In this book, the authors focus on the improvement of the scientific base for the development of environmental risk indicators measured by the presence of pollutants in water and porous media. In pursuit of a correct and complete numerical approach, they deliver insight into the understanding of integrated process, and also of modeling capabilities.
Ground water reactive transport models are useful to assess and quantify contaminant precipitation, absorption and migration in subsurface media. Many ground water reactive transport models available today are characterized by varying complexities, strengths, and weaknesses. Selecting accurate, efficient models can be a challenging task. This book addresses the needs, issues and challenges relevant to selecting a ground water reactive transport model to evaluate natural attenuation and alternative remediation schemes. It should serve as a handy guide for water resource managers seeking to achieve economically feasible results.
Ground water reactive transport models are useful to assess and quantify contaminant precipitation, absorption and migration in subsurface media. Many ground water reactive transport models available today are characterized by varying complexities, strengths, and weaknesses. Selecting accurate, efficient models can be a challenging task. This ebook addresses the needs, issues and challenges relevant to selecting a ground water reactive transport model to evaluate natural attenuation and alternative remediation schemes. It should serve as a handy guide for water resource managers seeking to ach.
Volume 34 of Reviews in Mineralogy focuses on methods to describe the extent and consequences of reactive flow and transport in natural subsurface systems. Since the field of reactive transport within the Earth Sciences is a highly multidisciplinary area of research, including geochemistry, geology, physics, chemistry, hydrology, and engineering, this book is an attempt to some extent bridge the gap between these different disciplines. This volume contains the contributions presented at a short course held in Golden, Colorado, October 25-27, 1996 in conjunction with the Mineralogical Society of America's (MSA) Annual Meeting with the Geological Society of America in Denver, Colorado.
In this book, the authors focus on the improvement of the scientific base for the development of environmental risk indicators measured by the presence of pollutants in water and porous media. In pursuit of a correct and complete numerical approach, they deliver insight into the understanding of integrated process, and also of modeling capabilities.
Open system behavior is predicated on a fundamental relationship between the timescale over which mass is transported and the timescale over which it is chemically transformed. This relationship describes the basis for the multidisciplinary field of reactive transport (RT). In the 20 years since publication of Review in Mineralogy and Geochemistry volume 34: Reactive Transport in Porous Media, RT principles have expanded beyond early applications largely based in contaminant hydrology to become broadly utilized throughout the Earth Sciences. RT is now employed to address a wide variety of natural and engineered systems across diverse spatial and temporal scales, in tandem with advances in computational capability, quantitative imaging and reactive interface characterization techniques. The present volume reviews the diversity of reactive transport applications developed over the past 20 years, ranging from the understanding of basic processes at the nano- to micrometer scale to the prediction of Earth global cycling processes at the watershed scale. Key areas of RT development are highlighted to continue advancing our capabilities to predict mass and energy transfer in natural and engineered systems.
In many parts of the world, groundwater resources are under increasing threat from growing demands, wasteful use, and contamination. To face the challenge, good planning and management practices are needed. A key to the management of groundwater is the ability to model the movement of fluids and contaminants in the subsurface. The purpose of this book is to construct conceptual and mathematical models that can provide the information required for making decisions associated with the management of groundwater resources, and the remediation of contaminated aquifers. The basic approach of this book is to accurately describe the underlying physics of groundwater flow and solute transport in heterogeneous porous media, starting at the microscopic level, and to rigorously derive their mathematical representation at the macroscopic levels. The well-posed, macroscopic mathematical models are formulated for saturated, single phase flow, as well as for unsaturated and multiphase flow, and for the transport of single and multiple chemical species. Numerical models are presented and computer codes are reviewed, as tools for solving the models. The problem of seawater intrusion into coastal aquifers is examined and modeled. The issues of uncertainty in model input data and output are addressed. The book concludes with a chapter on the management of groundwater resources. Although one of the main objectives of this book is to construct mathematical models, the amount of mathematics required is kept minimal.
This second edition is extensively revised throughout with expanded discussion of modeling fundamentals and coverage of advances in model calibration and uncertainty analysis that are revolutionizing the science of groundwater modeling. The text is intended for undergraduate and graduate level courses in applied groundwater modeling and as a comprehensive reference for environmental consultants and scientists/engineers in industry and governmental agencies. - Explains how to formulate a conceptual model of a groundwater system and translate it into a numerical model - Demonstrates how modeling concepts, including boundary conditions, are implemented in two groundwater flow codes-- MODFLOW (for finite differences) and FEFLOW (for finite elements) - Discusses particle tracking methods and codes for flowpath analysis and advective transport of contaminants - Summarizes parameter estimation and uncertainty analysis approaches using the code PEST to illustrate how concepts are implemented - Discusses modeling ethics and preparation of the modeling report - Includes Boxes that amplify and supplement topics covered in the text - Each chapter presents lists of common modeling errors and problem sets that illustrate concepts
Teaches the application of Reactive Transport Modeling (RTM) for subsurface systems in order to expedite the understanding of the behavior of complex geological systems This book lays out the basic principles and approaches of Reactive Transport Modeling (RTM) for surface and subsurface environments, presenting specific workflows and applications. The techniques discussed are being increasingly commonly used in a wide range of research fields, and the information provided covers fundamental theory, practical issues in running reactive transport models, and how to apply techniques in specific areas. The need for RTM in engineered facilities, such as nuclear waste repositories or CO2 storage sites, is ever increasing, because the prediction of the future evolution of these systems has become a legal obligation. With increasing recognition of the power of these approaches, and their widening adoption, comes responsibility to ensure appropriate application of available tools. This book aims to provide the requisite understanding of key aspects of RTM, and in doing so help identify and thus avoid potential pitfalls. Reactive Transport Modeling covers: the application of RTM for CO2 sequestration and geothermal energy development; reservoir quality prediction; modeling diagenesis; modeling geochemical processes in oil & gas production; modeling gas hydrate production; reactive transport in fractured and porous media; reactive transport studies for nuclear waste disposal; reactive flow modeling in hydrothermal systems; and modeling biogeochemical processes. Key features include: A comprehensive reference for scientists and practitioners entering the area of reactive transport modeling (RTM) Presented by internationally known experts in the field Covers fundamental theory, practical issues in running reactive transport models, and hands-on examples for applying techniques in specific areas Teaches readers to appreciate the power of RTM and to stimulate usage and application Reactive Transport Modeling is written for graduate students and researchers in academia, government laboratories, and industry who are interested in applying reactive transport modeling to the topic of their research. The book will also appeal to geochemists, hydrogeologists, geophysicists, earth scientists, environmental engineers, and environmental chemists.
This standard work on contaminated site management covers the whole chain of steps involved in dealing with contaminated sites, from site investigation to remediation. An important focus throughout the book is on Risk Assessment. In addition, the book includes chapters on characterisation of natural and urban soils, bioavailability, natural attenuation, policy and stakeholder viewpoints and Brownfields. Typically, the book includes in-depth theories on soil contamination, along with offering possibilities for practical applications. More than sixty of the world’s top experts from Europe, the USA, Australia and Canada have contributed to this book. The twenty-five chapters in this book offer relevant information for experienced scientists, students, consultants and regulators, as well as for ‘new players’ in contaminated site management
