Photoelectrochemistry and Photovoltaics of Layered Semiconductors

Photoelectrochemistry and Photovoltaics of Layered Semiconductors

Author: A. Aruchamy

Publisher: Springer Science & Business Media

Published: 2013-03-13

Total Pages: 367

ISBN-13: 9401513015

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This volume aims at bringing together the results of extensive research done during the last fifteen years on the interfacial photoelectronic properties of the inorganic layered semiconducting materials, mainly in relation to solar energy conversion. Significant contributions have been made both on the fundamental aspects of interface characteristics and on the suitability of the layered materials in photoelectrochemical (semiconductor/electrolyte junctions) and in solid state photovoltaic(Schottky and p-n junctions) cells. New insights into the physical and chemical characteristics of the contact surfaces have been gained and many new applications of these materials have been revealed. In particular, the basal plane surface of the layered materials shows low chemical reactivity and specific electronic behaviour with respect to isotropic solids. In electrochemical systems, the inert nature of these surfaces characterized by saturated chemical bonds has been recognized from studies on charge transfer reactions and catalysis. In addition, studies on the role of the d-band electronic transitions and the dynamics of the photogene rated charge carriers in the relative stability of the photoelectrodes of the transition metal dichalcogenides have deepened the understanding of the interfacial photoreactions. Transition metal layered compounds are also recognized as ideal model compounds for the studies Involving surfaces: photoreactions, adsorption phenomena and catalysis, scanning tunneling microscopy and spectroscopy and epitaxial growth of thin films. Recently, quantum size effects have been investigated in layered semiconductor colloids.


Photoelectrochemistry and Photovoltaics of Layered Semiconductors

Photoelectrochemistry and Photovoltaics of Layered Semiconductors

Author: A Aruchamy

Publisher:

Published: 1992-01-31

Total Pages: 376

ISBN-13: 9789401513029

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This volume is devoted exclusively to the interfacial photoelectronic properties of the inorganic layered semiconductors investigated in solid state (Schottky and p-n) photovoltaic and photoelectrochemical (solid/electrolyte) cells. The results of extensive studies on the various interfacial and surface electronic characteristics, interfacial photoreactions and materials aspects of the layered semiconductors reported in the last fifteen years have been reviewed. The layered transition metal dichalcogenides have served as model compounds for the investigation of the details of photoelectrochemical processes and related studies involving surfaces. The layered semiconducting materials have been found to be promising solar cell materials. Significant energy conversion efficiencies have been realized in photoelectrochemical solar cells and in solid state photovoltaic cells. Novel studies including quantum size effects in layered semiconductors have been reported. UHV spectroscopic studies of the surfaces of important layered semiconductors have been given. Recent developments in the preparation of the layered materials have been summarized. New insights into the physical and chemical characteristics of this class of materials have been gained by the studies reported in this book. Highlights include: -- Data on optical and electronic properties of layered semiconductors; -- Solid state and semiconductor/electrolyte junction characteristics; -- Photovoltaic and photoelectrochemical solar cells based on layered materials; -- UHV spectroscopic studies of surfaces of layered semiconductors; -- Quantum size effects in layered semiconductor colloids; -- Novel layered material preparation techniques.


Photoelectrochemical Engineering for Solar Harvesting

Photoelectrochemical Engineering for Solar Harvesting

Author: Samrana Kazim

Publisher: Elsevier

Published: 2024-06-24

Total Pages: 504

ISBN-13: 0323954952

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Photoelectrochemical Engineering for Solar Harvesting provides an up-to-date appraisal of the photon engineering of innovative catalysts for solar energy harvesting.Sunlight-driven fuel synthesis is the most sustainable and potentially economical option for producing energy vectors through water splitting. Thus this book focuses on the design of photocatalysts and water oxidation catalysts, as artificial photosynthesis and hydrogen fuel production via water oxidation (in place of fossil fuels) are two promising approaches towards renewable energy.The book critically analyzes the overall progress, potential challenges, and the possibility of industrialization of new catalysts in the near future. The primary emphasis of the discussion is on experimental approaches from materials synthesis to device applications, however, there will also be some introduction to relevant photochemistry concepts.Photoelectrochemical Engineering for Solar Harvesting is suitable for materials scientists and chemists who through the use of photonics are in continuous pursuit of improving the efficiencies of different devices used to capture solar energy for the generation of sustainable fuel. - Covers design of innovative energy materials such as photocatalysts and water oxidation catalysts for solar energy harvesting - Reviews briefly computational and theoretical approaches before providing comprehensive overview of experimental directions - Provides information to guide photon and photoelectrochemical engineering of catalysts for solar application


Nanostructured and Photoelectrochemical Systems for Solar Photon Conversion

Nanostructured and Photoelectrochemical Systems for Solar Photon Conversion

Author: Mary D. Archer

Publisher: Imperial College Press

Published: 2008

Total Pages: 781

ISBN-13: 1848161549

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In this book, expert authors describe advanced solar photon conversion approaches that promise highly efficient photovoltaic and photoelectrochemical cells with sophisticated architectures on the one hand, and plastic photovoltaic coatings that are inexpensive enough to be disposable on the other. Their leitmotifs include light-induced exciton generation, junction architectures that lead to efficient exciton dissociation, and charge collection by percolation through mesoscale phases. Photocatalysis is closely related to photoelectrochemistry, and the fundamentals of both disciplines are covered in this volume.


Photoelectrochemical Materials and Energy Conversion Processes

Photoelectrochemical Materials and Energy Conversion Processes

Author: Richard C. Alkire

Publisher: John Wiley & Sons

Published: 2010-12-01

Total Pages: 374

ISBN-13: 3527633235

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An international group of leading scientists from the field has contributed to the 12th volume in this series, covering a range of different types of solar cells and including a critical comparison of the different techniques available for manufacturing the semiconductors needed. The result is an expert insight the central questions surrounding photovoltaic materials and systems, reflecting the latest developments in this hot and timely green topic.


Springer Handbook of Inorganic Photochemistry

Springer Handbook of Inorganic Photochemistry

Author: Detlef Bahnemann

Publisher: Springer Nature

Published: 2022-06-25

Total Pages: 1914

ISBN-13: 3030637131

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The handbook comprehensively covers the field of inorganic photochemistry from the fundamentals to the main applications. The first section of the book describes the historical development of inorganic photochemistry, along with the fundamentals related to this multidisciplinary scientific field. The main experimental techniques employed in state-of-art studies are described in detail in the second section followed by a third section including theoretical investigations in the field. In the next three sections, the photophysical and photochemical properties of coordination compounds, supramolecular systems and inorganic semiconductors are summarized by experts on these materials. Finally, the application of photoactive inorganic compounds in key sectors of our society is highlighted. The sections cover applications in bioimaging and sensing, drug delivery and cancer therapy, solar energy conversion to electricity and fuels, organic synthesis, environmental remediation and optoelectronics among others. The chapters provide a concise overview of the main achievements in the recent years and highlight the challenges for future research. This handbook offers a unique compilation for practitioners of inorganic photochemistry in both industry and academia.