Atomically Precise Metal Nanoclusters
Atomically Precise Metal Nanoclusters

Author: Zhikun Wu

Publisher: Morgan & Claypool Publishers

Published: 2020-11-06

Total Pages: 141

ISBN-13: 1636390250

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Atomically precise metal nanocluster research has emerged as a new frontier. This book serves as an introduction to metal nanoclusters protected by ligands. The authors have summarized the synthesis principles and methods, the characterization methods and new physicochemical properties, and some potential applications. By pursuing atomic precision, such nanocluster materials provide unprecedented opportunities for establishing precise relationships between the atomic-level structures and the properties. The book should be accessible to senior undergraduate and graduate students, researchers in various fields (e.g., chemistry, physics, materials, biomedicine, and engineering), R&D scientists, and science policy makers.

Electrocrystallization
Electrocrystallization

Author: Alexander Milchev

Publisher: Springer Science & Business Media

Published: 2007-05-08

Total Pages: 274

ISBN-13: 0306475529

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“Electrocrystallization is a particular case of a first order phase transition” and “Electrocrystallization is a particular case of electrochemical kinetics” are two statements that I have heard and read many times. I do not like them for a simple reason: it is annoying to see that the subject to which you have devoted more than 30 years of your life may be considered as a “particular case”. Therefore, I decided to write this book in which Electrocrystallization is the main subject. To become competent in the field of Electrocrystallization one should possess knowledge of Electrochemistry, Nucleation and Crystal Growth, which means knowledge of Physical Chemistry, Physics and Mathematics. That is certainly difficult and in most cases those who study Electrocrystallization are either more electrochemists, or more physical chemists, or more physicists, very often depending on whom has been their teacher. Of course, there are scientists who consider themselves equally good in all those fields. Very frequently they are, unfortunately, equally bad. The difference is essential but strange enough, it is sometimes not easy to realize the truth immediately.

Platinum Monolayer Electrocatalysts
Platinum Monolayer Electrocatalysts

Author: Radoslav Adzic

Publisher: Springer

Published: 2021-08-13

Total Pages: 0

ISBN-13: 9783030495688

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This book describes a science and technology of a new type of electrocatalysts consisting of a single atomic layer of platinum on suitable supports. This development helped overcome three major obstacles—catalysts‘ cost, activity, and stability—for a broad range of fuel cell applications. The volume begins with a short introduction to the science of electrocatalysis, covering four reactions important for energy conversion in fuel cells. A description follows of the properties of metal monolayers on electrode surfaces, and underpotential deposition of metals. The authors then describe the concept of Pt monolayer electrocatalysts and its implications and their synthesis by galvanic displacement of less-noble metal monolayers and other methods. The main part of the book presents a discussion of catalysts’ characterization and catalytic properties of Pt monolayers for the four main reactions of electrochemical energy conversion: oxygen reduction and oxidation of hydrogen, methanol and ethanol. The book concludes with a treatment of scale-up syntheses, fuel cell tests, catalysts’ stability and application prospects.

Metal-Air Batteries
Metal-Air Batteries

Author: Xin-bo Zhang

Publisher: John Wiley & Sons

Published: 2019-02-11

Total Pages: 432

ISBN-13: 3527342796

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A comprehensive overview of the research developments in the burgeoning field of metal-air batteries An innovation in battery science and technology is necessary to build better power sources for our modern lifestyle needs. One of the main fields being explored for the possible breakthrough is the development of metal-air batteries. Metal-Air Batteries: Fundamentals and Applications offers a systematic summary of the fundamentals of the technology and explores the most recent advances in the applications of metal-air batteries. Comprehensive in scope, the text explains the basics in electrochemical batteries and introduces various species of metal-air batteries. The author-a noted expert in the field-explores the development of metal-air batteries in the order of Li-air battery, sodium-air battery, zinc-air battery and Mg-O2 battery, with the focus on the Li-air battery. The text also addresses topics such as metallic anode, discharge products, parasitic reactions, electrocatalysts, mediator, and X-ray diffraction study in Li-air battery. Metal-Air Batteries provides a summary of future perspectives in the field of the metal-air batteries. This important resource: -Covers various species of metal-air batteries and their components as well as system designation -Contains groundbreaking content that reviews recent advances in the field of metal-air batteries -Focuses on the battery systems which have the greatest potential for renewable energy storage Written for electrochemists, physical chemists, materials scientists, professionals in the electrotechnical industry, engineers in power technology, Metal-Air Batteries offers a review of the fundamentals and the most recent developments in the area of metal-air batteries.

Interfacial Electrochemistry
Interfacial Electrochemistry

Author: Wolfgang Schmickler

Publisher: Springer Science & Business Media

Published: 2010-08-26

Total Pages: 273

ISBN-13: 3642049370

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Electrochemistry is an old branch of physical chemistry. Due to the development of surface sensitive techniques, and a technological interest in fuel cells and batteries, it has recently undergone a rapid development. This textbook treats the field from a modern, atomistic point of view while integrating the older, macroscopic concepts. The increasing role of theory is reflected in the presentation of the basic ideas in a way that should appeal to experimentalists and theorists alike. Special care is taken to make the subject comprehensible to scientists from neighboring disciplines, especially from surface science. The book is suitable for an advanced course at the master or Ph.D. level, but should also be useful for practicing electrochemists, as well as to any scientist who wants to understand modern electrochemistry.

