The influence of size effects on the properties of nanostructures is subject of this book. Size and interfacial effects in oxides, semiconductors, magnetic and superconducting nanostructures, from very simple to very complex, are considered. The most general meaning is assumed for size effects, including not only the influence of a reduced dimension/dimensionality, but also specific interfacial effects. Preparation and characterization tools are explained for various nanostructures. The specific applications are discussed with respect to size-related properties. A logic implication of type phenomenon-property-material-application is envisaged throughout this work.
This book can be roughly divided into three parts: fundamental physico-chemical and physical principles of Nanoscience, chemistry and synthesis of nanoparticles, and techniques to study nanoparticles. The first chapter is concerned with the origin of the size dependence of the properties of nanomaterials, explaining it in terms of two fundamental nanoscale effects. This chapter also serves as a general introduction to the book, briefly addressing the definition and classification of nanomaterials and the techniques used to fabricate and study them. Chapter 2 lays out the theoretical framework within which to understand size effects on the properties of semiconductor nanocrystals, with particular emphasis on the quantum confinement effect. The optical properties of metal nanoparticles and metal nanostructures (periodic lattices) are discussed in Chapter 3. Chapter 4 is devoted to nanoporous materials, treating in detail their synthesis, structure and functional properties, as well as the physical properties of liquids confined in nanopores. The preparation methods, characterization techniques, and applications of supported nanoparticles are covered in Chapter 5. The sixth Chapter presents the essential physical-chemical concepts needed to understand the preparation of colloidal inorganic nanoparticles, and the remarkable degree of control that has been achieved over their composition, size, shape and surface. The last four Chapters are dedicated to a few selected characterization techniques that are very valuable tools to study nanoparticles. Chapter 7 concentrates on electron microscopy techniques, while Chapter 8 focuses on scanning probe microscopy and spectroscopy. Electron paramagnetic resonance (EPR) based spectroscopic techniques and their application to nanoparticles are explored in Chapter 9. Finally, Chapter 10 shows how solution Nuclear Magnetic Resonance (NMR) spectroscopic techniques can be used to unravel the surface chemistry of colloidal nanoparticles.
This Handbook focuses on the recent advancements in Safety, Risk, Ethical Society and Legal Implications (ESLI) as well as its commercialization of nanotechnology, such as manufacturing. Nano is moving out of its relaxation phase of scientific route, and as new products go to market, organizations all over the world, as well as the general public, are discussing the environmental and health issues associated with nanotechnology. Nongovernmental science organizations have long since reacted; however, now the social sciences have begun to study the cultural portent of nanotechnology. Societal concerns and their newly constructed concepts, show nanoscience interconnected with the economy, ecology, health, and governance. This handbook addresses these new challenges and is divided into 7 sections: Nanomaterials and the Environment; Life Cycle Environmental Implications of Nanomanufacturing; Bioavailability and Toxicity of Manufactured Nanoparticles in Terrestrial Environments; Occupational Health Hazards of Nanoparticles; Ethical Issues in Nanotechnology; Commercialization of Nanotechnology; Legalization of Nanotechnology.
This Handbook covers all aspects of Nanoparticles, from their preparation to their practical application. The chapters present different ways to synthesize nanometer particles, as well as their functionalization and other surface treatments to allow them to a practical use. Several industrial applications of such nanometer particles are also covered in this Handbook. It is a complete reference for those working with Nanotechnology at the lab level, from students to professionals.
Ellipsometry is a powerful tool used for the characterization of thin films and multi-layer semiconductor structures. This book deals with fundamental principles and applications of spectroscopic ellipsometry (SE). Beginning with an overview of SE technologies the text moves on to focus on the data analysis of results obtained from SE, Fundamental data analyses, principles and physical backgrounds and the various materials used in different fields from LSI industry to biotechnology are described. The final chapter describes the latest developments of real-time monitoring and process control which have attracted significant attention in various scientific and industrial fields.
