Polymers, Liquid Crystals, and Low-Dimensional Solids
Polymers, Liquid Crystals, and Low-Dimensional Solids

Author: Norman H. March

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 635

ISBN-13: 1461323673

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This book deals with three related areas having both fundamental and technological interest. In the first part, the objective is to provide a bird's eye view on structure in polymeric solids. This is then complemented by a chapter, directly technological in its emphasis, dealing with the influence of processing on polymeric materials. In spite of the technological interest, this leads to some of the current fundamental theory. Part II, concerned with liquid crystals, starts with a discussion of the physics of the various types of material, and concludes with a treatment of optical applications. Again, aspects of the theory are stressed though this part is basically phenomenological in character. In Part III, an account is given first of the use of chemical-bonding arguments in understanding the electronic structure of low-dimensional solids, followed by a comprehensive treatment of the influence of dimen sionality on phase transitions. A brief summary of dielectric screening in low-dimensional solids follows. Space-charge layers are then treated, including semiconductor inversion layers. Effects of limited dimensionality on superconductivity are also emphasized. Part IV concludes the volume with two specialized topics: electronic structure of biopolymers, and topological defects and disordered systems. The Editors wish to acknowledge that this book had its origins in the material presented at a course organized by the International Centre for Theoretical Physics, Trieste.

Introduction to Liquid State Physics
Introduction to Liquid State Physics

Author: Norman Henry March

Publisher: World Scientific

Published: 2002

Total Pages: 454

ISBN-13: 9789810246525

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This important book provides an introduction to the liquid state. A qualitative description of liquid properties is first given, followed by detailed chapters on thermodynamics, liquid structure in relation to interaction forces and transport properties such as diffusion and viscosity. Treatment of complex fluids such as anisotropic liquid crystals and polymers, and of technically important topics such as non-Newtonian and turbulent flows, is included. Surface properties and characteristics of the liquid-vapour critical point are also discussed. While the book focuses on classical liquids, the final chapter deals with quantal fluids.

Liquid Crystalline and Mesomorphic Polymers
Liquid Crystalline and Mesomorphic Polymers

Author: Valery P. Shibaev

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 378

ISBN-13: 1461383331

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Among the various new directions in modern polymer science, the design and investigation of liquid crystal (LC) polymers have been the ones growing most actively and fruitfully. In spite of that, the possible formation of an anisotropic LC phase was only demonstrated theoretically for the first time in the 1950s by Onsager [1] and Flory [2], and then experimentally verified in the studies with polypeptides solutions. In essence, the studies of these LC lyotropic systems did not deviate from the theme of purely academic interest. It was at the beginning of the 1970s that the experimental "explosion" occurred, when aromatic polyamides were synthesized and their ability to form LC solutions in certain very aggressive solvents was discovered. The search for practical applications of such LC systems was crowned with the successful creation of the new generation of ultrastrong high-modulus ther mostable fibers, such as the Kevlar, due to the high degree of order of the macromolecules in the anisotropic LC state. In fact, these investigations coincided with the swift emergence on the practical "scene" of thermotropic low-molar-mass liquid crystals, with the use of these materials in microelectronics and electro optics (figures and let ters indicators, displays in personal computers, and flat TV, etc.). Polymer scientists also began to develop methods of synthesizing thermotropic LC polymers by incorporating mesogenic fragments in the main (main-chain LC polymers) or side branchings of the macromolecules (side-chain or comb shaped polymers).

Polymer Structure Characterization
Polymer Structure Characterization

Author: Richard A Pethrick

Publisher: Royal Society of Chemistry

Published: 2015-10-20

Total Pages: 493

ISBN-13: 1782625593

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The different physical properties displayed by low molar mass organic materials and polymers are a result of their molecular organisation. In order to understand the structure – property relationship of a material it is necessary to first look at the interactions at a molecular level. This new edition of Polymer Structure Characterization provides readers with the background needed to understand the factors that influence molecular organization and how this affects the morphology and bulk physical properties of a material. In order to introduce the concepts, the book first looks at small molecular systems and builds up to complex macromolecular systems. The second edition has been fully revised and updated to include new examples and references. Topics covered include: organic crystals, liquid crystals, plastic crystals, polymer crystal growth, amorphous glassy materials, polymer surfaces and interfaces, colloids and molecular organization in liquids as well as two new chapters on self-assembly and biopolymer systems. The book is intended to provide complimentary material for a range of undergraduate and postgraduate courses in materials science, molecular chemistry and chemical physics. In addition to polymer and material scientists, the book would also be of interest to chemists and physicists studying the properties of organic materials.

