A Textbook of Physical Chemistry, Second Edition serves as an introductory text to physical chemistry. Topics covered range from wave mechanics and chemical bonding to molecular spectroscopy and photochemistry; ideal and nonideal gases; the three laws of thermodynamics; thermochemistry; and solutions of nonelectrolytes. The kinetics of gas-phase reactions; colloids and macromolecules; and nuclear chemistry and radiochemistry are also discussed. This edition is comprised of 22 chapters; the first of which introduces the reader to the behavior of ideal and nonideal gases, with particular emphasis on the van der Waals equation. The discussion then turns to the kinetic molecular theory of gases and the application of the Boltzmann principle to the treatment of molar polarization; dipole and magnetic moments; the phenomenology of light absorption; and classical and statistical thermodynamics. The chapters that follow focus on the traditional sequence of chemical and phase equilibria, electrochemistry, and chemical kinetics in gas phase and solution phase. This book also considers wave mechanics and its applications; molecular spectroscopy and photochemistry; and the excited state, and then concludes with an analysis of crystal structure, colloid and polymer chemistry, and radio and nuclear chemistry. This reference material is intended primarily as an introductory text for students of physical chemistry.
Maintaining the clear, approachable writing style characteristic of author Karen Timberlake, Basic Chemistry, Fourth Edition, adds to its suite of problem-solving tools and techniques necessary for success in chemistry. Engaging new features such as end-of-section Math Practice problems, video tutorials and Math Review Modules allow readers to practice and master quantitative skills. Popular features, including "Combining Ideas" sections and end-of-chapter questions, have also been strengthened and expanded. Modern real-world applications help students connect chemical principles to events in their world, while stories involving careers illustrate the importance of chemistry in future careers.
This fifth edition gives students an in-depth fundamental treatment of physical chemistry which is made easy to follow by providing full step-by-step derivations, clear explanations and by avoiding advanced mathematics unfamiliar to students. Necessary maths and physics have thorough review sections, and all worked examples are now followed by a practice exercise. The material on quantum mechanics has been substantially revised. The book is organized so that students can see the broad structure and logic of physical chemistry rather than a mixture of formulas and ideas presented randomly, and a fair number of biological applications are included.
A Concise Introduction to General, Organic, and Biological Chemistry General, Organic, and Biological Chemistry strengthens the evidenced strategy of integrating general, organic, and biological chemistry for a focused introduction to the fundamental connections between chemistry and life. The streamlined approach offers readers a clear path through the content over a single semester. The Third Edition integrates essential topics more effectively than any text on the market, covering core concepts in each discipline in just 12 comprehensive chapters. Practical connections and applications show readers how to use their understanding of chemistry in everyday life and future health professions. With an emphasis on problem solving and critical thinking, the book promotes active and attentive learning, which now include NEW! media assets, Practicing the Concepts. Featuring coauthor Todd Deal, these 3 to 5 minute videos explore key concepts in general, organic, and biological chemistry that readers traditionally find difficult. Readers gain skills and deepen their knowledge as they watch the videos and then practice what they have learned with Pause & Predict problems and a series of follow up multiple-choice questions. The Third Edition places a greater emphasis on matching what professors teach in the classroom by increasing the coverage of biochemical applications in each chapter. A new design was created to highlight the career content in order to increase relevancy. Also available as a Pearson eText or packaged with Mastering Chemistry Pearson eText is a simple-to-use, mobile-optimized, personalized reading experience that can be adopted on its own as the main course material. It lets students highlight, take notes, and review key vocabulary all in one place, even when offline. Seamlessly integrated videos and other rich media engage students and give them access to the help they need, when they need it. Educators can easily share their own notes with students so they see the connection between their eText and what they learn in class – motivating them to keep reading, and keep learning. Mastering combines trusted author content with digital tools and a flexible platform to personalize the learning experience and improve results for each student. Built for, and directly tied to the text, Mastering Chemistry enables an extension of learning, allowing students a platform to practice, learn, and apply outside of the classroom. Note: You are purchasing a standalone book; Pearson eText and Mastering Chemistry do not come packaged with this content. Students, ask your instructor for the correct package ISBN and Course ID. Instructors, contact your Pearson representative for more information. If your instructor has assigned Pearson eText as your main course material, search for: • 0135237327 / 9780135237328 Pearson eText General, Organic, and Biological Chemistry, 3/e -- Access Card OR • 0135237335 / 9780135237335 Pearson eText General, Organic, and Biological Chemistry, 3/e -- Instant Access If you would like to purchase both the physical text and MasteringChemistry, search for: 0134041569/9780134041568 General, Organic, and Biological Chemistry Plus MasteringChemistry with eText -- Access Card Package, 3/e Package consists of: 0134162048 / 9780134162041 MasteringChemistry with Pearson eText -- ValuePack Access Card -- for General, Organic, and Biological Chemistry 0134042425 / 9780134042428 General, Organic, and Biological Chemistry, 3/e
