Selective Oxidation by Heterogeneous Catalysis
Selective Oxidation by Heterogeneous Catalysis

Author: Gabriele Centi

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 519

ISBN-13: 1461541751

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Selective Oxidation by Heterogeneous Catalysis covers one of the major areas of industrial petrochemical production, outlining open questions and new opportunities. It gives keys for the interpretation and analysis of data and design of new catalysts and reactions, and provides guidelines for future research. A distinctive feature of this book is the use of concept by example. Rather than reporting an overview of the literature results, the authors have selected some representative examples, the in-depth analysis of which makes it possible to clarify the fundamental, but new concepts necessary for a better understanding of the new opportunities in this field and the design of new catalysts or catalytic reactions. Attention is given not only to the catalyst itself, but also to the use of the catalyst inside the process, thus evidencing the relationship between catalyst design and engineering aspects of the process. This book provides suggestions for new innovative directions of research and indications on how to reconsider the field of selective oxidation from different perspectives, outlining that is not a mature field of research, but that new important breakthroughs can be derived from fundamental and applied research. Suggestions are offered on how to use less conventional approaches in terms of both catalyst design and analysis of the data.

Selective Oxidation by Heterogeneous Catalysis
Selective Oxidation by Heterogeneous Catalysis

Author: Gabriele Centi

Publisher: Boom Koninklijke Uitgevers

Published: 2001-03-31

Total Pages: 534

ISBN-13: 9780306462658

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Three Italian industrial chemists examine one of the major areas of industrial petrochemical production, concentrating on open questions and new opportunities rather than the cutting-edge techniques themselves. They survey recent developments that have been driven by the need for alternative, less expensive reagents and the mandate to reduce the environmental impact of chemical production processes, analyzing representative examples in-depth analysis to help clarify the basic but new concepts for designing new catalysts or catalytic reactions. They also identify new directions of both basic and industrial research that seem likely to lead to new breakthroughs. They assume a basic knowledge of homogeneous and heterogeneous catalysis at the level of a graduate or practicing engineer. Annotation copyrighted by Book News Inc., Portland, OR

Liquid Phase Oxidation via Heterogeneous Catalysis
Liquid Phase Oxidation via Heterogeneous Catalysis

Author: Mario G. Clerici

Publisher: John Wiley & Sons

Published: 2013-04-26

Total Pages: 438

ISBN-13: 1118356756

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Sets the stage for environmentally friendly industrial organic syntheses From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid-phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. Liquid Phase Oxidation via Heterogeneous Catalysis features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers: Selective oxidations catalyzed by TS-1 and other metal-substituted zeolites Selective catalytic oxidation over ordered nanoporous metallo-aluminophosphates Selective oxidations catalyzed by mesoporous metal-silicates Liquid phase oxidation of organic compounds by supported metal-based catalysts Selective liquid phase oxidations in the presence of supported polyoxometalates Selective oxidations catalyzed by supported metal complexes Liquid phase oxidation of organic compounds by metal-organic frameworks Heterogeneous photocatalysis for selective oxidations with molecular oxygen All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications.

Modern Heterogeneous Oxidation Catalysis
Modern Heterogeneous Oxidation Catalysis

Author: Noritaka Mizuno

Publisher: John Wiley & Sons

Published: 2009-11-18

Total Pages: 356

ISBN-13: 3527627553

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Filling a gap in the current literature, this comprehensive reference presents all important catalyst classes, including metal oxides, polyoxometalates, and zeolites. Readers will find here everything they need to know -- from structure design to characterization, and from immobilization to industrial processes. A true must-have for anyone working in this key technology.

Vanadium Catalysis
Vanadium Catalysis

Author: Manas Sutradhar

Publisher: Royal Society of Chemistry

Published: 2020-11-05

Total Pages: 526

ISBN-13: 1839160896

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Vanadium is one of the more abundant elements in the Earth’s crust and exhibits a wide range of oxidation states in its compounds making it potentially a more sustainable and more economical choice as a catalyst than the noble metals. A wide variety of reactions have been found to be catalysed by homogeneous, supported and heterogeneous vanadium complexes and the number of applications is growing fast. Bringing together the research on the catalytic uses of this element into one essential resource, including theoretical perspectives on proposed mechanisms for vanadium catalysis and an overview of its relevance in biological processes, this book is a useful reference for industrial and academic chemists alike.