Design and Development of Nanostructured Thin Films
Design and Development of Nanostructured Thin Films

Author: Antonella Macagnano

Publisher: MDPI

Published: 2020-05-13

Total Pages: 386

ISBN-13: 3039287389

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Due to their unique size-dependent physicochemical properties, nanostructured thin films are used in a wide range of applications from smart coating and drug delivery to electrocatalysis and highly-sensitive sensors. Depending on the targeted application and the deposition technique, these materials have been designed and developed by tuning their atomic-molecular 2D- and/or 3D-aggregation, thickness, crystallinity, and porosity, having effects on their optical, mechanical, catalytic, and conductive properties. Several open questions remain about the impact of nanomaterial production and use on environment and health. Many efforts are currently being made not only to prevent nanotechnologies and nanomaterials from contributing to environmental pollution but also to design nanomaterials to support, control, and protect the environment. This Special Issue aims to cover the recent advances in designing nanostructured films focusing on environmental issues related to their fabrication processes (e.g., low power and low cost technologies, the use of environmentally friendly solvents), their precursors (e.g., waste-recycled, bio-based, biodegradable, and natural materials), their applications (e.g., controlled release of chemicals, mimicking of natural processes, and clean energy conversion and storage), and their use in monitoring environment pollution (e.g., sensors optically- or electrically-sensitive to pollutants)

Electrochemical Surface Science: Basics and Applications
Electrochemical Surface Science: Basics and Applications

Author: Gaetano Granozzi

Publisher: MDPI

Published: 2019-10-07

Total Pages: 398

ISBN-13: 3039216422

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Electrochemical surface science (EC-SS) is the natural advancement of traditional surface science (where gas–vacuum/solid interfaces are studied) to liquid (solution)/electrified solid interfaces. Such a merging between two different disciplines—i.e., surface science (SS) and electrochemistry—officially advanced ca. three decades ago. The main characteristic of EC-SS versus electrochemistry is the reductionist approach undertaken, inherited from SS and aiming to understand the microscopic processes occurring at electrodes on the atomic level. A few of the exemplary keystone tools of EC-SS include EC-scanning probe microscopies, operando and in situ spectroscopies and electron microscopies, and differential EC mass spectrometry (DEMS). EC-SS indirectly (and often unconsciously) receives a great boost from the requirement for rational design of energy conversion and storage devices for the next generation of energetic landscapes. As a matter of fact, the number of material science groups deeply involved in such a challenging field has tremendously expanded and, within such a panorama, EC and SS investigations are intimately combined in a huge number of papers. The aim of this Special Issue is to offer an open access forum where researchers in the field of electrochemistry, surface science, and materials science could outline the great advances that can be reached by exploiting EC-SS approaches. Papers addressing both the basic science and more applied issues in the field of EC-SS and energy conversion and storage materials have been published in this Special Issue.

Metal Electrodeposition
Metal Electrodeposition

Author: Magdalena Nuñez

Publisher: Nova Publishers

Published: 2005

Total Pages: 226

ISBN-13: 9781594544569

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Electrochemistry is the branch of chemistry that deals with the chemical action of electricity and the production of electricity by chemical reactions. In a world short of energy sources yet long on energy use, electrochemistry is a critical component of the mix necessary to keep the world economies growing. Electrochemistry is involved with such important applications as batteries, fuel cells, corrosion studies, hydrogen energy conversion, and bioelectricity. Research on electrolytes, cells, and electrodes is within the scope of this old but extremely dynamic field. This book details advances in metal electrodeposition.

Photoelectrocatalysis
Photoelectrocatalysis

Author: Leonardo Palmisano

Publisher: Elsevier

Published: 2022-10-21

Total Pages: 488

ISBN-13: 0128242426

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Photoelectrocatalysis: Fundamentals and Applications presents an in-depth review of the topic for students and researchersworking on photoelectrocatalysis-related subjects from pure chemistry to materials and environmental chemistry inorder to propose applications and new perspectives. The main advantage of a photoelectrocatalytic process is the mildexperimental conditions under which the reactions are carried out, which are often possible at atmospheric pressure androom temperature using cheap and nontoxic solvents (e.g., water), oxidants (e.g., O2 from the air), catalytic materials (e.g.,TiO2 on Ti layer), and the potential exploitation of solar light. This book presents the fundamentals and the applications of photoelectrocatalysis, such as hydrogen production fromwater splitting, the remediation of harmful compounds, and CO2 reduction. Photoelectrocatalytic reactors and lightsources, in addition to kinetic aspects, are presented along with an exploration of the relationship between photocatalysisand electrocatalysis. In addition, photocorrosion issues and the application of selective photoelectrocatalytic organictransformations, which is now a growing field of research, are also reported. Finally, the advantages/disadvantages andfuture perspectives of photoelectrocatalysis are highlighted through the possibility of working at a pilot/industrial scale inenvironmentally friendly conditions. - Presents the fundamentals of photoelectrocatalysis - Outlines photoelectrocatalytic green chemistry - Reviews photoelectrocatalytic remediation of harmful compounds, hydrogen production, and CO2 reduction - Includes photocorrosion, photoelectrocatalytic reactors, and modeling along with kinetic aspects