Thermotropic Liquid Crystal Polymers
Thermotropic Liquid Crystal Polymers

Author: Tai-Shung Chung

Publisher: CRC Press

Published: 2001-03-01

Total Pages: 392

ISBN-13: 9781420012521

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Liquid crystal polymers are sometimes called super polymers--with good reason. Their wide range of exceptional properties and ease of processing make them design candidates for many demanding applications. This new book provides a thorough review of LCP technology with the emphasis on the chemistry, synthesis and characterization of the material in its many variants. Additional chapters cover processing and applications. From the Editor's Preface The field of thermotropic liquid crystalline polymers has grown substantially in the last two decades, with fundamental research, publications, commercial products, and patents. In the 1980's, Dr. Ralph Miano led my colleagues and me at Hoechst Celanese in commercializing the first thermotropic liquid crystalline polymers, based on Dr. Gordon Calundann's composition patents. Today, more than seven companies have produced thermotropic liquid crystalline polymer materials, with at least 50 variants available. Hence, it is timely to compile a comprehensive review on the nature of this type of material and the ongoing progress in this field.... The goals of this book are to summarize previous work, provide new insights into this class of polymers, and add to the understanding of the formation of liquid crystallinity. This book covers a wide range of topics and addresses different disciplines in the field. The chapters are arranged as a learning scheme for the professional, from basic science to applied engineering. The first few chapters summarize the syntheses of various polyester, polyester-amid, and polyimide liquid crystalline polymers. The science and origins of liquid crystal formation are revealed. Next, we introduce the characterizations of these materials by their different chemical and physical aspects. Because most commercially available thermotropic liquid crystalline polymers have been used in the form of composites, we have also incorporated a chapter on polymer blends, detailing blending mechanisms and resultant properties. Two chapters on thermosetting liquid crystalline polymers integrate them with other topics, because of their unique importance and their applications for microelectronics and packaging. The final chapter deals with the engineering and processing aspects of thermoplastic liquid crystalline polymers for a variety of applications.

Polymer Structure Characterization
Polymer Structure Characterization

Author: Richard Arthur Pethrick

Publisher: Royal Society of Chemistry

Published: 2007

Total Pages: 353

ISBN-13: 0854044663

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This book brings together, in a logical fashion, the way in which molecular interactions lead to the observedmorphologies in crystalline organic materials and polymers. It is arranged into self contained chapters on various aspects of materials science and includes discussions of topics such as crystal growth, polymer morphology, amorphous glassy materials, polymer phase separation and structure and organisation in materials. The main feature of this title is that, within a single volume, a range of topics is covered which normally would only be found in a number of separate volumes. It is aimed at polymer - materials scientists but will also be of interest to chemists and physics students interested in the properties of organic materials.

Electro-optic and Photorefractive Materials
Electro-optic and Photorefractive Materials

Author: Peter Günter

Publisher: Springer Science & Business Media

Published: 2012-12-06

Total Pages: 395

ISBN-13: 3642719074

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This volume is based on lectures and contributed papers presented at the Eleventh Course of the International School of Materials Science and Tech nology that was held in Erice, Sicily, Italy at the Ettore Majorana Center for Scientific Culture during the period 6-17 July 1986. The subject of the course was "Electro-optic and Photorefractive Materials: Applications in Sig nal Processing and Phase Conjugation" . The fields of electro-optics and photorefraction have developed rapidly since the invention of lasers just over twenty-five years ago. The possibil of altering the optical properties of a material by electric fields or by ity optical waves is of great importance for both pure science and for practical applications such as optical signal processing, telecommunications and opti cal display devices. These effects allow us to manipulate (modulate, deflect) and process a given light wave. Modulation, deflection and processing of light waves by means of the electro-optic effect is of fundamental importance in fiber optic telecommuniC1. tions and sensor systems w here the light signals can be processed prior or subsequent to transmission through the fibers. Thin film electro-optic materials with suitable electrode arrays on· the surface of the wave-guiding structures result in a technology often referred to as inte grated optics. In principle, integrated optics devices allow miniaturization and integration of many operations onto a single chip. The photorefractive effect, defined as a photo-induced change of the in dices of refraction, was the other topic treated in this course.

Liquid Crystals
Liquid Crystals

Author: S. Chandrasekhar

Publisher: Cambridge University Press

Published: 1992-11-26

Total Pages: 484

ISBN-13: 9780521417471

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This is a new and greatly revised edition of Professor Chandrasekhar's classic book Liquid Crystals, first published in 1977. The subject of liquid crystals has grown into an exciting interdisciplinary research field with important practical applications. This book presents a systematic and self-contained treatment of the physics of the different types of thermotropic liquid crystals - the three classical types, nematic, cholesteric and smectic, and the newly discovered discotic type. Included is a description of the structures of these four main types and their polymorphic modifications, their thermodynamical, optical and mechanical properties and their behaviour under external fields. The basic principles underlying the major applications of liquid crystals in display technology and in thermography are also discussed. This book will be of great value to advanced students and researchers in condensed matter physics, chemical physics, materials science and technology with an interest in the physics, chemistry and applications of liquid crystals.