Light Scattering in Liquids and Macromolecular Solutions

Light Scattering in Liquids and Macromolecular Solutions

Author: V. Degiorgio

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 293

ISBN-13: 1461591856

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This volume contains most of the papers presented at the "Workshop on Quasielastic Light Scattering Studies of Fluids and Macromolecular Solutions" held at CISE, Segrate (Milano), Italy, from 11 to 13 May, 1979. Quasielastic light scattering (also called self-beating spectroscopy or intensity correlation spectroscopy) is the technique, introduced by Benedek and coworkers and by Cummins and coworkers about 15 years ago, by which dynamical information about a scattering medium is obtained through the measurement of the power spectrum (or the intensity correlation function) of the laser light scattered from the medium. The technique received in the early seventies a considerable impulse from the development of real-time fast digital correlators. The aim of the Workshop was to bring together a selected number of researchers in order to discuss recent developments in quasielastic light scattering and related optical methods and to report about new applications of the technique in physics, chemistry and biology. The first two days of the meeting were devoted to the oral presentations of papers. In the third day an informal session was held which included a very lively and thorough discussion of the highlights of the Workshop. Most part of the technical problems were debated during the informal session and during the subsequent visits to the light scattering laboratory in CISE.


Light Scattering in Liquids and Macromolecular Solutions

Light Scattering in Liquids and Macromolecular Solutions

Author: V. Degiorgio

Publisher: Springer

Published: 2012-02-16

Total Pages: 295

ISBN-13: 9781461591863

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This volume contains most of the papers presented at the "Workshop on Quasielastic Light Scattering Studies of Fluids and Macromolecular Solutions" held at CISE, Segrate (Milano), Italy, from 11 to 13 May, 1979. Quasielastic light scattering (also called self-beating spectroscopy or intensity correlation spectroscopy) is the technique, introduced by Benedek and coworkers and by Cummins and coworkers about 15 years ago, by which dynamical information about a scattering medium is obtained through the measurement of the power spectrum (or the intensity correlation function) of the laser light scattered from the medium. The technique received in the early seventies a considerable impulse from the development of real-time fast digital correlators. The aim of the Workshop was to bring together a selected number of researchers in order to discuss recent developments in quasielastic light scattering and related optical methods and to report about new applications of the technique in physics, chemistry and biology. The first two days of the meeting were devoted to the oral presentations of papers. In the third day an informal session was held which included a very lively and thorough discussion of the highlights of the Workshop. Most part of the technical problems were debated during the informal session and during the subsequent visits to the light scattering laboratory in CISE.


Soft-Matter Characterization

Soft-Matter Characterization

Author: Redouane Borsali

Publisher: Springer Science & Business Media

Published: 2008-07-28

Total Pages: 1490

ISBN-13: 140204464X

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This 2-volume set includes extensive discussions of scattering techniques (light, neutron and X-ray) and related fluctuation and grating techniques that are at the forefront of this field. Most of the scattering techniques are Fourier space techniques. Recent advances have seen the development of powerful direct imaging methods such as atomic force microscopy and scanning probe microscopy. In addition, techniques that can be used to manipulate soft matter on the nanometer scale are also in rapid development. These include the scanning probe microscopy technique mentioned above as well as optical and magnetic tweezers.


Dynamic Light Scattering

Dynamic Light Scattering

Author: R. Pecora

Publisher: Springer Science & Business Media

Published: 2013-11-11

Total Pages: 429

ISBN-13: 1461323894

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In the twenty years since their inception, modern dynamic light-scattering techniques have become increasingly sophisticated, and their applications have grown exceedingly diverse. Applications of the techniques to problems in physics, chemistry, biology, medicine, and fluid mechanics have prolifer ated. It is probably no longer possible for one or two authors to write a monograph to cover in depth the advances in scattering techniques and the main areas in which they have made a major impact. This volume, which we expect to be the first of aseries, presents reviews of selected specialized areas by renowned experts. It makes no attempt to be comprehensive; it emphasizes a body of related applications to polymeric, biological, and colloidal systems, and to critical phenomena. The well-known monographs on dynamic light scattering by Berne and Pecora and by Chu were published almost ten years ago. They provided comprehensive treatments of the general principles of dynamic light scat tering and gave introductions to a wide variety of applications, but natu rally they could not treat the new applications and advances in older ones that have arisen in the last decade. The new applications include studies of interacting particles in solution (Chapter 4); scaling approaches to the dynamics of polymers, including polymers in semidilute solution (Chapter 5); the use of both Fabry-Perot interferometry and photon correlation spectroscopy to study bulk polymers (Chapter 6); studies of micelIes and microemulsions (Chapter 8); studies of polymer gels (Chapter 9).


