Reactive Extraction
Reactive Extraction

Author: Hans-Jörg Bart

Publisher: Springer Science & Business Media

Published: 2013-04-17

Total Pages: 224

ISBN-13: 366204403X

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This booklet is designed to bridge the gap between handbooks and technical literature and aims at graduate students or experienced readers. Commercial flow sheeting simulation software is increasingly available and is used in the early steps of process design in industry. As to this, more sophisticated and precise models based on activities instead of concentrations should be used. After an introductory chapter there is in Chapter 2 an intensive discussion of reactive phase equilibria of ionic and non-ionic solutes based on chemical potentials. Chapter 3 introduces to multicomponent diffusion and mass transfer. However, the main focus is on the reactive mass transfer on rigid and mobile surfaces where the interfacial reaction, molecular diffusion and adsorption layers are decisive. The respective extraction of zinc with a cation exchanger and of acetic acid with an anion exchanger is discussed as case studies. Since adsorption layers and surfactants have a major impact on liquid-liquid extraction efficiency, the final chapter reviews several tech niques which make use of polymeric species in an extractive process. A short review is also given on extraction apparatus and the hydrodynamics (hydraulic design, droplet populance balances) of columns. Much of the booklet is based on the PhD works of C. Czapla (2000), G. Modes (2000), H. Klocker (1996), T. Kronberger (1995), M. Marters (2000), M. Roos (2000), M. Traving (2000) and B. Wachter (1996) who I wish to thank for their fruitful contributions.

Introduction to Non-equilibrium Physical Chemistry
Introduction to Non-equilibrium Physical Chemistry

Author: R. P. Rastogi

Publisher: Elsevier

Published: 2007-10-16

Total Pages: 357

ISBN-13: 0080551807

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Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. - The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium - Experimental studies have been reported which provide test of the theories and their limitations - Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed

High Temperature Oxidation and Corrosion of Metals
High Temperature Oxidation and Corrosion of Metals

Author: David John Young

Publisher: Elsevier

Published: 2008-10-03

Total Pages: 593

ISBN-13: 008044587X

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The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.

Applications of Nanofluid for Heat Transfer Enhancement
Applications of Nanofluid for Heat Transfer Enhancement

Author: Mohsen Sheikholeslami

Publisher: William Andrew

Published: 2017-02-26

Total Pages: 620

ISBN-13: 0128123982

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Applications of Nanofluid for Heat Transfer Enhancement explores recent progress in computational fluid dynamic and nonlinear science and its applications to nanofluid flow and heat transfer. The opening chapters explain governing equations and then move on to discussions of free and forced convection heat transfers of nanofluids. Next, the effect of nanofluid in the presence of an electric field, magnetic field, and thermal radiation are investigated, with final sections devoted to nanofluid flow in porous media and application of nanofluid for solidification. The models discussed in the book have applications in various fields, including mathematics, physics, information science, biology, medicine, engineering, nanotechnology, and materials science. - Presents the latest information on nanofluid free and force convection heat transfer, of nanofluid in the presence of thermal radiation, and nanofluid in the presence of an electric field - Provides an understanding of the fundamentals in new numerical and analytical methods - Includes codes for each modeling method discussed, along with advice on how to best apply them

Academic Press Dictionary of Science and Technology
Academic Press Dictionary of Science and Technology

Author: Christopher G. Morris

Publisher: Gulf Professional Publishing

Published: 1992-08-27

Total Pages: 2488

ISBN-13: 9780122004001

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A Dictonary of Science and Technology. Color Illustration Section. Symbols and Units. Fundamental Physical Constants. Measurement Conversion. Periodic Table of the Elements. Atomic Weights. Particles. The Solar System. Geologial Timetable. Five-Kingdom Classification of Organisms. Chronology of Modern Science. Photo Credits.