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Author: Peter Buhler
Publisher:
Published: 2000
Total Pages: 168
ISBN-13:
DOWNLOAD EBOOKDescribes the use of concept of the energetic unity of fundemental laws of thermodynamics. Refers only to experimentally measurable properties of materials such as internal energy, free energy, and entropy.
Author: Bruce H. Mahan
Publisher: Courier Corporation
Published: 2006-03-17
Total Pages: 178
ISBN-13: 0486450546
DOWNLOAD EBOOKThis straightforward presentation explores chemical applications of thermodynamics as well as physical interpretations. The author considers the first and second laws of thermodynamics in turn, after which he proceeds to applications of thermodynamic principles, emphasizing the interpretation of entropy changes and chemical behavior in terms of qualitative molecular properties. 1964 edition.
Author: Peter A. Rock
Publisher: University Science Books
Published: 2013-06-19
Total Pages: 576
ISBN-13: 9781891389320
DOWNLOAD EBOOKThis textbook is a general introduction to chemical thermodynamics.
Author: Norio Sato
Publisher: Elsevier
Published: 2004-03-31
Total Pages: 161
ISBN-13: 0080501001
DOWNLOAD EBOOKThis book is a beginners introduction to chemical thermodynamics for engineers. In the textbook efforts have been made to visualize as clearly as possible the main concepts of thermodynamic quantities such as enthalpy and entropy, thus making them more perceivable. Furthermore, intricate formulae in thermodynamics have been discussed as functionally unified sets of formulae to understand their meaning rather than to mathematically derive them in detail.In this textbook, the affinity of irreversible processes, defined by the second law of thermodynamics, has been treated as the main subject, rather than the equilibrium of chemical reactions. The concept of affinity is applicable in general not only to the processes of chemical reactions but also to all kinds of irreversible processes.This textbook also includes electrochemical thermodynamics in which, instead of the classical phenomenological approach, molecular science provides an advanced understanding of the reactions of charged particles such as ions and electrons at the electrodes.Recently, engineering thermodynamics has introduced a new thermodynamic potential called exergy, which essentially is related to the concept of the affinity of irreversible processes. This textbook discusses the relation between exergy and affinity and explains the exergy balance diagram and exergy vector diagram applicable to exergy analyses in chemical manufacturing processes. This textbook is written in the hope that the readers understand in a broad way the fundamental concepts of energy and exergy from chemical thermodynamics in practical applications. Finishing this book, the readers may easily step forward further into an advanced text of their specified line.- Visualizes the main concepts of thermodynamics to show the meaning of the quantities and formulae.- Focuses mainly on the affinity of irreversible processes and the related concept of exergy.- Provides an advanced understanding of electrochemical thermodynamics.
Author: E Brian Smith
Publisher: World Scientific Publishing Company
Published: 2004-04-08
Total Pages: 182
ISBN-13: 1911298305
DOWNLOAD EBOOKThis widely acclaimed text, now in its fifth edition and translated into many languages, continues to present a clear, simple and concise introduction to chemical thermodynamics. An examination of equilibrium in the everyday world of mechanical objects provides the starting point for an accessible account of the factors that determine equilibrium in chemical systems. This straightforward approach leads students to a thorough understanding of the basic principles of thermodynamics, which are then applied to a wide range of physico-chemical systems. The book also discusses the problems of non-ideal solutions and the concept of activity, and provides an introduction to the molecular basis of thermodynamics.Over five editions, the views of teachers of the subject and their students have been incorporated. The result is a little more rigour in specifying the dimensions within logarithmic expressions, the addition of more worked examples and the inclusion of a simple treatment of the molecular basis of thermodynamics. Students on courses in thermodynamics will continue to find this popular book an excellent introductory text./a
Author: Leonard K. Nash
Publisher: Courier Corporation
Published: 2005-08-23
Total Pages: 194
ISBN-13: 0486446123
DOWNLOAD EBOOKOriginally published: 2nd ed. Reading, Mass.: Addison-Wesley Pub. Co., 1970, in series: Addison-Wesley series in the principles of chemistry.
Author: Donald D. Wagman
Publisher:
Published: 1982
Total Pages: 412
ISBN-13:
DOWNLOAD EBOOKAuthor: Byung Chan Eu
Publisher: World Scientific
Published: 2010
Total Pages: 467
ISBN-13: 9814295116
DOWNLOAD EBOOKThermodynamics is an ever evolving subject. This book aims to introduce to advanced undergraduate students and graduate students the fundamental ideas and notions of the first and second laws of thermodynamics in a manner unavailable in the usual textbooks on the subject of thermodynamics. For example, it treats the notions of unavailable work, compensated and uncompensated heats, and dissipation, which make it possible to formulate the thermodynamic laws in more broadened forms than those in the conventional treatment of equilibrium thermodynamics. It thus strives to prepare students for more advanced subjects of irreversible processes, which are encountered in our everyday scientific activities. In addition, it also aims to provide them with functional and practical knowledge of equilibrium chemical thermodynamics of reversible processes in real fluids. It discusses temperature, work and heat, thermodynamic laws, equilibrium conditions and thermodynamic stability, thermodynamics of reversible processes in gases and liquids, in surfaces, chemical equilibria, reversible processes in electrolyte solutions and dielectrics in static electric and magnetic fields. A couple of examples for irreversible processes associated with fluid flows and chemical pattern formation and wave propagations are discussed as examples for applications of broader treatments of the thermodynamic laws in the realm of irreversible phenomena.
Author: Gilbert Newton Lewis
Publisher:
Published: 1923
Total Pages: 688
ISBN-13:
DOWNLOAD EBOOKThe scope of thermodynamics. Definitions; the concept of equilibrium. Conventions and mathematical methods. Solutions. The first law of thermodynamics and the concept of energy. The fugacity. Application of the second law to solutions. The perfect solution. The laws of the dilute solution. Systems involving variables other than pressure, temperature and composition. A useful function, called the activity, and its application to solutions. Change of activity with the temperature, and the calculation of activity from freezing points. The standard change of free energy; the equilibrium constant. Solutions of electrolytes. The activity of strong electrolytes. The activity of electrolytes from freezing point data, and tables of activity coefficients. Activity coefficient in mixed electrolytes; the principle of the ionic strength; the activity of individual ions. The galvanic cell. Single potentials; standard electrode potentials of the elements. The third law of thermodynamics. The entropy of monatomic gases and a table of atomic entropies. Introduction to systematic free energy calculations: the free energy of elementary hydrogen and metallic hydrides. Oxygen and its compouns with hydrogen and with some metals. Chlorine and its compouns. Bromine and its compounds. Iodine and its compounds. Nitrogen compounds. Carbon and some of its compounds. Compounds of carbon and nitrogen. Table of free energies; and examples illustrating its use. Conversion table for mol fractions, mol ratios and molities. Some useful numerical factors. Coefficients employed in converting activity, equilibrium constant and free energy from one temperature to another. Publications by the authrs, pertaining to thermodynamics.
Author: Maxwell Len McGlashan
Publisher: Royal Society of Chemistry
Published: 1978
Total Pages: 292
ISBN-13: 0851862632
DOWNLOAD EBOOKThis product is not available separately, it is only sold as part of a set. There are 750 products in the set and these are all sold as one entity. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.