Heterogeneous Catalysis and Fine Chemicals IV
Heterogeneous Catalysis and Fine Chemicals IV

Author: H.U. Blaser

Publisher: Elsevier

Published: 1997-06-19

Total Pages: 693

ISBN-13: 0080533930

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After three meetings in Poitiers, France, the 4th International Symposium on Heterogeneous Catalysis and Fine Chemicals was held under the auspices of the New Swiss Chemical Society in Basel, Switzerland. Fundamental as well as applied contributions on the use of heterogeneous catalysis for the preparation of fine chemicals were presented and discussed.The program consisted of 4 plenary lectures, 28 oral contributions and around 90 posters covering a broad range of reactions and catalytic aspects. 82 of these contributions are collected in the present proceedings, grouped into the following 8 topical areas:- Industrial and engineering problems (7 contributions)- Alkylation and acylation reactions (11 contributions)- Enantio- and diastereoselective hydrogenation reactions (9 contributions)- Chemoselective hydrogenation reactions (12 contributions)- Oxidation reactions (14 contributions)- Immobilized and encapsulated complex catalysts (12 contributions)- Zeolite and clay catalysts (12 contributions)- Miscellaneous topics (5 contributions)

Heterogeneous Catalysts for Clean Technology
Heterogeneous Catalysts for Clean Technology

Author: Karen Wilson

Publisher: John Wiley & Sons

Published: 2013-09-17

Total Pages: 466

ISBN-13: 3527659005

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Reactive, but not a reactant. Heterogeneous catalysts play an unseen role in many of today's processes and products. With the increasing emphasis on sustainability in both products and processes, this handbook is the first to combine the hot topics of heterogeneous catalysis and clean technology. It focuses on the development of heterogeneous catalysts for use in clean chemical synthesis, dealing with how modern spectroscopic techniques can aid the design of catalysts for use in liquid phase reactions, their application in industrially important chemistries - including selective oxidation, hydrogenation, solid acid- and base-catalyzed processes - as well as the role of process intensification and use of renewable resources in improving the sustainability of chemical processes. With its emphasis on applications, this book is of high interest to those working in the industry.

Metal Oxides in Heterogeneous Catalysis
Metal Oxides in Heterogeneous Catalysis

Author: Jacques C. Vedrine

Publisher: Elsevier

Published: 2018-01-11

Total Pages: 620

ISBN-13: 0128116323

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Metal Oxides in Heterogeneous Catalysis is an overview of the past, present and future of heterogeneous catalysis using metal oxides catalysts. The book presents the historical, theoretical, and practical aspects of metal oxide-based heterogeneous catalysis. Metal Oxides in Heterogeneous Catalysis deals with fundamental information on heterogeneous catalysis, including reaction mechanisms and kinetics approaches.There is also a focus on the classification of metal oxides used as catalysts, preparation methods and touches on zeolites, mesoporous materials and Metal-organic frameworks (MOFs) in catalysis. It will touch on acid or base-type reactions, selective (partial) and total oxidation reactions, and enzymatic type reactions The book also touches heavily on the biomass applications of metal oxide catalysts and environmentally related/depollution reactions such as COVs elimination, DeNOx, and DeSOx. Finally, the book also deals with future trends and prospects in metal oxide-based heterogeneous catalysis. - Presents case studies in each chapter that provide a focus on the industrial applications - Includes fundamentals, key theories and practical applications of metal oxide-based heterogeneous catalysis in one comprehensive resource - Edited, and contributed, by leading experts who provide perspectives on synthesis, characterization and applications

Ultrathin Oxide Layers for Solar and Electrocatalytic Systems
Ultrathin Oxide Layers for Solar and Electrocatalytic Systems

Author: Heinz Frei

Publisher: Royal Society of Chemistry

Published: 2022-01-04

Total Pages: 321

ISBN-13: 1839163712

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Ultrathin metal oxide layers have emerged in recent years as a powerful approach for substantially enhancing the performance of photo, electro, or thermal catalytic systems for energy, in some cases even enabling the use of highly attractive materials previously found unsuitable. This development is due to the confluence of new synthetic preparation methods for ultrathin oxide layers and a more advanced understanding of interfacial phenomena on the nano and atomic scale. This book brings together the fundamentals and applications of ultrathin oxide layers while highlighting connections and future opportunities with the intent of accelerating the use of these materials and techniques for new and emerging applications of catalysis for energy. It comprehensively covers the state-of-the-art synthetic methods of ultrathin oxide layers, their structural and functional characterization, and the broad range of applications in the field of catalysis for energy. Edited by leaders in the field, and with contributions from global experts, this title will be of interest to graduate students and researchers across materials science and chemistry who are interested in ultrathin oxide layers and their applications in solar energy conversion, renewable energy, photocatalysis, electrocatalysis and protective coatings.