Phenomenology of Polymer Solution Dynamics

Phenomenology of Polymer Solution Dynamics

Author: George D. J. Phillies

Publisher: Cambridge University Press

Published: 2011-10-06

Total Pages: 527

ISBN-13: 1139504517

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Presenting a completely new approach to examining how polymers move in non-dilute solution, this book focuses on experimental facts, not theoretical speculations, and concentrates on polymer solutions, not dilute solutions or polymer melts. From centrifugation and solvent dynamics to viscosity and diffusion, experimental measurements and their quantitative representations are the core of the discussion. The book reveals several experiments never before recognized as revealing polymer solution properties. A novel approach to relaxation phenomena accurately describes viscoelasticity and dielectric relaxation and how they depend on polymer size and concentration. Ideal for graduate students and researchers interested in the properties of polymer solutions, the book covers real measurements on practical systems, including the very latest results. Every significant experimental method is presented in considerable detail, giving unprecedented coverage of polymers in solution.


Light Scattering and Photon Correlation Spectroscopy

Light Scattering and Photon Correlation Spectroscopy

Author: E.R. Pike

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 468

ISBN-13: 9401155860

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Since their inception more than 2.5 years ago, photon correlation techniques for the spatial, temporal or spectral analysis of fluctuating light fields have found an ever-widening range of applications. Using detectors which re spond to single quanta of the radiation field, these methods are intrinsically digital in natnre and in many experimental situations offer a unique degree of accuracy and sensitivity, not only for the study of primary light sources themselves, but most particularly in the use of a laser-beam probe to study light scattering from pure fluids, macromolecular suspensions and laminar or turbulent flowing fluids and gases. Following the earliest developments in laser scattering by dilute macro nl01ecular suspensions, in , ... hich particle sizing was the main aim, and the use of photon correlation techniques for laser-Doppler studies of flow and tnrbuence. both of which areas were the subject of NATO ASls in Capri, Italy in 19;:3 and 19;6. significant advances have be('n made in recent years in many other areas. These were reflected in the topics covered in this NATO Advanced Research Workshop, which took place from August 2;th to 30th, 1!)!}6, at the Jagiellonian University, Krakow, Poland. These in cluded ('xperimental techniques. statist.ics and data reduction, colloids and aggregation, polymers, gels, liquid crystals and mixtures, protein solutions, critical pllf'nomena and dense media.


Laser Light Scattering

Laser Light Scattering

Author: Benjamin Chu

Publisher: Academic Press

Published: 2012-12-02

Total Pages: 354

ISBN-13: 032316188X

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Laser Light Scattering: Basic Principles and Practice, Second Edition deals with the technical aspects of laser light scattering, including the basic principles and practice. Topics covered include light scattering theory, optical mixing spectrometry, photon correlation spectroscopy, and interferometry. Experimental methods and methods of data analysis are also described. This book is comprised of eight chapters and begins with a discussion on the interrelationship between laser light scattering and other types of scattering techniques that use X-rays and neutrons, with particular reference to momentum and energy transfers as well as time-averaged and time-dependent scattered intensity. The spectrum of scattered light and a single-particle approach to time-averaged scattered intensity are considered. The following chapters focus on photoelectric detection of the scattered electric field; optical mixing spectrometers; basic equations for photon correlation spectroscopy; and the principles of Fabry-Perot interferometry. The pertinent features of the experimental aspects of laser light scattering are also outlined, together with the Laplace inversion problem. The final chapter examines polymer molecular-weight distributions in relation to particle sizing. This monograph will be of interest to physicists.


Light Scattering Reviews 4

Light Scattering Reviews 4

Author: Alexander A. Kokhanovsky

Publisher: Springer Science & Business Media

Published: 2009-07-25

Total Pages: 516

ISBN-13: 354074276X

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This fourth volume of Light Scattering Reviews is composed of three parts. The ?rstpartisconcernedwiththeoreticalandexperimentalstudiesofsinglelightsc- tering by small nonspherical particles. Light scattering by small particles such as, for instance, droplets in the terrestrial clouds is a well understood area of physical optics. On the other hand, exact theoretical calculations of light scattering p- terns for most of nonspherical and irregularly shaped particles can be performed only for the restricted values of the size parameter, which is proportional to the ratio of the characteristic size of the particle to the wavelength?. For the large nonspherical particles, approximations are used (e. g. , ray optics). The exact th- retical techniques such as the T-matrix method cannot be used for extremely large particles, such as those in ice clouds, because then the size parameter in the v- iblex=2?a/???,wherea is the characteristic size (radius for spheres), and the associated numerical codes become unstable and produce wrong answers. Yet another problem is due to the fact that particles in many turbid media (e. g. , dust clouds) cannot be characterized by a single shape. Often, refractive indices also vary. Because of problems with theoretical calculations, experimental (i. e. , la- ratory) investigations are important for the characterization and understanding of the optical properties of such types of particles. The ?rst paper in this volume, written by B. Gustafson, is aimed at the descr- tionofscaledanalogueexperimentsinelectromagneticscattering.


Polyelectrolytes

Polyelectrolytes

Author: Masanori Hara

Publisher: CRC Press

Published: 1992-11-12

Total Pages: 416

ISBN-13: 9780824787592

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Aims to provide in-depth coverage of recent advances in all important areas of polyelectrolyte research and applications. Topics covered in this text include scaling theory, dynamic light scattering, neutron scattering, biopolymers and ionomers.