Organized nanoassemblies of inorganic nanoparticles and organic molecules are building blocks of nanodevices, whether they are designed to perform molecular level computing, sense the environment or improve the catalytic properties of a material. The key to creation of these hybrid nanostructures lies in understanding the chemistry at a fundamental level. This book serves as a reference book for researchers by providing fundamental understanding of many nanoscopic materials.
Systematically summarizes the current status and recent advances in bimetallic structures, their shape-controlled synthesis, properties, and applications Intensive researches are currently being carried out on bimetallic nanostructures, focusing on a number of fundamental, physical, and chemical questions regarding their synthesis and properties. This book presents a systematic and comprehensive summary of the current status and recent advances in this field, supporting readers in the synthesis of model bimetallic nanoparticles, and the exploration and interpretation of their properties. Bimetallic Nanostructures: Shape-Controlled Synthesis for Catalysis, Plasmonics and Sensing Applications is divided into three parts. Part 1 introduces basic chemical and physical knowledge of bimetallic structures, including fundamentals, computational models, and in situ characterization techniques. Part 2 summarizes recent developments in synthetic methods, characterization, and properties of bimetallic structures from the perspective of morphology effect, including zero-dimensional nanomaterials, one-dimensional nanomaterials, and two-dimensional nanomaterials. Part 3 discusses applications in electrocatalysis, heterogeneous catalysis, plasmonics and sensing. Comprehensive reference for an important multidisciplinary research field Thoroughly summarizes the present state and latest developments in bimetallic structures Helps researchers find optimal synthetic methods and explore new phenomena in surface science and synthetic chemistry of bimetallic nanostructures Bimetallic Nanostructures: Shape-Controlled Synthesis for Catalysis, Plasmonics and Sensing Applications is an excellent source or reference for researchers and advanced students. Academic researchers in nanoscience, nanocatalysis, and surface plasmonics, and those working in industry in areas involving nanotechnology, catalysis and optoelectronics, will find this book of interest.
Textbook introducing engineers to quantum mechanics and nanostructures, covering the fundamentals and applications to nanoscale materials and nanodevices.
Nanoparticle technology, which handles the preparation, processing, application and characterisation of nanoparticles, is a new and revolutionary technology. It becomes the core of nanotechnology as an extension of the conventional Fine Particle / Powder Technology. Nanoparticle technology plays an important role in the implementation of nanotechnology in many engineering and industrial fields including electronic devices, advanced ceramics, new batteries, engineered catalysts, functional paint and ink, Drug Delivery System, biotechnology, etc.; and makes use of the unique properties of the nanoparticles which are completely different from those of the bulk materials.This new handbook is the first to explain complete aspects of nanoparticles with many application examples showing their advantages and advanced development. There are handbooks which briefly mention the nanosized particles or their related applications, but no handbook describing the complete aspects of nanoparticles has been published so far.The handbook elucidates of the basic properties of nanoparticles and various nanostructural materials with their characterisation methods in the first part. It also introduces more than 40 examples of practical and potential uses of nanoparticles in the later part dealing with applications. It is intended to give readers a clear picture of nanoparticles as well as new ideas or hints on their applications to create new materials or to improve the performance of the advanced functional materials developed with the nanoparticles.* Introduces all aspects of nanoparticle technology, from the fundamentals to applications.* Includes basic information on the preparation through to the characterization of nanoparticles from various viewpoints * Includes information on nanostructures, which play an important role in practical applications.
Recent developments in the technology of silicon nanocrystals and silicon nanostructures, where quantum-size effects are important, are systematically described including examples of device applications. Due to the strong quantum confinement effect, the material properties are freed from the usual indirect- or direct-bandgap regime, and the optical, electrical, thermal, and chemical properties of these nanocrystalline and nanostructured semiconductors are drastically changed from those of bulk silicon. In addition to efficient visible luminescence, various other useful material functions are induced in nanocrystalline silicon and periodic silicon nanostructures. Some novel devices and applications, in fields such as photonics (electroluminescence diode, microcavity, and waveguide), electronics (single-electron device, spin transistor, nonvolatile memory, and ballistic electron emitter), acoustics, and biology, have been developed by the use of these quantum-induced functions in ways different from the conventional scaling principle for ULSI.