to arrive at some temporary consensus model or models; and to present reliable physical data pertaining to water under a range of conditions, i.e., "Dorsey revisited," albeit on a less ambitious scale. I should like to acknowledge a debt of gratitude to several of my col leagues, to Prof. D. J. G. Ives and Prof. Robert L. Kay for valuable guidance and active encouragement, to the contributors to this volume for their willing cooperation, and to my wife and daughters for the understanding shown to a husband and father who hid in his study for many an evening. My very special thanks go to Mrs. Joyce Johnson, who did all the cor respondence and much of the arduous editorial work with her usual cheerful efficiency. F. FRANKS Biophysics Division Unilever Research Laboratory ColworthjWelwyn Colworth House, Sharnbrook, Bedford March 1972 Contents Chapter 1 Introduction-Water, the Unique Chemical F. Franks I. lntroduction ........................................ . 2. The Occurrence and Distribution of Water on the Earth 2 3. Water and Life ...................................... 4 4. The Scientific Study of Water-A Short History ........ 8 5. The Place of Water among Liquids . . . . . . . . . . . . . . . 13 . . . . . Chapter 2 The Water Moleeule C. W. Kern and M. Karplus 1. Introduction. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 . . . . . . . . . . 2. Principles of Structure and Spectra: The Born-Oppenheimer Separation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 . . . . . . . . . . . . 3. The Electronic Motion ............................... 26 3.1. The Ground Electronic State of Water ............ 31 3.2. The Excited Electronic States of Water ........... 50 4. The Nuclear Motion ................................. 52 5. External-Field Effects ................................. 70 5.1. Perturbed Hartree-Fock Method . . . . . . . . . . . . . . . 74 . . .
"Conceptual Chemistry, " Third Edition features more applied material and an expanded quantitative approach to help readers understand how chemistry is related to their everyday lives. Building on the clear, friendly writing style and superior art program that has made "Conceptual Chemistry" a market-leading text, the Third Edition links chemistry to the real world and ensures that readers master the problem-solving skills they need to solve chemical equations. Chemistry Is A Science, Elements of Chemistry, Discovering the Atom and Subatomic Particles, The Atomic Nucleus, Atomic Models, Chemical Bonding and Molecular Shapes, Molecular Mixing, Those, Incredible Water Molecules, An Overview of Chemical Reactions, Acids and Bases, Oxidations and Reductions, Organic Chemistry, Chemicals of Life, The Chemistry of Drugs, Optimizing Food Production, Fresh Water Resources, Air Resources, Material Resources, Energy Resources For readers interested in how chemistry is related to their everyday lives.
Atkins' Physical Chemistry: Molecular Thermodynamics and Kinetics is designed for use on the second semester of a quantum-first physical chemistry course. Based on the hugely popular Atkins' Physical Chemistry, this volume approaches molecular thermodynamics with the assumption that students will have studied quantum mechanics in their first semester. The exceptional quality of previous editions has been built upon to make this new edition of Atkins' Physical Chemistry even more closely suited to the needs of both lecturers and students. Re-organised into discrete 'topics', the text is more flexible to teach from and more readable for students. Now in its eleventh edition, the text has been enhanced with additional learning features and maths support to demonstrate the absolute centrality of mathematics to physical chemistry. Increasing the digestibility of the text in this new approach, the reader is brought to a question, then the math is used to show how it can be answered and progress made. The expanded and redistributed maths support also includes new 'Chemist's toolkits' which provide students with succinct reminders of mathematical concepts and techniques right where they need them. Checklists of key concepts at the end of each topic add to the extensive learning support provided throughout the book, to reinforce the main take-home messages in each section. The coupling of the broad coverage of the subject with a structure and use of pedagogy that is even more innovative will ensure Atkins' Physical Chemistry remains the textbook of choice for studying physical chemistry.
Chemical Kinetics bridges the gap between beginner and specialist with a path that leads the reader from the phenomenological approach to the rates of chemical reactions to the state-of-the-art calculation of the rate constants of the most prevalent reactions: atom transfers, catalysis, proton transfers, substitution reactions, energy transfers and electron transfers. For the beginner provides the basics: the simplest concepts, the fundamental experiments, and the underlying theories. For the specialist shows where sophisticated experimental and theoretical methods combine to offer a panorama of time-dependent molecular phenomena connected by a new rational. Chemical Kinetics goes far beyond the qualitative description: with the guidance of theory, the path becomes a reaction path that can actually be inspected and calculated. But Chemical Kinetics is more about structure and reactivity than numbers and calculations. A great emphasis in the clarity of the concepts is achieved by illustrating all the theories and mechanisms with recent examples, some of them described with sufficient detail and simplicity to be used in general chemistry and lab courses.* Looking at atoms and molecules, and how molecular structures change with time. * Providing practical examples and detailed theoretical calculations* Of special interest to Industrial Chemistry and Biochemistry
