reactions, fine chemical synthesis) as well as energy technology and gas separation. Written by pioneers in the field, this book is an invaluable reference book for organic chemists in academia or industry.
Due to their distinctive properties, ionic liquids have attracted the great and unflagging interest of researchers for over 30 years. This interest has been focused mainly on their use as a green alternative to volatile organic solvents. However, they often act not only as solvents but also as catalysts, catalyst immobilizers and initiators. Over 100 types of chemical reactions are known in which ionic liquids (ILs) were applied successfully. This Special Issue is aimed at showing the most recent advances and trends in the design, synthesis and characterization of catalysts based on ILs, as well as presenting their activity and application potential.
Ionic liquids (ILs) are a class of low melting point, ionic compounds which have a variety of properties allowing many of them to be sustainable green solvents. These non-molecular solvents possess high thermal stabilities and negligible vapour pressures making them attractive alternatives to environmentally unfriendly solvents that produce volatile organic compounds (VOCs). In this book, the authors present research on the properties, applications and hazards of ionic liquids. Some of the topics discussed include challenges and perspectives of ionic liquids vs. traditional solvents for cellulose processing; ionic liquids as sustainable extractants in petrochemical processing; bronsted acid-base ionic liquids and membranes as ion conducting materials; and, physical and chemical properties of ionic liquids.
Ionic Liquids in Organic Synthesis brings together leading scientists who have made major contributions to the field of ionic liquids. This book assembles several new methodologies that are interdisciplinary by nature, discussing the unique properties of ionic liquids and the ways in which they induce significant solvent effects on a wide range of pf processes. Twenty-two chapters are included. Ionic Liquids in Organic Synthesis covers areas of rapid progress and industrial importance. Ionic liquids are emerging as novel replacements for volatile organic compounds traditionally used as industrial solvents this book will elaborate on this subject while also examining practical synthetic applications of ionic liquids. This field has been an important topic of research for scientists in both industry and academia over the past 30 years and continues to grow.
This comprehensive database on physical properties of pure ionic liquids (ILs) contains data collected from 269 peer-reviewed papers in the period from 1982 to June 2008. There are more than 9,400 data points on the 29 kinds of physicochemical properties for 1886 available ionic liquids, from which 807 kinds of cations and 185 kinds of anions were extracted. This book includes nearly all known pure ILs and their known physicochemical properties through June 2008. In addition, the authors incorporate the main applications of individual ILs and a large number of references. Nearly 50 tables include typical data, experimental and modelling or simulation comparison, and model parameters, enhancing the application of ILs 100 figures--from QSPR, EOS and gE models to quantum and molecular simulations--help readers understand ILs at molecular level Applications illustrate the role of IL properties in industry, in particular the development of novel clean processes and products
